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31.
TH. Blumenstock H. Fisher A. Friedle F. Hase P. Thomas 《Journal of Atmospheric Chemistry》1997,26(3):311-321
During SESAME phase I ground-based FTIR measurements were performed atEsrange near Kiruna, Sweden, from 28 January to 26 March 1994. Zenith columnamounts of ClONO2, HCl, HF, HNO3,O3, N2O, CH4, and CFC-12 werederived from solar absorption spectra. Time series of ClONO2and HCl indicate a chlorine activation at the end of January and around 1March. On 1 March a very low amount of HCl of 2.09times; 1015molec. cm-2 was detected, probably caused by a second chlorineactivation phase starting from an already decreased amount of HCl. The ratioof column amounts of HCl to ClONO2 decreased inside the vortexfrom about 1 in January to 0.4 in late March compared to values of about 2outside the vortex. Although the Arctic stratosphere was rather warm in winter1993/94 and PSCs occurred seldom, chlorine partitioning into its reservoirspecies HCl and ClONO2 changed during that winter andClONO2 is the major chlorine reservoir at the end of thewinter as in cold winters like 1991/92 and 1994/95. 相似文献
32.
Thomas S. Bianchi M. Baskaran Joseph DeLord M. Ravichandran 《Estuaries and Coasts》1997,20(2):404-415
Particulate organic carbon (POC), dissolved organic carbon (DOC), and plant pigments (chlorophylls and carotenoids) were measured approximately bimonthly from March 1992 to October 1993 in the Sabine-Neches estuary (Sabine Lake region), located on the Texas-Louisiana border. High freshwater inflow into this shallow turbid estuary results in the shortest hydraulic residence time (ca. 7 d) of all Texas estuaries (Baskaran et al. in press). Annual averages of chlorophyll-a (3.0 μg l?1) and particulate organic carbon (1.1 mg l?1) in the water column were extremely low in comparison to other shallow estuaries. The highest chlorophyll-a concentrations were observed in October 1993, in the mid and lower regions of the estuary, during the lowest river discharge. Zeaxanthin and fucoxanthin concentrations suggested that much of the chlorophyll-a during this low flow period was represented by cyanobacteria and diatoms that entered from the Gulf of Mexico. The range of DOC concentrations was generally high (4.4–20.9 mg l?1) and were significantly correlated with POC, but not with chlorophyll-a concentrations. When total suspended particulate (TSP) concentrations were below 20 to 30 mg l?1, there were significant increases in %POC and %PON of the TSP. The unusually high POC: chlorophyll-a ratios (highest value of 1423) suggested that much of the POC contained low concentrations of chlorophyll-a that had degraded during transport from wetlands in the Sabine and Neches rivers. Based on these data, this estuary can be characterized as a predominantly heterotrophic system, with low light penetrance, short particle-residence times, high DOC, and low inputs from autochthonous carbon sources. 相似文献
33.
Thomas A. Jones 《Mathematical Geology》2004,36(3):399-401
34.
35.
Thomas R. Baker 《The Professional geographer》2005,57(1):44-50
Internet‐based mapping provides a powerful alternative for successfully establishing GIS technology in the K‐12 education community, while simultaneously avoiding the traditional barriers associated with desktop GIS. Internet‐based GIS can support standards‐based inquiry methods of teaching and learning while providing basic analysis tools for studying and exploring geographic or scientific data in the classroom. 相似文献
36.
It is desirable to design proxy investigations that target regions where properties reconstructed from calibrated parameters potentially carry high-fidelity information concerning changes in large-scale climate systems. Numerical climate models can play an important role in this task, producing simulations that can be analyzed to produce spatial “fingerprints” of the expected response of various properties under a variety of different scenarios. We will introduce a new method of fingerprinting the Atlantic meridional overturning circulation (AMOC) that not only provides information concerning the sensitivity of the response at a given location to changes in the large-scale system, but also quantifies the linearity, monotonicity and symmetry of the response. In this way, locations that show high sensitivities to changes in the AMOC, but that exhibit, for example, strongly nonlinear behavior can be avoided during proxy investigations. To demonstrate the proposed approach we will use the example of the response of seawater temperatures to changes in the strength of the AMOC. We present results from an earth-system climate model which has been perturbed with an idealized freshwater forcing scenario in order to reduce the strength of the AMOC in a systematic manner. The seawater temperature anomalies that result from the freshwater forcing are quantified in terms of their sensitivity to the AMOC strength in addition to the linearity and monotonicity of their response. A first-order reversal curve (FORC) approach is employed to investigate and quantify the irreversibility of the temperature response to a slowing and recovering AMOC. Thus, FORCs allow the identification of areas that are unsuitable for proxy reconstructions because their temperature versus AMOC relationship lacks symmetry. 相似文献
37.
Thomas K. Flesch Lowry A. Harper Raymond L. Desjardins Zhiling Gao Brian P. Crenna 《Boundary-Layer Meteorology》2009,132(1):11-30
Inverse-dispersion calculations can be used to infer atmospheric emission rates through a combination of downwind gas concentrations
and dispersion model predictions. With multiple concentration sensors downwind of a compound source (whose component positions
are known) it is possible to calculate the component emissions. With this in mind, a field experiment was conducted to examine
the feasibility of such multi-source inferences, using four synthetic area sources and eight concentration sensors arranged
in different configurations. Multi-source problems tend to be mathematically ill-conditioned, as expressed by the condition
number κ. In our most successful configuration (average κ = 4.2) the total emissions from all sources were deduced to within 10% on average, while component emissions were deduced
to within 50%. In our least successful configuration (average κ = 91) the total emissions were calculated to within only 50%, and component calculations were highly inaccurate. Our study
indicates that the most accurate multi-source inferences will occur if each sensor is influenced by only a single source.
A “progressive” layout is the next best: one sensor is positioned to “see” only one source, the next sensor is placed to see
the first source and another, a third sensor is placed to see the previous two plus a third, and so on. When it is not possible
to isolate any sources κ is large and the accuracy of a multi-source inference is doubtful. 相似文献
38.
39.
Thomas R. Stewart 《Climatic change》1987,11(1-2):97-113
The Delphi technique for judgmental forecasting by expert groups is described and the controversy surrounding its use is summarized. The technique clearly does not eliminate all unwanted psychological effects on group judgment. Furthermore, the design of most Delphi studies makes it impossible to separate the signal from the noise in expert judgment. A methodological standard for evaluating judgmental forecasts is proposed. 相似文献
40.
Seong-Joong Kim Thomas J. Crowley David J. Erickson Bala Govindasamy Phillip B. Duffy Bang Yong Lee 《Climate Dynamics》2008,31(1):1-16
The climate of the last glacial maximum (LGM) is simulated with a high-resolution atmospheric general circulation model, the
NCAR CCM3 at spectral truncation of T170, corresponding to a grid cell size of roughly 75 km. The purpose of the study is
to assess whether there are significant benefits from the higher resolution simulation compared to the lower resolution simulation
associated with the role of topography. The LGM simulations were forced with modified CLIMAP sea ice distribution and sea
surface temperatures (SST) reduced by 1°C, ice sheet topography, reduced CO2, and 21,000 BP orbital parameters. The high-resolution model captures modern climate reasonably well, in particular the distribution
of heavy precipitation in the tropical Pacific. For the ice age case, surface temperature simulated by the high-resolution
model agrees better with those of proxy estimates than does the low-resolution model. Despite the fact that tropical SSTs
were only 2.1°C less than the control run, there are many lowland tropical land areas 4–6°C colder than present. Comparison
of T170 model results with the best constrained proxy temperature estimates (noble gas concentrations in groundwater) now
yield no significant differences between model and observations. There are also significant upland temperature changes in
the best resolved tropical mountain belt (the Andes). We provisionally attribute this result in part as resulting from decreased
lateral mixing between ocean and land in a model with more model grid cells. A longstanding model-data discrepancy therefore
appears to be resolved without invoking any unusual model physics. The response of the Asian summer monsoon can also be more
clearly linked to local geography in the high-resolution model than in the low-resolution model; this distinction should enable
more confident validation of climate proxy data with the high-resolution model. Elsewhere, an inferred salinity increase in
the subtropical North Atlantic may have significant implications for ocean circulation changes during the LGM. A large part
of the Amazon and Congo Basins are simulated to be substantially drier in the ice age—consistent with many (but not all) paleo
data. These results suggest that there are considerable benefits derived from high-resolution model regarding regional climate
responses, and that observationalists can now compare their results with models that resolve geography at a resolution comparable
to that which the proxy data represent. 相似文献