A critical zone observatory dedicated to suspended sediment transport: The meso-scale Galabre catchment (southern French Alps)

The 20 km² Galabre catchment belongs to the French network of critical zone observatories (OZCAR; Gaillardet et al., Vadose Zone Journal, 2018, 17(1), 1–24). It is representative of the sedimentary lithology and meteorological forcing found in Mediterranean and mountainous areas. Due to the presence of highly erodible and sloping badlands on various lithologies, the site was instrumented in 2007 to understand the dynamics of suspended sediments (SS) in such areas. Two meteorological stations including measurements of air temperature, wind speed and direction, air moisture, rainfall intensity, raindrop size and velocity distribution were installed both in the upper and lower part of the catchment. At the catchment outlet, a gauging station records the water level, temperature and turbidity (10 min time-step). Stream water samples are collected automatically to estimate SS concentration-turbidity relationships, allowing quantification of SS fluxes with known uncertainty. The sediment samples are further characterized by measuring their particle size distributions and by applying a low-cost sediment fingerprinting approach using spectrocolorimetric tracers. Thus, the contributions of badlands located on different lithologies to total SS flux are quantified at a high temporal resolution, providing the opportunity to better analyse the links between meteorological forcing variability and watershed hydrosedimentary response. The set of measurements was extended to the dissolved phase in 2017. Both stream water electrical conductivity and major ion concentrations are measured each week and every 3 h during storm events. This extension of measurements to the dissolved phase will allow progress in understanding both the origin of the water during the events and the partitioning between particulate and dissolved fluxes of solutes in the critical zone. All data sets are available at https://doi.osug.fr/public/DRAIXBLEONE_GAL/index.html .     

Asteroid 21 Lutetia at 3 μm: Observations with IRTF SpeX

We present observations of Asteroid 21 Lutetia collected 2003–2008 using the SpeX instrument on the NASA Infrared Telescope Facility (IRTF) covering 2–4 μm. We also reevaluate NSFCam observations obtained in 1996 (Rivkin, A.S., Lebofsky, L.A., Clark, B.E., Howell, E.S., Britt, D.T. [2000]. Icarus 145, 351–368). Taken together, these show deeper 3-μm band depths (of order 3–5%) in the southern hemisphere of Lutetia, and shallower band depths (of order 2% or less) in the north. Such variation is consistent with observations at shorter wavelength by previous workers (Nedelcu, D.A. et al. [2007]. Astron. Astrophys. 470, 1157–1164; Lazzarin, M. et al. [2010]. Mon. Not. R. Astron. Soc. 408, 1433–1437), who observed hemispheric-level variations from C-like spectra to X-like spectra.While the shallowness of absorption bands on Lutetia hinders identification of its surface composition, goethite appears plausible as a constituent in its southern hemisphere (Beck, P., Quirico, E., Sevestre, D., Montes-Hernandez, G., Pommerol, A., Schmitt, B. [2011]. Astron. Astrophys. 526, A85–A89). Mathematical models of space weathered goethite are most consistent with Lutetia’s southern hemisphere spectrum, but more work and further observations are necessary to confirm this suggestion.     

δ34S isotope values of dissolved sulfate (SO4 2−) as a tracer for battery acid (H2SO4) contamination in groundwater

The application of sulfur isotope (³⁴S) values of sulfate in groundwater provided the information necessary to evaluate the source, transport and fate of battery acid and associated contaminants at the Gulf Coast Recycling (GCR) facility. The chemical and isotopic composition of groundwater beneath the (GCR) property, a battery recycling facility in east Tampa, Florida, varies more than expected for an area of comparable size. Sulfate (SO₄^2–) values, for example, range from 1.2 to 11,500 mg/L and oxygen and hydrogen isotopes do not attenuate towards the weighted annual mean. Those samples that are high in sulfate generally have a low pH, which immediately indicates battery acid (H₂SO₄) contamination as a potential source for the sulfate. The low pH and high reactivity of the sulfuric acid groundwater cause the formation of hydrogeological microenvironments due to preferential dissolution of carbonate minerals, which in turn causes enhanced recharge and groundwater flow in certain areas; thus, the extreme scatter in the data set. Because of the difficult hydrogeology it is not straightforward to delineate the point-sources of contamination and up to five potential scenarios have to be evaluated: (1) seawater intrusion, (2) upwelling of high-sulfate groundwater, (3) local dissolution of gypsum, (4) an up-gradient contaminant source to the northeast of the GCR property and (5) battery acid contamination.     

Interannual variability in glacier contribution to runoff from a high‐elevation Andean catchment: understanding the role of debris cover in glacier hydrology

We present a field‐data rich modelling analysis to reconstruct the climatic forcing, glacier response, and runoff generation from a high‐elevation catchment in central Chile over the period 2000–2015 to provide insights into the differing contributions of debris‐covered and debris‐free glaciers under current and future changing climatic conditions. Model simulations with the physically based glacio‐hydrological model TOPKAPI‐ETH reveal a period of neutral or slightly positive mass balance between 2000 and 2010, followed by a transition to increasingly large annual mass losses, associated with a recent mega drought. Mass losses commence earlier, and are more severe, for a heavily debris‐covered glacier, most likely due to its strong dependence on snow avalanche accumulation, which has declined in recent years. Catchment runoff shows a marked decreasing trend over the study period, but with high interannual variability directly linked to winter snow accumulation, and high contribution from ice melt in dry periods and drought conditions. The study demonstrates the importance of incorporating local‐scale processes such as snow avalanche accumulation and spatially variable debris thickness, in understanding the responses of different glacier types to climate change. We highlight the increased dependency of runoff from high Andean catchments on the diminishing resource of glacier ice during dry years.     

Inducing mineral precipitation in groundwater by addition of phosphate

Background

Induced precipitation of phosphate minerals to scavenge trace elements from groundwater is a potential remediation approach for contaminated aquifers. The success of engineered precipitation schemes depends on the particular phases generated, their rates of formation, and their long term stability. The purpose of this study was to examine the precipitation of calcium phosphate minerals under conditions representative of a natural groundwater. Because microorganisms are present in groundwater, and because some proposed schemes for phosphate mineral precipitation rely on stimulation of native microbial populations, we also tested the effect of bacterial cells (initial densities of 10⁵ and 10⁷ mL^-1) added to the precipitation medium. In addition, we tested the effect of a trace mixture of propionic, isovaleric, formic and butyric acids (total concentration 0.035 mM).

Results

The general progression of mineral precipitation was similar under all of the study conditions, with initial formation of amorphous calcium phosphate, and transformation to poorly crystalline hydroxylapatite (HAP) within one week. The presence of the bacterial cells appeared to delay precipitation, although by the end of the experiments the overall extent of precipitation was similar for all treatments. The stoichiometry of the final precipitates as well as Rietveld structure refinement using x-ray diffraction data indicated that the presence of organic acids and bacterial cells resulted in an increasing a and decreasing c lattice parameter, with the higher concentration of cells resulting in the greatest distortion. Uptake of Sr into the solids was decreased in the treatments with cells and organic acids, compared to the control.

Conclusions

Our results suggest that the minerals formed initially during an engineered precipitation application for trace element sequestration may not be the ones that control long-term immobilization of the contaminants. In addition, the presence of bacterial cells appears to be associated with delayed HAP precipitation, changes in the lattice parameters, and reduced incorporation of trace elements as compared to cell-free systems. Schemes to remediate groundwater contaminated with trace metals that are based on enhanced phosphate mineral precipitation may need to account for these phenomena, particularly if the remediation approach relies on enhancement of in situ microbial populations.     

Assessment of soil erosion in a tropical mountain river basin of the southern Western Ghats,India using RUSLE and GIS

Revised Universal Soil Loss Equation(RUSLE) model coupled with transport limited sediment delivery(TLSD) function was used to predict the longtime average annual soil loss, and to identify the critical erosion-/deposition-prone areas in a tropical mountain river basin, viz., Muthirapuzha River Basin(MRB; area=271.75 km~2), in the southern Western Ghats, India. Mean gross soil erosion in MRB is 14.36 t ha~(-1) yr~(-1), whereas mean net soil erosion(i.e., gross erosion-deposition) is only 3.60 t ha~(-1) yr~(-1)(i.e., roughly 25% of the gross erosion). Majority of the basin area(~86%) experiences only slight erosion(5 t ha~(-1) yr~(-1)), and nearly 3% of the area functions as depositional environment for the eroded sediments(e.g., the terraces of stream reaches, the gentle plains as well as the foot slopes of the plateau scarps and the terrain with concordant summits). Although mean gross soil erosion rates in the natural vegetation belts are relatively higher, compared to agriculture, settlement/built-up areas and tea plantation, the sediment transport efficiency in agricultural areas and tea plantation is significantly high,reflecting the role of human activities on accelerated soil erosion. In MRB, on a mean basis, 0.42 t of soil organic carbon(SOC) content is being eroded per hectare annually, and SOC loss from the 4th order subbasins shows considerable differences, mainly due to the spatial variability in the gross soil erosion rates among the sub-basins. The quantitative results, on soil erosion and deposition, modelled using RUSLE and TLSD, are expected to be beneficial while formulating comprehensive land management strategies for reducing the extent of soil degradation in tropical mountain river basins.     

Mars: Experimental study of albedo changes caused by dust fallout

An experimental study was undertaken to determine how the spectral and photometric properties of representative Martian areas are affected by fallout of atmospheric dust suspended during dust forms. A laboratory apparatus was used to simulate the uniform fallout and deposition of particles 1 to 5 μm in diameter. Spectral measurements from 0.4- to 1.2-μm wavelengths and photometric measurements at several wavelengths were made for a number of Mars-analog materials before and after deposition of 6 × 10^?5 to 1.5 × 10^?3 g/cm² of simulated fallout. These results indicate that the spectral and photometric properties of Martian regions can be affected significantly even by minute amounts of fallout. For instance, the reflectance at 0.56 μm of an average dark area will increase by 35% after deposition of only 9 × 10^?5 g/cm², and by 70% after deposition of 1.5 × 10^?4 g/cm². Thus the fallout from even one dust storm season (～2 × 10^?3 g/cm²) is sufficient to change significantly the spectral and photometric characteristics of the substrate material, if the fallout were ubiquitous over the surface and if no competing processes of dust removal from surface grains occured.     

Orbital-scale record of the late Cenomanian–Turonian oceanic anoxic event (OAE-2) in the Tarfaya Basin (Morocco)

High sedimentation rates (up to 12 cm/kyear) of laminated organic carbon-rich biogenic limestones in the Tarfaya Basin provide an unusually high (millennial) resolution record of the late Cenomanian oceanic anoxic event (OAE-2). The global positive carbon-isotope excursion across the Cenomanian–Turonian corresponds to 11 light/dark sedimentary cycles. We interpret these cycles as a response to orbital obliquity variation and estimate the duration of the complete excursion as 440 kyear or one long eccentricity cycle. On this timescale, the main increase in ¹³C values occurred over a short time interval of less than 20 kyear in the late Cenomanian and reached a first maximum approximately 15 kyear prior to the bulk (mainly coccoliths) ¹⁸O-derived sea surface maximum temperature that occurs coeval to the extinction of Rotalipora cushmani. Organic carbon-accumulation rates follow obliquity cycles, reaching a maximum approximately 10 kyear after the last occurrence of R. cushmani, then slowly decreasing during the early Turonian. Thus, the maximum temperature and the maximum organic carbon accumulation in the Tarfaya Basin lagged by at least 15 kyear behind the global carbon-isotope shift and a proposed reduction of atmospheric CO₂ content. The climate change across the Cenomanian/Turonian boundary probably occurred independent of CO₂ levels and may have been controlled by different greenhouse gases (water vapour and methane) and changes in ocean circulation (i.e., opening of the Equatorial Atlantic gateway)     

Space–time foam and cosmic-ray interactions

It has been proposed that propagation of cosmic-rays at extreme-energy may be sensitive to Lorentz-violating metric fluctuations (“foam”). We investigate the changes in interaction thresholds for cosmic-rays and gamma-rays interacting on the CMB and IR backgrounds, for a class of stochastic models of space–time foam. The strength of the foam is characterized by the factor (E/M_P)^a, where a is a phenomenological suppression parameter. We find that there exists a critical value of a (dependent on the particular reaction: a_crit3 for cosmic-rays, 1 for gamma-rays), below which the threshold energy can only be lowered, and above which the threshold energy may be raised, but at most by a factor of two. Thus, it does not appear possible in this class of models to extend cosmic-ray spectra significantly beyond their classical absorption energies. However, the lower thresholds resulting from foam may have signatures in the cosmic-ray spectrum. In the context of this foam model, we find that cosmic-ray energies cannot exceed the fundamental Planck scale, and so set a lower bound of 10⁸ TeV for the scale of gravity. We also find that suppression of p→pπ⁰ and γ→e⁻e⁺ “decays” favors values aa_crit. Finally, we comment on the apparent non-conservation of particle energy–momentum, and speculate on its re-emergence as dark energy in the foamy vacuum.