Carbon-Nitrogen-Phosphorus Cyclingin Tomales Bay, California

Tomales Bay, California, has been the site oflong-term study of carbon-nitrogen-phospho-rus fluxes in the coastal zone. It has also one of severalcoastal sites being used for comparison of C-N-Pbiogeochemical fluxes. The site releases phosphorusand consumes dissolved nitrogen. It also producesdissolved inorganic carbon, mostly as elevatedalkalinity. The overall interpretation placed on thebiogeochemical fluxes is as follows. The system is netheterotrophic; that is, it consumes more organicmatter than it produces. A pathway of consumption thatis of particular importance to the nitrogen cycle isdenitrification. The combination of net heterotrophyand denitrification is the simultaneous release ofdissolved inorganic phosphorus and the uptake ofdissolved inorganic nitrogen. Much of the dissolvedinorganic carbon released during the net heterotrophyis bound in alkalinity, apparently the result ofsulfate reduction.Because this work can be traced by to the trainingthat one of the authors (SVS) received from KeithChave, it is appropriate to present a summary of theTomales Bay research in memory of Keith.     

Electrogeochemical sampling with

 Eruptions from Ruapehu Volcano on 11 and 14 October 1995 and 17 June 1996 distributed at least 36×10⁶ m³ of sulphur(S)-rich tephra over the central and eastern North Island of New Zealand. The tephras added between 30–1500 kg ha^–1 S to at least 25 000 km² of land in primary production. Smaller but beneficial amounts of selenium (Se) and in some areas potassium and magnesium were also supplied. Addition of S to the soils in the form of sulphate and elemental S resulted in a drop in soil pH and an increase in pasture S contents within seven weeks of the eruptions. The soils affected by the tephra are naturally low in S and Se, but following the eruptions S was not required in fertilizer applications in many areas. The strongest and longest lasting effects of S and Se deposition were in high anion-retention soils particularly Hapludands (moist, moderately weathered soils, derived from volcanic ash). Soluble fluorine concentrations within the tephras were low compared to historic Icelandic and Chilean examples. However, pastoral livestock deaths were apparently caused by fluorosis in addition to starvation when tephra covered feed. The Ruapehu tephra contained very low concentrations of other soluble toxic elements. Received: 17 January 1997 · Accepted: 31 March 1997     

Agronomic impact of tephra fallout from the 1995 and 1996 Ruapehu Volcano eruptions, New Zealand

 Eruptions from Ruapehu Volcano on 11 and 14 October 1995 and 17 June 1996 distributed at least 36×10⁶ m³ of sulphur(S)-rich tephra over the central and eastern North Island of New Zealand. The tephras added between 30–1500 kg ha^–1 S to at least 25 000 km² of land in primary production. Smaller but beneficial amounts of selenium (Se) and in some areas potassium and magnesium were also supplied. Addition of S to the soils in the form of sulphate and elemental S resulted in a drop in soil pH and an increase in pasture S contents within seven weeks of the eruptions. The soils affected by the tephra are naturally low in S and Se, but following the eruptions S was not required in fertilizer applications in many areas. The strongest and longest lasting effects of S and Se deposition were in high anion-retention soils particularly Hapludands (moist, moderately weathered soils, derived from volcanic ash). Soluble fluorine concentrations within the tephras were low compared to historic Icelandic and Chilean examples. However, pastoral livestock deaths were apparently caused by fluorosis in addition to starvation when tephra covered feed. The Ruapehu tephra contained very low concentrations of other soluble toxic elements. Received: 17 January 1997 · Accepted: 31 March 1997     

Methane distribution and cycling in Tomales Bay, California

Cycling of methane (CH₄) in Tomales Bay, a 28-km² temperature estuary in northern California with relatively low inputs of organic carbon, was studied over a 1-yr period. Water column CH₄ concentrations showed spatial and temporal variability (range=8–100 nM), and were supersaturated with respect to the atmosphere by a factor of 2–37. Rates of net water column CH₄ production-oxidation were determined by in situ experiments, and were not found to be significantly different from zero. Fluxes across the sediment-water interface, determined by direct measurement using benthic chambers, varied from ?0.1 μmol m^?2 d^?1 to +16 μmol m^?2 d^?1 (positive fluxes into water). Methane concentrations in the two perennial creeks feeding the bay varied annually (140–950 nM); these creeks were a significant CH₄ source to the bay during winter. In addition, mass-balance calculations indicate a significant additional inter CH₄ source, which is hypothesized to result from storm-related runoff from dairy farms adjacent to the bay. Systemwide CH₄ budgets of the 16-km² inner bay indicate benthic production (110 mol d^?1) and atmospheric evasion (110 mol d^?1) dominated during summer, while atmospheric evasion (160 mol d^?1) and runoff from dairy farms (90 mol d^?1) dominated during winter.     

Molecular Outflows from High-Mass Protostars

The youngest protostars are obscured from direct view by a high column of molecular gas. Nevertheless, their presence is betrayed through spectacular infrared outflows. I demonstrate here that infrared spectroscopy has the potential to reveal a remarkable variety of details concerning the underlying physics. Near-infrared spectroscopic analyses of the OMC-1, DR 21 & Cepheus A outflows are discussed here. Molecular hydrogen is vibrationally excited by collisions in shock waves. In OMC-1, the ortho-para ratio has been mapped. The ratio is close to 3, suggesting efficient shock thermalisation. In DR 21, shocked (up to the first vibrational level) and fluorescent (higher v-levels) components have been successfully separated. In Cepheus A, non-LTE effects imply low densities. This revised version was published online in July 2006 with corrections to the Cover Date.     

A study of the 2.5–25 μm spectrum of H2O ice

We present new absorbance spectra of the 3-, 6- and 12-μm features of amorphous and crystalline H₂O ice obtained between 10 and 140 K. Three sets of measurements have been made. In series I, the ice film was initially deposited on to a CsI substrate at 10 K and successive spectra were then obtained at intermediate temperatures as the ice was warmed up to 140 K. The second set, series II, comprises spectra for ice films deposited and measured at temperatures between 10 and 140 K. In the third set of measurements, series III, spectra were obtained for an ice film deposited at 140 K and then at intermediate temperatures as the film was cooled down to 10 K. The series I and II results show that the ice undergoes an amorphous-to-crystalline phase transition in the 110–120 K range. The 3- and 12-μm bands have similar trends in full width at half-maximum (FWHM) and opposite peak wavelength shifts. The temperature behaviour of the 6-μm band is different, as no clear phase transition temperature can be discerned from its FWHM and peak wavelength position data. In the series III spectra the peak wavelength positions and FWHM of the three bands remain relatively constant, thus demonstrating the stability of the crystalline phase against thermal cycling. A comparison between the laboratory results and astronomical spectra suggests that the identification of the librational band of H₂O ice in OH 231.8 + 4.2 may be incorrect.     

ISO observations of molecular hydrogen in the DR 21 bipolar outflow

We demonstrate that a wide range of molecular hydrogen excitation can be observed in protostellar outflows at wavelengths in excess of 5 μm. Cold H₂ in DR 21 is detected through the pure rotational transitions in the ground vibrational level (0–0). Hot H₂ is detected in pure rotational transitions within higher vibrational levels (1–1, 1–2, etc.). Although this emission is relatively weak, we have detected two 1–1 lines in the DR 21 outflow with the ISO SWS instrument. We thus investigate molecular excitation over energy levels corresponding to the temperature range 1015–15 722 K, without the uncertainty introduced by differential extinction when employing near-infrared data.
This gas is thermally excited. We uncover a rather low H₂ excitation in the DR 21 West Peak. The line emission cannot be produced from single C-shocks or J-shocks; a range of shock strengths is required. This suggests that bow shocks and/or bow-generated supersonic turbulence is responsible. We are able to distinguish this shock-excited gas from the fluoresced gas detected in the K band, providing support for the dual-excitation model of Fernandes, Brand & Burton.     

A textbook case of bow shock entrainment in a YSO outflow

Near-infrared images in H₂ line emission and submillimetre maps in CO J  = 3–2 emission illustrate the remarkable association between a molecular bow shock and the redshifted molecular outflow lobe in W75N. The flow lobe fits perfectly into the wake of the bow, as one would expect if the lobe represented swept-up gas. Indeed, these observations strongly support the 'bow shock' entrainment scenario for molecular outflows driven by young stars.   The characteristics of the bow shock and CO outflow lobe are compared with those of numerical simulations of jet-driven flows. These models successfully reproduce the bulge and limb-brightening in the CO outflow, although the model H₂ bow exhibits more structure extending back along the flow axis. We also find that the size of the flow, the high mass fraction in the flow at low outflow velocities (low γ values) and the high CO/H₂ luminosity ratio indicate that the system is evolved. We also predict a correlation, in evolved systems, between outflow age and the CO/H₂ luminosity ratio.