The impact of the nitrogen-to-oxygen ratio on ionized nebula diagnostics based on [N ii] emission lines

We study the relation between nitrogen and oxygen abundances as a function of metallicity for a sample of emission-line objects for which a direct measurement of the metallicity has been possible. This sample is representative of the very different conditions in ionization and chemical enrichment that we can find in the Universe. We first construct the N/O versus O/H ratio diagram, and discuss its large dispersion at all metallicity regimes. Using the same sample and a large grid of photoionization models covering very different values of the N/O ratio, we then study the most widely used strong-line calibrators of metallicity based on [N  ii ] emission lines, such as N2 and O3N2. We demonstrate that these parameters underestimate the metallicity at low N/O ratios and vice versa. We also investigate the effect of the N/O ratio on different diagnostic diagrams used to discriminate narrow-line active galactic nuclei from star-forming regions, such as the [O  iii ]/Hβ versus [N  ii ]/Hα, and show that a large fraction of the galaxies catalogued as composite in this diagram can be, in fact, star-forming galaxies with a high value of the N/O ratio. Finally, using strong-line methods sensitive to the N/O abundance ratio, like N2O2 and N2S2, we investigate the relation between this ratio and the stellar mass for the galaxies of the Sloan Digital Sky Survey. We find, as in the case of the mass–metallicity relation, a correlation between these two quantities and a flattening of the relation for the most massive galaxies, which could be a consequence of the enhancement of the dispersion of N/O ratio in the high-metallicity regime.     

The Meteoritical Bulletin,No. 96, September 2009

Abstract— The Meteoritical Bulletin No. 96 contains a total of 1590 newly approved meteorite names with their relevant data. These include 12 from specific locations within Africa, 76 from northwest Africa, 9 from the Americas, 13 from Asia, 1 from Australia, 2 from Europe, 950 from Antarctica recovered by the Chinese Antarctic Research Expedition (CHINARE), and 527 from the American Antarctic program (ANSMET). Among these meteorites are 4 falls, Almahata Sitta (Sudan), Sulagiri (India), Ash Creek (United States), and Maribo (Denmark). Almahata Sitta is an anomalous ureilite and is debris from asteroid 2008 TC3 and Maribo is a CM2 chondrite. Other highlights include a lunar meteorite, a CM1 chondrite, and an anomalous IVA iron.     

Integrated estimates of global terrestrial carbon sequestration

Assessing the contribution of terrestrial carbon sequestration to climate change mitigation requires integration across scientific and disciplinary boundaries. A comprehensive analysis incorporating ecologic, geographic and economic data was used to develop terrestrial carbon sequestration estimates for agricultural soil carbon, reforestation and pasture management. These estimates were applied in the MiniCAM integrated assessment model to evaluate mitigation strategies within policy and technology scenarios aimed at achieving atmospheric greenhouse gas stabilization by 2100. Terrestrial sequestration reaches a peak rate of 0.5–0.7 GtC yr⁻¹ in mid-century with contributions from agricultural soils (0.21 GtC yr⁻¹), reforestation (0.31 GtC yr⁻¹) and pasture (0.15 GtC yr⁻¹). Sequestration rates vary over time and with different technology and policy scenarios. The combined contribution of terrestrial sequestration over the next century ranges from 23 to 41 GtC.     

Influence of dissolved organic carbon on photochemically mediated cycling of hydrogen peroxide in rainwater

The influence of sunlight and dissolved organic carbon (DOC) on the photochemically mediated cycling of hydrogen peroxide (H₂O₂) was investigated in rainwater samples collected in Wilmington, North Carolina USA. Upon exposure to simulated sunlight 14 of 19 authentic rainwater samples exhibited significant decreases in H₂O₂. The concentration of hydrogen peroxide did not change significantly in organic-free synthetic rainwater spiked with H₂O₂ in the light or in dark controls suggesting that the loss was not due to direct photolysis or dark mediated reactions. There was a significant correlation between pseudo-first order rate constants of H₂O₂ decay and initial H₂O₂ concentrations. There was also a significant correlation between the rate constant and the abundance of DOC suggesting that rainwater organic carbon plays an important role during photolytic decay either via direct reaction or indirectly through production of peroxide reactive species or scavenging of peroxide generating radicals. Several rain samples exhibited an initial increase in H₂O₂ during the first 2 h of irradiation. These increases were generally small and most likely do not represent a significant input of peroxide in precipitation. The photo-induced destruction of H₂O₂ is important because it may partly explain the late afternoon decrease of peroxide concentrations observed in earlier field studies and the substantial under saturation (<10%) of this oxidant in rainwater compared with gas phase concentrations.     

An architecture for government action on adaptation to climate change. An editorial comment

An architecture of government adaptation programs is presented. Components include leadership, institutional organization, stakeholder involvement, climate change information, appropriate use of decision analysis techniques, explicit consideration of barriers to adaptation, funding for adaptation, technology development and diffusion, and adaptation research. This architecture is a useful heuristic for identifying, evaluating, and reevaluating the needs of decision makers as they improve management of climate-sensitive resources in a changing environment.     

Abundance and fractionation of Al,Fe and trace metals following tidal inundation of a tropical acid sulfate soil

Tidal inundation was restored to a severely degraded tropical acid sulfate soil landscape and subsequent changes in the abundance and fractionation of Al, Fe and selected trace metals were investigated. After 5 a of regular tidal inundation there were large decreases in water-soluble and exchangeable Al fractions within former sulfuric horizons. This was strongly associated with decreased soil acidity and increases in pH, suggesting pH-dependent immobilisation of Al via precipitation as poorly soluble phases. The water-soluble fractions of Fe, Zn, Ni and Mn also decreased. However, there was substantial enrichment (2–5×) of the reactive Fe fraction (Fe_R; 1 M HCl extractable) near the soil surface, plus a closely corresponding enrichment of 1 M HCl extractable Cr, Zn, Ni and Mn. Surficial accumulations of Fe(III) minerals in the inter-tidal zone were poorly crystalline (up to 38% Fe_R) and comprised mainly of schwertmannite (Fe₈O₈(OH)₆SO₄) with minor quantities of goethite (α-FeOOH) and lepidocrocite (γ-FeOOH). These Fe (III) mineral accumulations provide an effective substrate for the adsorption/co-precipitation and accumulation of trace metals. Arsenic displayed contrary behaviour to trace metals with peak concentrations (∼60 μg g⁻¹) near the redox minima. Changes in the abundance and fractionation of the various metals can be primarily explained by the shift in the geochemical regime from oxic–acidic to reducing-circumneutral conditions, combined with the enrichment of reactive Fe near the soil surface. Whilst increasing sequestration of trace metals via sulfidisation is likely to occur over the long-term, the current abundance of reactive Fe near the sediment–water interface favours a dynamic environment with respect to metals in the tidally inundated areas.     

Insights into silicic melt generation using plagioclase, quartz and melt inclusions from the caldera-forming Rotoiti eruption, Taupo volcanic zone, New Zealand

The Rotoiti (~120 km³) and Earthquake Flat (~10 km³) eruptions occurred in close succession from the Okataina Volcanic Centre at ~50 ka. While accessory mineral geochronology points to long periods of crystallization prior to eruption (10⁴–10⁵ years) and separate thermal histories for the magmas, little was known about the rates and processes of the final melt production and eruption. Crystal zoning patterns in plagioclase and quartz reveal the thermal and compositional history of the magmatic system leading up to the eruption. The dominant modal phase, plagioclase, displays considerable within-crystal zonation: An_37–74, ~40–227 ppm MgO, 45–227 ppm TiO₂, 416–910 ppm Sr and 168–1164 ppm Ba. Resorption horizons in the crystals are marked by sharp increases (10–30%) in Sr, MgO and X_An that reflect changes in melt composition and are consistent with open system processes. Melt inclusions display further evidence for open system behaviour, some are depleted in Sr and Ba relative to accompanying matrix glass not consistent with crystallization of modal assemblage. MI also display a wide range in XH₂O that is consistent with volatile fluxing. Quartz CL images reveal zoning that is truncated by resorption, and accompanied by abrupt increases in Ti concentration (30–80 ppm) that reflect temperature increases ~50–110°C. Diffusion across these resorption horizons is restricted to zones of <20 μm, suggesting most crystallization within the magma occurred in <2000 years. These episodes are brief compared to the longevity (10⁴–10⁵ year) of the crystal mush zones. All textural and compositional features observed within the quartz and plagioclase crystals are best explained by periodic mafic intrusions repeatedly melting parts of a crystal-rich zone and recharging the system with silicic melt. These periodic influxes of silicic melt would have accumulated to form the large volume of magma that fed the caldera-forming Rotoiti eruption.     

Meridional distribution of CH3C2H and C4H2 in Saturn’s stratosphere from CIRS/Cassini limb and nadir observations

Limb and nadir spectra acquired by Cassini/CIRS (Composite InfraRed Spectrometer) are analyzed in order to derive, for the first time, the meridional variations of diacetylene (C₄H₂) and methylacetylene (CH₃C₂H) mixing ratios in Saturn’s stratosphere, from 5 hPa up to 0.05 hPa and 80°S to 45°N. We find that the C₄H₂ and CH₃C₂H meridional distributions mimic that of acetylene (C₂H₂), exhibiting small-scale variations that are not present in photochemical model predictions. The most striking feature of the meridional distribution of both molecules is an asymmetry between mid-southern and mid-northern latitudes. The mid-southern latitudes are found depleted in hydrocarbons relative to their northern counterparts. In contrast, photochemical models predict similar abundances at north and south mid-latitudes. We favor a dynamical explanation for this asymmetry, with upwelling in the south and downwelling in the north, the latter coinciding with the region undergoing ring shadowing. The depletion in hydrocarbons at mid-southern latitudes could also result from chemical reactions with oxygen-bearing molecules.Poleward of 60°S, at 0.1 and 0.05 hPa, we find that the CH₃C₂H and C₄H₂ abundances increase dramatically. This behavior is in sharp contradiction with photochemical model predictions, which exhibit a strong decrease towards the south pole. Several processes could explain our observations, such as subsidence, a large vertical eddy diffusion coefficient at high altitudes, auroral chemistry that enhances CH₃C₂H and C₄H₂ production, or shielding from photolysis by aerosols or molecules produced from auroral chemistry. However, problems remain with all these hypotheses, including the lack of similar behavior at lower altitudes.Our derived mean mixing ratios at 0.5 hPa of (2.4 ± 0.3) × 10⁻¹⁰ for C₄H₂ and of (1.1 ± 0.3) × 10⁻⁹ for CH₃C₂H are compatible with the analysis of global-average ISO observations performed by Moses et al. (Moses, J.I., Bézard, B., Lellouch, E., Gladstone, G.R., Feuchtgruber, H., Allen, M. [2000a]. Icarus 143, 244-298). Finally, we provide values for the ratios [CH₃C₂H]/[C₂H₂] and [C₄H₂]/[C₂H₂] that can constrain the coupled chemistry of these hydrocarbons.     

What do near-term observations tell us about long-term developments in greenhouse gas emissions?

Long-term scenarios developed by integrated assessment models are used in climate research to provide an indication of plausible long-term emissions of greenhouse gases and other radiatively active substances based on developments in the global energy system, land-use and the emissions associated with these systems. The phenomena that determine these long-term developments (several decades or even centuries) are very different than those that operate on a shorter time-scales (a few years). Nevertheless, in the literature, we still often find direct comparisons between short-term observations and long-term developments that do not take into account the differing dynamics over these time scales. In this letter, we discuss some of the differences between the factors that operate in the short term and those that operate in the long term. We use long-term historical emissions trends to show that short-term observations are very poor indicators of long-term future emissions developments. Based on this, we conclude that the performance of long-term scenarios should be evaluated against the appropriate, corresponding long-term variables and trends. The research community may facilitate this by developing appropriate data sets and protocols that can be used to test the performance of long-term scenarios and the models that produce them.