Les sondages électromagnétiques temporels comme outil de reconnaissance du gisement phosphaté de Sidi Chennane (Maroc) : apport à la résolution d'un problème d'exploitation

Exploitation of the phosphatic layers in Sidi Chennane deposit (Morocco) collides frequently with problems bound to the existence, in the phosphatic series, of sterile bodies qualified as derangements. Our study shows that these bodies, masked by the Quaternary cover can be mapped using the Time-Domain ElectroMagnetic Soundings method (TDEM). It is based on the acquisition and the interpretation of a series of tests carried out above a visible derangement in an old trench of exploitation and on 2500 TDEM soundings carried out in a virgin area of the deposit. The article concerns to the analysis of the results and of the proceeding for a possible large geophysics survey. To cite this article: A. Kchikach et al., C. R. Geoscience 338 (2006).     

δ13C variation of soil organic matter as an indicator of vegetation change during the Holocene in central Cameroon

In order to better understand the dynamics of the forest–savanna mosaic from central Cameroon, we analyzed ¹³C and ¹⁴C profiles of six oxisols: two under forests and four under savannas. The δ¹³C soil profiles collected in the forests indicate that these environments are stable at least since the mid-Holocene, whereas the areas currently covered by savannas were formerly occupied by more forested vegetations. The ¹⁴C dating of organic matter indicate that the late extension of the savannas in central Cameroon date from the Late Holocene, starting from 4000–3500 ¹⁴C yr BP.     

Were the 2.1-Gyr fossil colonial organisms discovered in the Francevillian basin (Palaeoproterozoic,Gabon) buried by turbidites?

The Francevillian series (Gabon) in which the Earth's oldest large colonial organisms were recently discovered (El Albani et al., 2010) were deposited 2 Gyr ago. These series are usually interpreted as a fining-upward basin-fill sequence composed by five superimposed lithological terms noted FA to FE. New studies initiated by AREVA, allowed new data to be collected on the southwestern edge of the Francevillian basin, particularly on newly excavated outcrops. Facies interpretations show that the Poubara sandstones and associated shales and black shales (upper part of FB,FB2a), correspond to turbidites deposited on an upper slope rather than one a shelf, submitted to tidal currents or storm wave action. These new interpretations based on facies association, sedimentary geometries, and basin evolution show that the depositional environment could be a turbidite lobe set at a palaeobathymetry deeper than 200 m.     

Producing time series of river water height by means of satellite radar altimetry—a comparative study

Abstract

Satellite radar altimetry is complementary to in situ limnimetric surveys as a means of estimating the water height of large rivers, lakes and flood plains. Production of water height time series by satellite radar altimetry technology requires first the selection of radar ground target locations corresponding to water body surfaces under study, i.e. the definition of “virtual limnimetric stations”. We propose to investigate qualitative and quantitative differences between three representative virtual station creation methodologies: (a) a fully manual method, (b) a semi-automatic method based on a land cover characterization that allows the water body surface under study to be located; and (c) an original fully automatic procedure that exploits a digital elevation model and an estimation of the river width. The results yielded by these three methods are comparable: maximum absolute magnitudes of water height differences being 0.46, 0.26 and 0.15 m for, respectively, 95, 90 and 80% of the water height values obtained. Moreover, more than 67% and 92% of time series jointly produced by the methods present root mean square differences lower than 20 and 50 cm, respectively. The results show that the fully automatic method developed herein provides as reliable results as the fully manual one. This opens the way to use of satellite radar altimetry for the generation of water height time series on a large scale, and considerably extends the applicability of satellite radar altimetry in hydrology.

Citation Roux, E., Santos da Silva, J., Vieira Getirana, A. C., Bonnet, M.-P., Calmant, S., Martinez, J.-M. & Seyler, F. (2010) Producing time series of river water height by means of satellite radar altimetry—comparative study. Hydrol. Sci. J. 55(1), 104–120.     

Bounding the time delay between high-energy neutrinos and gravitational-wave transients from gamma-ray bursts

We derive a conservative coincidence time window for joint searches of gravitational-wave (GW) transients and high-energy neutrinos (HENs, with energies ?100 GeV), emitted by gamma-ray bursts (GRBs). The last are among the most interesting astrophysical sources for coincident detections with current and near-future detectors. We take into account a broad range of emission mechanisms. We take the upper limit of GRB durations as the 95% quantile of the T₉₀’s of GRBs observed by BATSE, obtaining a GRB duration upper limit of ∼150 s. Using published results on high-energy (>100 MeV) photon light curves for 8 GRBs detected by Fermi LAT, we verify that most high-energy photons are expected to be observed within the first ∼150 s of the GRB. Taking into account the breakout-time of the relativistic jet produced by the central engine, we allow GW and HEN emission to begin up to 100 s before the onset of observable gamma photon production. Using published precursor time differences, we calculate a time upper bound for precursor activity, obtaining that 95% of precursors occur within ∼250 s prior to the onset of the GRB. Taking the above different processes into account, we arrive at a time window of t_HEN − t_GW ∈ [−500 s, +500 s]. Considering the above processes, an upper bound can also be determined for the expected time window of GW and/or HEN signals coincident with a detected GRB, t_GW − t_GRB ≈ t_HEN − t_GRB ∈ [−350 s, +150 s]. These upper bounds can be used to limit the coincidence time window in multimessenger searches, as well as aiding the interpretation of the times of arrival of measured signals.     

Geodynamic and climate controls in the formation of Mio–Pliocene world-class oxidized cobalt and manganese ores in the Katanga province, DR Congo

The Katanga province, Democratic Republic of Congo, hosts world-class cobalt deposits accounting for ~50% of the world reserves. They originated from sediment-hosted stratiform copper and cobalt sulfide deposits within Neoproterozoic metasedimentary rocks. Heterogenite, the main oxidized cobalt mineral, is concentrated as “cobalt caps” along the top of silicified dolomite inselbergs. The supergene cobalt enrichment process is part of a regional process of residual ore formation that also forms world-class “manganese cap” deposits in western Katanga, i.e., the “black earths” that are exploited by both industrial and artisanal mining. Here, we provide constraints on the genesis and the timing of these deposits. Ar–Ar analyses of oxidized Mn ore and in situ U–Pb SIMS measurements of heterogenite yield Mio–Pliocene ages. The Ar–Ar ages suggest a multi-phase process, starting in the Late Miocene (10–5 Ma), when the metal-rich substratum was exposed to the action of meteoric fluids, due to major regional uplift. Further oxidation took place in the Pliocene (3.7–2.3 Ma) and formed most of the observed deposits under humid conditions: Co- and Mn-caps on metal-rich substrata, and coeval Fe laterites on barren areas. These deposits formed prior to the regional shift toward more arid conditions in Central Africa. Arid conditions still prevailed during the Quaternary and resulted in erosion and valley incision, which dismantled the metal-bearing caps and led to ore accumulation in valleys and along foot slopes.     

Crystal chemistry of suspended matter in a tropical hydrosystem, Nyong basin (Cameroon, Africa)

Suspended matter (SM) from the Nyong basin (Cameroon, Africa), a tropical watershed, was collected by tangential flow ultrafiltration to separate particulate (>0.45 μm) and colloidal (<0.45 μm; >20 kDa) fractions. In this basin, two distinctive systems in a selected small catchment (Nsimi–Zoétélé) of the Nyong river basin have been considered: (i) colourless water (groundwater and spring) with a low suspended load (<3 mg/l) and a low total organic carbon content (TOC<1 mg/l) and (ii) coloured water (Mengong brook and Nyong river), which is organic rich (TOC>10 mg/l) and contains higher amounts of SM (10–20 mg/l) than the colourless water. Freeze-dried samples of SM have been analysed by X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier-transform infrared spectroscopy (FTIR), electron paramagnetic resonance spectroscopy (EPR), and visible diffuse reflectance spectroscopy (DRS).

Colourless water mainly contains mineral phases, such as poorly ordered kaolinite, plus quartz and goethite in the particulate fraction, and euhedral kaolinite plus amorphous iron oxyhydroxides in the colloidal fraction. In contrast, the SM in coloured water is mainly organic in nature. The mineral phases in the particulate fraction are similar to those from clear water, but with additional phytoliths and diatom frustules composed of biogenic opal. In the colloidal fraction, complexation of Fe³⁺ and Mn²⁺ with organic matter is evidenced by EPR, together with significant occurrence of Fe oxyhydroxides associated with organic matter.

The sites of Al, Si, Fe, Mn in colloidal fractions derived from spectroscopic analyses are discussed with reference to chemical analyses performed by inductively coupled plasma mass spectrometry. Most of the observed solid phases or species correspond to those expected from published thermodynamic calculations for the same hydrosystem, except the colloidal iron oxyhydroxides in the coloured water. The presence of such iron phases is emphasised since they are expected to have large sorption capacities for numerous trace elements.

The crystal chemistry of SM is used to discuss the origin of the mineral particles transported from the soil to the main rivers in terms of mechanical and chemical erosion processes.     

In Situ Multi-Element Analysis of the Mount Pinatubo Quartz-Hosted Melt Inclusions by NIR Femtosecond Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry

Microscopic melt inclusions found in magmatic minerals are undoubtedly one of the most important sources of information on the chemical composition of melts. This paper reports on the successful application of near-infrared (NIR) femtosecond laser ablation (LA) - inductively coupled plasma-mass spectrometry to in situ determination of incompatible trace elements (Li, Rb, Sr, Y, Zr, Nb, Cs, Ba, REE, Ta, Th, U) and ore metals (As, Mo, Pb) in individual melt inclusions hosted in quartz from the Mount Pinatubo dacites, Philippines. The determined elements cover a concentration range of five orders of magnitude. Femtosecond LA-ICP-MS analyses of twenty-eight individual melt inclusions demonstrate the efficiency of the microanalytical technique and suggests a spectacular homogeneity of the entrapped melt, at least with respect to the following incompatible trace elements: Rb, Sr, Nb, Cs, Ba, La, Ce, Pr, Nd, Pb, Th. The analytical precision (1s) for Na, Ca, Rb, Sr, Y, Nb, Ba and LREE ranged from 3 to 20%. Comparison of trace element concentrations in Mt. Pinatubo melt inclusions determined by femtosecond LA-ICP-MS with those of melt inclusions previously analysed by secondary ion mass spectrometry analysis (SIMS) and those of matrix glasses previously determined by nanosecond LA-ICP-MS showed an agreement typically within 30–40%. The homogeneity of trace element concentrations of the Mt. Pinatubo melt inclusions and the matrix glasses is consistent with the melt inclusion origin as homogeneous rhyolitic melt that was trapped in quartz phenocrysts at the final crystallisation stages of the host adakite (dacite) magma.     

Zircon U–Pb geochronology of Ordovician magmatism in the polycyclic Ruitor Massif (Internal W Alps)

Among the Middle Penninic basements of the Internal NW-Alps, the Ruitor massif shows the best preserved remnants of pre-Permian metamorphic rocks. Their Barrovian-type mineral associations are somewhat masked by the greenschist to blueschist Alpine metamorphism of Tertiary age. Four Ruitor gneisses have been analysed, showing geochemical characters of granitoids from orogenic zones. Zircon morphology also suggests magmatic protoliths and a crustal source; some of the morphological zircon types suggest anatectic granites. The first U-Pb ages on zircon for this massif have been obtained concurrently through conventional multigrain and ion microprobe dating. Two metavolcanic rocks at 471LJ and 468ᆪ Ma could be slightly older than the porphyritic augen gneisses at 465ᆟ and 460lj Ma. Regional data from the other Internal basement massifs suggest that the Variscan event is poorly recorded, except in Ruitor-type units. Ruitor and Sapey gneisses belonged to the same unit (Nappe des Pontis), which was affected by a 480-450-Ma event including volcanism and anatexis and ended with a late calc-alkaline granite emplacement at 460-450 Ma. The distribution of Variscan basement units roughly parallels Alpine zonation.