Biogeochemistry and carbon mass balance of a coccolithophore bloom in the northern Bay of Biscay (June 2006)

Primary production (PP), calcification (CAL), bacterial production (BP) and dark community respiration (DCR) were measured along with a set of various biogeochemical variables, in early June 2006, at several stations at the shelf break of the northern Bay of Biscay. The cruise was carried out after the main spring diatom bloom that, based on the analysis of a time-series of remotely sensed chlorophyll-a (Chl-a), peaked in mid-April. Remotely sensed sea surface temperature (SST) indicated the occurrence of enhanced vertical mixing (due to internal tides) at the continental slope, while adjacent waters on the continental shelf were stratified, as confirmed by vertical profiles of temperature acquired during the cruise. The surface layer of the stratified water masses (on the continental shelf) was depleted of inorganic nutrients. Dissolved silicate (DSi) levels probably did not allow significant diatom development. We hypothesize that mixing at the continental slope allowed the injection of inorganic nutrients that triggered the blooming of mixed phytoplanktonic communities dominated by coccolithophores (Emiliania huxleyi) that were favoured with regards to diatoms due to the low DSi levels. Based on this conceptual frame, we used an indicator of vertical stratification to classify the different sampled stations, and to reconstruct the possible evolution of the bloom from the onset at the continental slope (triggered by vertical mixing) through its development as the water mass was advected on-shelf and stratified. We also established a carbon mass balance at each station by integrating in the photic layer PP, CAL and DCR. This allowed computation at each station of the contribution of PP, CAL and DCR to CO₂ fluxes in the photic layer, and how they changed from one station to another along the sequence of bloom development (as traced by the stratification indicator). This also showed a shift from net autotrophy to net heterotrophy as the water mass aged (stratified), and suggested the importance of extracellular production of carbon to sustain the bacterial demand in the photic and aphotic layers.     

Pliocene to Recent shallow-water contourite deposits on the shelf and shelf edge off south-western Mallorca, Spain

This paper presents evidence for the presence of shallow-water contourite drifts on the south-western shelf and shelf edge off Mallorca in water depths between 150 and 275?m. These are called the Mallorca contourite depositional system (CDS). The elongate-mounded shallow-water CDS in this area is ascribed to an offshoot of the Balearic Current, which flows north to south through the Mallorca Channel as part of the overall thermohaline circulation in the Mediterranean Sea. Drift geometry suggests that the north?Csouth current is deflected into an east?Cwest flow pattern by interaction with a marked seafloor bathymetry, associated with major fault displacement. Four seismic units separated by three prominent discontinuities can be identified. The three internal discontinuities are correlated to large-scale basin-wide events: the lower Pliocene revolution (4.2?Ma), the upper Pliocene revolution (2.4?Ma) and the mid-Pleistocene revolution (0.9?Ma). The Plio-Quaternary succession has been deposited on top of a Miocene reef, which serves as an acoustic basement and is affected by a large fault, offsetting the basement on average by 150?m. Marked erosional features throughout and further incision of the Sant Jordi Channel along the basement fault in the Pleistocene deposits indicate stronger currents in this period. The Pleistocene deposits also show a pronounced cyclicity, which is tentatively ascribed to climatic variations and the effects of eustatic sea-level fluctuation over the south-western Mallorca shelf at that time.     

Seafloor change detection using multibeam echosounder backscatter: case study on the Belgian part of the North Sea

To characterize seafloor substrate type, seabed mapping and particularly multibeam echosounding are increasingly used. Yet, the utilisation of repetitive MBES-borne backscatter surveys to monitor the environmental status of the seafloor remains limited. Often methodological frameworks are missing, and should comprise of a suite of change detection procedures, similarly to those developed in the terrestrial sciences. In this study, pre-, ensemble and post-classification approaches were tested on an eight km² study site within a Habitat Directive Area in the Belgian part of the North Sea. In this area, gravel beds with epifaunal assemblages were observed. Flourishing of the fauna is constrained by overtopping with sand or increased turbidity levels, which could result from anthropogenic activities. Monitoring of the gravel to sand ratio was hence put forward as an indicator of good environmental status. Seven acoustic surveys were undertaken from 2004 to 2015. The methods allowed quantifying temporal trends and patterns of change of the main substrate classes identified in the study area; namely fine to medium homogenous sand, medium sand with bioclastic detritus and medium to coarse sand with gravel. Results indicated that by considering the entire study area and the entire time series, the gravel to sand ratio fluctuated, but was overall stable. Nonetheless, when only the biodiversity hotspots were considered, net losses and a gradual trend, indicative of potential smothering, was captured by ensemble and post-classification approaches respectively. Additionally, a two-dimensional morphological analysis, based on the bathymetric data, suggested a loss of profile complexity from 2004 to 2015. Causal relationships with natural and anthropogenic stressors are yet to be established. The methodologies presented and discussed are repeatable and can be applied to broad-scale geographical extents given that broad-scale time series datasets become available.     

A dynamical solution of the triple asteroid system (45) Eugenia

We present the first dynamical solution of the triple asteroid system (45) Eugenia and its two moons Petit–Prince (diameter ∼ 7 km) and S/2004 (45) 1 (diameter ∼ 5 km). The two moons orbit at 1165 and 610 km from the primary, describing an almost-circular orbit (e ∼ 6 × 10⁻³ and e ∼ 7 × 10⁻² respectively). The system is quite different from the other known triple systems in the main belt since the inclinations of the moon orbits are sizeable (9° and 18° with respect to the equator of the primary respectively). No resonances, neither secular nor due to Lidov–Kozai mechanism, were detected in our dynamical solution, suggesting that these inclinations are not due to excitation modes between the primary and the moons. A 10-year evolution study shows that the orbits are slightly affected by perturbations from the Sun, and to a lesser extent by mutual interactions between the moons. The estimated J₂ of the primary is three times lower than the theoretical one, calculated assuming the shape of the primary and an homogeneous interior, possibly suggesting the importance of other gravitational harmonics.     

Chromium(III) — chromium(VI) interconversions in seawater

The stable form of dissolved chromium in oxygenated seawater is Cr(VI). But Cr(III)-species are also present at an analytically significant level. It is shown that Cr(III) is oxidized only slowly by dissolved oxygen, and that manganese oxide is a strong catalyst for such oxidation. However, the low oceanic concentration of suspended MnO₂ impedes the conclusion that the former process is quantitatively less important than the latter one. The distribution of dissolved chromium among Cr(VI)- and Cr(III)-species is probably kinetically controlled.     

ISO SWS Spectroscopy of WR 146 (WC6+O)

We have obtained ISO SWS spectroscopy of WR 146 (WC6+O) covering the wavelength range 2.6-20 μm. WC6 wind emission is observed in numerous lines of He II and C IV, as well as in the [Ne III] 15.5 μm line, but not in [Ne II] 12.81 or [Ne V] 14.32 μm. An analysis of these spectra (and complementary radio and optical data) yields for the WC6 star: v∞ = 2700 km s-1; M=2.6×10-5M⊙yr-1; C/He = 0.15; and a neon abundance bound of 3.4×10-3≤Ne/He≤6.8×10-3. The neon abundance is close to that predicted in stellar evolution models of WC stars. This revised version was published online in August 2006 with corrections to the Cover Date.     

Some geochemical controls on lead and barium concentrations in ferromanganese deposits

The Pb content of natural deep-sea ferromanganese deposits decreases with depth. This is commonly explained by assuming oxidation of Pb²⁺ and uptake as (Mn, Pb)O₂ in normally oxygenated shallow water, a process that is less likely to occur in deep water which is somewhat depleted in oxygen. This concept is discussed and rejected, both on theoretical grounds and based on experimental results of Pb²⁺ sorption by Mn oxides. Comparative sorption experiments on Mn oxides were carried out with Pb and Ba. It is shown that Pb is preferentially adsorbed by birnessite at $\text{pH}\text{? 4}$. The uptake ratio is, however, much lower than the relative enrichment factor in natural nodule material. Suggested explanations for this discrepancy are: influence of hydrostatic pressure and extent of hydrolysis of the cations at the pH of ocean water.     

Some oscillator strengths in the spectra of Ci,Oi, Sii,Caii and Srii

A number of wave functions for bound electrons have been calculated in scaled Thomas-Fermi ion potentials in order to evaluate some oscillator strengths and mean square radii. The results differ only slightly from those obtained by the well-known method of Bates and Damgaard. After that, the values of the oscillator strengths for the transition 4s4p in Sii have been evaluated in intermediate coupling, showing large differences with the LS-coupling results. These new values are supported by the fact that they show somewhat better agreement with observations, described earlier in this issue of Solar Physics by De Jager and Neven.     

Observations of a post-flare radio burst in X-rays

More than six hours after the two-ribbon flare of 21 May 1980, the hard X-ray spectrometer aboard the SMM imaged an extensive arch above the flare region which proved to be the lowest part of a stationary post-flare noise storm recorded at the same time at Culgoora. The X-ray arch extended over 3 or more arc minutes to a projected distance of 95 000 km, and its real altitude was most probably between 110 000 and 180 000 km. The mean electron density in the cloud was close to 10⁹ cm^–3 and its temperature stayed for many hours at a fairly constant value of about 6.5 × 10⁶ K. The bent crystal spectrometer aboard the SMM confirms that the arch emission was basically thermal. Variations in brightness and energy spectrum at one of the supposed footpoints of the arch seem to correlate in time with radio brightness suggesting that suprathermal particles from the radio noise regions dumped in variable quantities into the low corona and transition layer; these particles may have contributed to the population of the arch, after being trapped and thermalized. The arch extended along the H = 0 line thus apparently hindering any upward movement of the upper loops reconnected in the flare process. There is evidence from Culgoora that this obstacle may have been present above the flare since 15–30 min after its onset.