Determination of major and trace elements in European bottled mineral water — Analytical methods

A total of 1785 European bottled water samples were analyzed using standard laboratory methods. The bottled water samples were purchased in 2008 at supermarkets throughout 40 European countries. The samples were analyzed for 71 chemical parameters (As, Al, As, B, Ba, Be, Bi, Ca, Cd, Ce, Co, Cr, Cs, Cu, Dy, Er, Eu, Fe, Ga, Gd, Ge, Hf, Hg, Ho, I, K, La, Li, Lu, Mg, Mn, Mo, Na, Nb, Nd, Ni, Pb, Pr, Rb, Sb, Sc, Se, Sm, Sn, Sr, Ta, Tb, Te, Th, Ti, Tl, Tm, U, V, W, Y, Yb, Zn, Zr, Br⁻, HCO₃⁻, Cl⁻, F⁻, NH₄⁺, NO₂⁻, NO₃⁻, PO₄³⁻, SO₄²⁻, SiO₂, pH, and EC) by quadrupole inductively coupled emission spectroscopy (ICP-QMS, trace elements), inductively coupled plasma atomic emission spectroscopy (ICP-AES, major elements), ion chromatography (IC, anions), atomic fluorescence spectrometry (AFS, Hg), titration (alkalinity), photometric methods (NH₄⁺), potentiometric methods (pH), and conductometric methods (specific electrical conductivity, EC). A very strict quality control procedure was followed by analysing blanks, international reference materials, an internal project standard, and duplicate analyses, as well as by analysing 23 elements by both ICP-QMS and ICP-AES. Analysis of marketed bottled water from springs, wells or boreholes, apart from the evaluation of its quality with respect to inorganic elements, it may provide a cheap alternative to obtain a first impression about groundwater chemistry at the European scale.     

Changes in the chemistry of shallow groundwater related to the 2008 injection of CO2 at the ZERT field site, Bozeman, Montana

Approximately 300 kg/day of food-grade CO₂ was injected through a perforated pipe placed horizontally 2–2.3 m deep during July 9–August 7, 2008 at the MSU-ZERT field test to evaluate atmospheric and near-surface monitoring and detection techniques applicable to the subsurface storage and potential leakage of CO₂. As part of this multidisciplinary research project, 80 samples of water were collected from 10 shallow monitoring wells (1.5 or 3.0 m deep) installed 1–6 m from the injection pipe, at the southwestern end of the slotted section (zone VI), and from two distant monitoring wells. The samples were collected before, during, and following CO₂ injection. The main objective of study was to investigate changes in the concentrations of major, minor, and trace inorganic and organic compounds during and following CO₂ injection. The ultimate goals were (1) to better understand the potential of groundwater quality impacts related to CO₂ leakage from deep storage operations, (2) to develop geochemical tools that could provide early detection of CO₂ intrusion into underground sources of drinking water (USDW), and (3) to test the predictive capabilities of geochemical codes against field data. Field determinations showed rapid and systematic changes in pH (7.0–5.6), alkalinity (400–1,330 mg/l as HCO₃), and electrical conductance (600–1,800 μS/cm) following CO₂ injection in samples collected from the 1.5 m-deep wells. Laboratory results show major increases in the concentrations of Ca (90–240 mg/l), Mg (25–70 mg/l), Fe (5–1,200 ppb), and Mn (5–1,400 ppb) following CO₂ injection. These chemical changes could provide early detection of CO₂ leakage into shallow groundwater from deep storage operations. Dissolution of observed carbonate minerals and desorption-ion exchange resulting from lowered pH values following CO₂ injection are the likely geochemical processes responsible for the observed increases in the concentrations of solutes; concentrations generally decreased temporarily following four significant precipitation events. The DOC values obtained are 5 ± 2 mg/l, and the variations do not correlate with CO₂ injection. CO₂ injection, however, is responsible for detection of BTEX (e.g. benzene, 0–0.8 ppb), mobilization of metals, the lowered pH values, and increases in the concentrations of other solutes in groundwater. The trace metal and BTEX concentrations are all significantly below the maximum contaminant levels (MCLs). Sequential leaching of core samples is being carried out to investigate the source of metals and other solutes.     

Autonomous and rapid deployment of a compact taut-wire mooring

The deployment time of a taut-wire mooring is reduced to the time any transportation/hoisting device needs to put a payload at the sea surface. This is a matter of minutes rather than hours needed for deployment of long deep-ocean moorings in the regular way. It is achieved by extending the basic function of mooring parts to temporarily form a Launcher for Oceanographic Equipment and Instruments (LOEI). Full preparation of the mooring is done onshore where the instruments are prepared and programmed, and spooled onto the top-buoy together with the line. At sea, no other gear is required than a device that is able to lift a load of, say, 2000 kg, even for long deep-ocean moorings. The compact mooring method realizes considerable budget savings through deployments from non-research vessels and airborne transportation-deployment. Limitations lay in size and weight of the oceanographic instruments. We present a test-design shaped as a barbell and loaded with 940 m line and 3 current meters. Unfurling speed was maximally 2.3 m s⁻¹ and the descent speed amounted 1.2 m s⁻¹ until landing on the seabed. These speeds are comparable to those acquired during a conventional free-falling mooring deployment.     

AA Dor—An Eclipsing sdOB—Brown Dwarf Binary

AA Dor is an eclipsing, close, post common-envelope binary (PCEB) consisting of a sdOB primary star and an unseen secondary with an extraordinary small mass (M ₂≈ 0.066 M _⊙)—formally a brown dwarf. The brown dwarf may have been a former planet which survived a common envelope (CE) phase and has even gained mass. A recent determination of the components’ masses from results of NLTE spectral analysis and subsequent comparison to evolutionary tracks shows a discrepancy compared to masses derived from radial-velocity and the eclipse curves. Phase-resolved high-resolution and high-SN spectroscopy was carried out in order to investigate this problem. We present results of a NLTE spectral analysis of the primary, an analysis of its orbital parameters, and discuss possible evolutionary scenarios.     

Multi-day activity scheduling reactions to planned activities and future events in a dynamic model of activity-travel behavior

Modeling multi-day planning has received scarce attention in activity-based transport demand modeling so far. However, new dynamic activity-based approaches are being developed at the current moment. The frequency and inflexibility of planned activities and events in activity schedules of individuals indicate the importance of incorporating those pre-planned activities in the new generation of dynamic travel demand models. Elaborating and combining previous work on event-driven activity generation, the aim of this paper is to develop and illustrate an extension of a need-based model of activity generation that takes into account possible influences of pre-planned activities and events. This paper describes the theory and shows the results of simulations of the extension. The simulation was conducted for six different activities, and the parameter values used were consistent with an earlier estimation study. The results show that the model works well and that the influences of the parameters are consistent, logical, and have clear interpretations. These findings offer further evidence of face and construct validity to the suggested modeling approach.     

An agent-based micro-simulation framework for modelling of dynamic activity–travel rescheduling decisions

The simultaneous implementation of daily activity–travel schedules of individuals in a given spatial environment generally gives rise to time- and location-varying congestion levels, which affect the conditions for subsequent activity and travel choices. Although such dynamics are commonly recognized, current activity-based models typically ignore the adaptive behaviour of individuals. In this article, we propose an agent-based simulation system that allows one to simulate, in addition to activity-scheduling behaviour, also the execution of schedules in space and time. Congestion levels at specific times and places emerge in the system and may lead to discrepancies between scheduled and actual activity and travel times. Agents respond to such unforeseen events by reconsidering an existing schedule (within-day re-planning) and by adapting their expectations about traffic conditions for subsequent days (learning). The system is illustrated using the activity–travel diary data collected in the Eindhoven region, the Netherlands, to better understand the choice of urban parks in the study area. We discuss the merits of the system for transport and spatial planning and identify avenues for future research.     

Buddha from space—An ancient object of art made of a Chinga iron meteorite fragment*

Abstract– The fall of meteorites has been interpreted as divine messages by multitudinous cultures since prehistoric times, and meteorites are still adored as heavenly bodies. Stony meteorites were used to carve birds and other works of art; jewelry and knifes were produced of meteoritic iron for instance by the Inuit society. We here present an approximately 10.6 kg Buddhist sculpture (the “iron man”) made of an iron meteorite, which represents a particularity in religious art and meteorite science. The specific contents of the crucial main (Fe, Ni, Co) and trace (Cr, Ga, Ge) elements indicate an ataxitic iron meteorite with high Ni contents (approximately 16 wt%) and Co (approximately 0.6 wt%) that was used to produce the artifact. In addition, the platinum group elements (PGEs), as well as the internal PGE ratios, exhibit a meteoritic signature. The geochemical data of the meteorite generally match the element values known from fragments of the Chinga ataxite (ungrouped iron) meteorite strewn field discovered in 1913. The provenance of the meteorite as well as of the piece of art strongly points to the border region of eastern Siberia and Mongolia, accordingly. The sculpture possibly portrays the Buddhist god Vai?ravana and might originate in the Bon culture of the eleventh century. However, the ethnological and art historical details of the “iron man” sculpture, as well as the timing of the sculpturing, currently remain speculative.     

Small‐Scale ASR Between Flow Barriers in a Saline Aquifer

Regular aquifer storage recovery, ASR, is often not feasible for small‐scale storage in brackish or saline aquifers because fresh water floats to the top of the aquifer where it is unrecoverable. Flow barriers that partially penetrate a brackish or saline aquifer prevent a stored volume of fresh water from expanding sideways, thus increasing the recovery efficiency. In this paper, the groundwater flow and mixing is studied during injection, storage, and recovery of fresh water in a brackish or saline aquifer in a flow‐tank experiment and by numerical modeling to investigate the effect of density difference, hydraulic conductivity, pumping rate, cyclic operation, and flow barrier settings. Two injection and recovery methods are investigated: constant flux and constant head. Fresh water recovery rates on the order of 65% in the first cycle climbing to as much as 90% in the following cycles were achievable for the studied configurations with constant flux whereas the recovery efficiency was somewhat lower for constant head. The spatial variation in flow velocity over the width of the storage zone influences the recovery efficiency, because it induces leakage of fresh water underneath the barriers during injection and upconing of salt water during recovery.     

FUV spectroscopy of the central star of the planetary nebula Sh 2–216

The far-ultraviolet (FUV) spectrum of LS?V +46°21, the central star (CS) of the planetary nebula (PN) Sh?2?216, is strongly contaminated by interstellar absorption and thus, we have to simultaneously model both, the stellar as well as the interstellar spectrum in order to identify strategic metal lines which are only accessible in the FUV wavelength range. These lines are necessary to determine the photospheric parameters reliably. We present results of a NLTE spectral analysis of the FUV spectrum of LS?V+46°21.     

The future of containerization: perspectives from maritime and inland freight distribution

As containerization enters its peak growth years, its potential future developments over maritime and inland freight transport systems are being questioned. A series of issues can either further accelerate the adoption of containerization worldwide or, alternatively, could impose an upper limit to the extraordinary contribution that containers have implied for logistics systems and global commodity chains. These mainly include macro-economic, technical/operational and governance factors. Future containerization will be largely determined by interactions within and between four domains ranging from a functional to a spatial perspective. The logistical domain involves the functional organization of transport chains and their integration in supply chains. The transport domain involves the operation of transport services and intermodal operations. The infrastructural domain involves the provision and management of basic infrastructure for both links and nodes in the transport system. The locational domain relates to the geographical location of nodes and sites in the economic space and forms a basic element for their intrinsic accessibility in terms of centrality or intermediacy. It is underlined that the future of containerization will dominantly be shaped by inland transport systems.