Hydrogen in some natural garnets studied by nuclear reaction analysis and vibrational spectroscopy

A suite of 11 gem-quality, optically completely clear garnet crystals with a broad variety of compositions in the space of the end members pyrope–almandine–spessartine–grossular–andradite–goldmanite were analyzed for trace amounts of “water” by nuclear reaction analysis, NRA, based on the reaction ¹H(¹⁵N, αγ)¹²C, and by single-crystal absorption spectroscopy in the ν_OH vibrational range using microscope-FTIR-spectroscopic methods. The aim was to establish a calibration of the highly sensitive IR method with high areal resolution for “water” determination in garnets, by studying garnets of a wide compositional range, and to check for compositional dependencies of the integral molar absorptivities of the “water” component, ?_int[1mol_H2O^?1cm^?2], in the nominally “water”-free garnets. The results of NRA show a broad variation of water contents in the range (14 ± 3) to (950 ± 80) wt ppm_H2O, the values being low and very high for the garnet solid solutions (PyrAlm)_SS and close-to-end-member Gross_SS, respectively. There were no indications of inhomogeneities in the OH distribution, except possibly for one of the garnets (grossular, variety hessonite, from Tanzania). The quantitative evaluation of the complex ν_OH spectra, which showed similar shape only for members of the (PyrAlm)_SS, yielded integral absorption coefficients, α_int (cm^?2), which allowed the calculation of integral molar absorptivities, ?_int, using the “water” values of NRA. The ?_int values obtained varied in a wide range but with no obvious correlation with the composition of the garnet except for the extremely high values, in the 10⁴ range, of the two specimen with compositions close to end-member grossular. In all other garnets, ?_int was in the 10³ range with an average of ?_int=3630±1580[1mol_H2O^?1cm^?2]. Therefore, this value is proposed for the use in routine “water” determinations of compositionally different garnets by the micro-IR method, except for garnets near to end-member grossular.     

POPCORN: A Field Study of Photochemistry in North-Eastern Germany

The intensive field study POPCORN (Photo-Oxidant Formation by Plant Emitted Compounds and OH Radicals in North-Eastern Germany) was carried out in a rural area of North-Eastern Germany during August 1994. An overview of the objectives, measurements and major results of this campaign is presented. Measurements of a set of relevant atmospheric trace compounds, including the hydroxyl radical, along with meteorological data were performed to increase the understanding of OH radical chemistry and photo-oxidant formation. Additionally, plant emissions and the exchange of trace gases between a maize field and the atmosphere were investigated. Budgets of selected trace gases were calculated to assess the relative importance of local sources, chemistry or transport. Intercomparisons between measurement techniques were a central issue of POPCORN and included measurements of OH, hydrocarbons, formaldehyde, photolysis frequencies and vertical fluxes. OH radical concentrations were measured simultaneously by LIF (Laser Induced Fluorescence) and DOAS (Differential Optical Absorption Spectroscopy). Both methods showed good agreement. Maximum OH concentrations were around 107 cm–3 and the diurnal cycles closely followed the rate of primary production via ozone photolysis. Generally, the trace gas composition during POPCORN was characterized by relatively low concentrations of most compounds, e.g. CO: 85–200 ppb, ethane: 0.6–2 ppb, and moderate NOx levels: 0.5–5 ppb (at noontime). Concentrations of individual biogenic volatile organic compounds (VOC) were mostly well below 100 ppt. However, formaldehyde and acetaldehyde which partly originate from biological sources were observed at mixing ratios of some ppb.     

In-situ Measurements of Tropospheric Hydroxyl Radicals by Folded Long-Path Laser Absorption During the Field Campaign POPCORN

Absolutely calibrated in-situ measurements of tropospheric hydroxyl radicals, formaldehyde, sulfur dioxide, and naphthalene (C10H8) were performed by long-path laser absorption spectroscopy during the field campaign POPCORN. The absorption light path was folded into an open optical multiple reflection cell with a mirror separation of 38.5 m. Using a light path length of 1848 m and an integration time of 200 s, the average 1-detection limits of OH, HCHO, SO2 and C10H8 during POPCORN were 8.7 · 105 cm–3, 8.3 · 109 cm–3, 2.4 · 109 cm–3, 1.5 · 108 cm–3, respectively. In total, 392 identifications of OH in air spectra were made in a rural environment between August 5 and August 23, 1994. We present and discuss OH absorption spectra and diurnal OH concentration profiles of three days which are representative for measurements under different pollution conditions during POPCORN. The observed maximum and median OH radical concentrations are 1.3 · 107 OH/cm3 and 4.0 · 106 OH/cm3, respectively. The measured diurnal variation of the OH concentration shows a good correlation with the primary formation reaction of OH radicals which is the photolysis of ambient ozone. Deviations from this correlation in the morning and evening hours, when the OH concentration is higher than expected from the ozone photolysis, demonstrate the importance of other photochemical HOx production pathways during POPCORN.     

Meteorological Aspects, Ozone, and Solar Radiation Measurements During POPCORN 1994

Meteorological data, ozone mixing ratios, and photolysis frequencies for the period August 2 to August 24, 1994, are presented and discussed in support of the field campaign POPCORN (Photochemistry of Plant Emitted Compounds and OH Radicals in Northeastern Germany). Measurements of temperature, ozone, and wind speed at different heights are used to evaluate micro-meteorological parameters. The observations provide information about local influences on the air mass composition. The analysis of radio sonde data of nearby stations provides the height of the planetary boundary layer.     

Preliminary results from the MEMO multicomponent measurements of waves on-board INTERBALL 2

The MEMO (MEsure Multicomposante des Ondes) experiment is a part of theINTERBALL 2 wave consortium. It is connected to a total of six electric and nine magnetic independent sensors. It provides waveforms associated with the measurement of two to five components in three frequency bands: ELF (5–1000 Hz), VLF (1–20 kHz), LF (20–250 kHz). Preliminary analyses of low and high resolution data are presented. The emphasis is put on the estimation of the propagation characteristics of the observed waves. VLF hiss emissions are shown to be mainly whistler mode emissions, but other modes are present. An accurate estimation of the local plasma frequency is proposed when the low L = 0 cutoff frequency is identified. AKR emissions observed just above source regions are studied. R-X and L-O modes are found: the first at the lowest frequencies and the second at the highest. Both propagate with wave normal directions weakly oblique or quasi-parallel to the Earths magnetic field direction. Propagation characteristics are also determined for a (non-drifting) fine structure of AKR. There is no fundamental difference with structurless events. Night-side and dayside bursts of ELF electromagnetic emissions are presented. It is not clear whether the two emissions belong to the lion roar emissions or not.     

An accumulation theory approach to the explanation of regional disparities in underdeveloped countries

This article argues that the current explanations (polarization and polarization reversal theories) for the existing and widening regional disparities found in the developing countries are unsatisfactory and lead to unhelpful policy initiatives. It accepts the existance of polarisation and equalization mechanisms but argues that the influence of the historically and spatially differentiated socio-economic structure is the proper focus of attention.     

The planet formation imager

The Planet Formation Imager (PFI, www.planetformationimager.org) is a next-generation infrared interferometer array with the primary goal of imaging the active phases of planet formation in nearby star forming regions. PFI will be sensitive to warm dust emission using mid-infrared capabilities made possible by precise fringe tracking in the near-infrared. An L/M band combiner will be especially sensitive to thermal emission from young exoplanets (and their disks) with a high spectral resolution mode to probe the kinematics of CO and H₂O gas. In this paper, we give an overview of the main science goals of PFI, define a baseline PFI architecture that can achieve those goals, point at remaining technical challenges, and suggest activities today that will help make the Planet Formation Imager facility a reality.     

A Bayesian method for missing rainfall estimation using a conceptual rainfall–runoff model

The estimation of missing rainfall data is an important problem for data analysis and modelling studies in hydrology. This paper develops a Bayesian method to address missing rainfall estimation from runoff measurements based on a pre-calibrated conceptual rainfall–runoff model. The Bayesian method assigns posterior probability of rainfall estimates proportional to the likelihood function of measured runoff flows and prior rainfall information, which is presented by uniform distributions in the absence of rainfall data. The likelihood function of measured runoff can be determined via the test of different residual error models in the calibration phase. The application of this method to a French urban catchment indicates that the proposed Bayesian method is able to assess missing rainfall and its uncertainty based only on runoff measurements, which provides an alternative to the reverse model for missing rainfall estimates.     

亚——非季风区非绝热加热与夏季环流关系的诊断研究

基于热力适应理论,本文利用 ＮＣＥＰ／ ＮＣＡＲ再分析资料对撒哈拉沙漠、青藏高原和孟加拉湾地区的非绝热加热与夏季环流进行了诊断研究。在非洲撒哈拉沙漠地区,以感热输送为主的加热仅局限于近地面层,边界层以上的大气则以辐射冷却占优势。因而除了边界层内存在着浅薄的正涡度和微弱的上升运动以外,整个对流层几乎都维持负涡度并盛行下沉运动。对于青藏高原地区,强大的表面感热通量引起的垂直扩散是近地面大气加热的主要分量,与大尺度上升运动相关的凝结潜热对低层大气的加热也有一定的贡献。长波辐射造成的对流层中、上层大气的冷却则主要由深对流潜热释放来补偿。夏季高原地区总非绝热加热是正值,且最大加热率出现在边界层内。低空大气辐合产生正涡度,而中、高层大气辐散伴有较强的负涡度。因而高原盛行上升运动,最大上升运动位于近地面层。夏季孟加拉湾地区的深对流凝结潜热释放远大于长波辐的冷却作用,因而整个对流层几乎都保持较强的非绝热加热。４００ｈＰａ层附近的最大加热率引起３００－４００ｈＰａ最强的上升运动。对流层上层是负涡度区,而中、低层为正涡度区。结果还表明,垂直和水平辐散环流与大气的热源和热汇区密切相联：在高层,辐散气流从热源区流向热汇区;在低层则相