Arsenic Speciation in Lichens and in Coarse and Fine Airborne Particulate Matter by HPLC–UV–HG–AFS

A three-step sequential extraction procedure with Milli-Q, CaCl₂ and H₃PO₄ was applied for extraction of arsenic species in lichen transplants and airborne particulate matter (fine and coarse fractions). The samples used in this work were collected in 1994–1995 near coal-fired power plants. Both transplant lichens and airborne particulate matter were submitted to the same environment simultaneously. Arsenic species identification and quantification was performed by HPLC–UV–HG–AFS. Inorganic forms of arsenic (arsenite and arsenate) were present in significant amounts in most of the samples. Only in lichens also organic forms of arsenic (monomethyl arsonic acid and dimethyl arsinic acid) were identified which may indicate biotransformation of inorganic arsenic.     

Field observations of waves generated by passing ships: A note

This short contribution reports the results of a field study on the nearshore characteristics of waves generated by both conventional and high speed passenger ferries. The field observations took place in the late summer of 2005, at a beach close to the port of Mytilene (Island of Lesbos, Greece), and involved the visual observation of ship waves, using digital video recordings and image processing techniques. The results showed that passage of the fast ferry was associated with a longer, more complex and energetic nearshore event; this event not only did include higher nearshore waves (up to 0.74 m) and was organised in different wave packets, but it was also an order of magnitude longer (∼ 680 s) than the conventional ferry event. Regarding the effects on beach sediment dynamics, the fast ferry waves were estimated to be very efficient in mobilising the nearshore sediments in contrast to those of the conventional ferry. The fast ferry service appears to generate daily prolonged nearshore events, which contain waves with higher energy than those expected from the normal summer wind wave regime of the area; these events also include some high and very steep waves, which can be particularly erosive. Therefore, fast ferry wakes may have considerable impacts on the seasonal beach sediment dynamics/morphodynamics and the nearshore benthic ecology, as well as they may pose significant risks to bathers, affecting the recreational use of the beaches exposed to fast ferry traffic. Finally, the study has shown that satisfactory field observations of the nearshore characteristics of ship-generated (and wind) waves can be obtained using inshore deployments of calibrated poles, digital video cameras and appropriate image processing algorithms.     

OSL and ESR studies of Aeolian quartz from the Upper Pleistocene loess sequence of Nussloch (Germany)

As part of a chronological study of the famous Upper Pleistocene Nussloch (Germany) loess sequence, three samples were collected to check the applicability of palaeodosimetric dating methods (OSL and ESR) to quartz grains. The ESR-multicentre method showed a partial bleaching of the ESR centers in aeolian sands. This partial bleaching was also observed by OSL. Laminated loess seemed to be sufficiently bleached but showed a large scatter of the doses, which we ascribed to heterogeneous responses of the luminescent grains to the SAR protocol. Ages could nevertheless be calculated for the three samples and were found to be somewhat older than the IRSL and ¹⁴C ages obtained for the same layers of the laminated loess.     

Transport and emplacement of crater and basin deposits

Material is ejected from impact craters in ballastic trajectories; it impacts first near the crater rim and then at progressively greater ranges. Ejecta from craters smaller than approximately 1 km is laid predominantly on top of the surrounding surface. With increasing crater size, however, more and more surrounding surface will be penetrated by secondary cratering action and these preexisting materials will be mixed with primary crater ejecta. Ejecta from large craters and especially basin forming events not only excavate preexisting, local materials, but also are capable of moving large amounts of material away from the crater. Thus mixing and lateral transport give rise to continuous deposits that contain materials from within and outside the primary crater. As a consequence ejecta of basins and large highland craters have eroded and mixed highland materials throughout geologic time and deposited them in depressions inside and between older crater structures.Because lunar mare surfaces contain few large craters, the mare regolith is built up by successive layers of predominantly primary ejecta. In contrast, the lunar highlands are dominated by the effects of large scale craters formed early in lunar history. These effects lead to thick fragmental deposits which are a mixture of primary crater material and local components. These deposits may also properly be named regolith though the term has been traditionally applied only to the relatively thin fine grained surficial deposit on mare and highland terranes generated during the past few billion year. We believe that the surficial highland regolith - generated over long periods of time - rests on massive fragmental units that have been produced during the early lunar history.     

Pitch-angle diffusion of ring current protons caused by electrostatic ion loss-cone waves

Pitch-angle diffusion of ring current protons is investigated, assuming that the scattering is caused by resonant interaction with electrostatic ion loss-cone waves. Bounce averaged diffusion coefficients are presented for different wave energy distributions. It is found that wave amplitudes about 1 mV/m are required to give strong diffusion of protons with average energy.     

Synthetic Spectra of Long-Period Variables: A First Comparison with ISO Observations

Exploratory synthetic spectra were computed for carbon-rich long-period variables. We used dynamic model atmospheres of Höfner &; Dorfi (1997) and calculated partial pressures, absorption- and scattering coefficients as input for the spectral synthesis code of Jørgensen et al. (1992). First ISO SWS-observations of the carbon-Mira T Dra are compared with our synthetic spectra.     

Lunar velocity structure and compositional and thermal inferences

Seismic data from the Apollo Passive Seismic Network stations are analyzed to determine the velocity structure and to infer the composition and physical properties of the lunar interior. Data from artificial impacts (S-IVB booster and LM ascent stage) cover a distance range of 70–1100 km. Travel times and amplitudes, as well as theoretical seismograms, are used to derive a velocity model for the outer 150 km of the Moon. TheP wave velocity model confirms our earlier report of a lunar crust in the eastern part of Oceanus Procellarum.The crust is about 60 km thick and may consist of two layers in the mare regions. Possible values for theP-wave velocity in the uppermost mantle are between 7.7 km s^–1 and 9.0 km s^–1. The 9 km s^–1 velocity cannot extend below a depth of about 100 km and must decrease below this depth. The elastic properties of the deep interior as inferred from the seismograms of natural events (meteoroid impacts and moonquakes) occurring at great distance indicate that there is an increase in attenuation and a possible decrease of velocity at depths below about 1000 km. This verifies the high temperatures calculated for the deep lunar interior by thermal history models.Paper presented at the Lunar Science Institute Conference on Geophysical and Geochemical Exploration of the Moon and Planets, January 10–12, 1973.     

Assessing the Constrained Harmonic Mean Method for Deriving the Kinematics of ICMEs with a Numerical Simulation

In this study we use a numerical simulation of an artificial coronal mass ejection (CME) to validate a method for calculating propagation directions and kinematical profiles of interplanetary CMEs (ICMEs). In this method observations from heliospheric images are constrained with in-situ plasma and field data at 1 AU. These data are used to convert measured ICME elongations into distance by applying the harmonic mean approach, which assumes a spherical shape of the ICME front. We used synthetic white-light images, similar to those observed by STEREO-A/HI, for three different separation angles between remote and in-situ spacecraft of 30^°, 60^°, and 90^°. To validate the results of the method, the images were compared to the apex speed profile of the modeled ICME, as obtained from a top view. This profile reflects the “true” apex kinematics because it is not affected by scattering or projection effects. In this way it is possible to determine the accuracy of the method for revealing ICME propagation directions and kinematics. We found that the direction obtained by the constrained harmonic mean method is not very sensitive to the separation angle (30^° sep: ?=W7; 60^° sep: ?=W12; 90^° sep: ?=W15; true dir.: E0/W0). For all three cases the derived kinematics agree relatively well with the real kinematics. The best consistency is obtained for the 30^° case, while with growing separation angle the ICME speed at 1 AU is increasingly overestimated (30^° sep: ΔV _arr≈??50 km?s^?1, 60^° sep: ΔV _arr≈+?75 km?s^?1, 90^° sep: ΔV _arr≈+?125 km?s^?1). Especially for future L₄/L₅ missions, the 60^° separation case is highly interesting in order to improve space-weather forecasts.