Evaluation of the Residual Mass Fractionation in High-Precision Cr Isotopic Analysis with TIMS

The Cr isotope ratios of terrestrial and extra-terrestrial materials are emerging as one of the most important tracers in geosciences. Previous studies on Cr isotopic measurements using TIMS have found that there is residual Cr isotopic fractionation between the mass-fractionation-corrected ⁵³Cr/⁵²Cr and ⁵⁴Cr/⁵²Cr ratios, which may cause an offset of obtained ratios from the reference values. The residual fractionation was thought to be caused by the evaporation of Cr-oxide species during thermal ionisation, but the mechanism by which this residual fractionation could be reduced remained unclear. Here we revisit the issue of residual fractionation and propose that this problem can be alleviated by utilising W filaments instead of conventionally used Re filaments for Cr ionisation. Using W filaments, the formation of CrO⁺ was suppressed during heating as the filament temperature was ~ 100 °C lower than when Re filaments were used. In repeated measurement of a carbonaceous chondrite, the intermediate precisions of ⁵³Cr/⁵²Cr and ⁵⁴Cr/⁵²Cr ratios in the W filament runs were two to three times better than those of the Re filament runs. Therefore, the new finding of this study will be of key importance for future studies of Cr isotopes for terrestrial and extra-terrestrial materials.     

Physical parameters identification for full-scale ten-story reinforced concrete building with degrading tri-linear model by modal iterative error correction method

To assess the post-earthquake seismic safety of buildings, it is crucial to predict seismic response, and it is necessary to set the appropriate physical parameters of the response analysis model. Numerous methods have been proposed to identify physical parameters. However, most of them are limited to linear systems, and previous researches on nonlinear systems have difficulties in practical applications. In this paper, a nonlinear response analysis model is identified for a full-scale ten-story reinforced concrete building with the degrading tri-linear stiffness model by the modal iterative error correction (MIEC) method, and the accuracy of this technique is discussed by comparing with the shaking table test.     

Hydrometeorological behaviour of pine and larch forests in eastern Siberia

Seasonal changes in the water and energy exchanges over a pine forest in eastern Siberia were investigated and compared with published data from a nearby larch forest. Continuous observations (April to August 2000) were made of the eddy‐correlation sensible heat flux and latent heat flux above the canopy. The energy balance was almost closed, although the sum of the turbulent fluxes sometimes exceeded the available energy flux (R_n ? G) when the latent heat flux was large; this was related to the wind direction. We examined the seasonal variation in energy balance components at this site. The seasonal variation and magnitude of the sensible heat flux (H) was similar to that of the latent heat flux (λE), with maximum values occurring in mid‐June. Consequently, the Bowen ratio was around 1·0 on many days during the study period. On some clear days just after rainfall, λE was very large and the sum of H and λE exceeded R_n ? G. The evapotranspiration rate above the dry canopy from May to August was 2·2 mm day^?1. The contributions of understory evapotranspiration (E_u) and overstory transpiration (E_o) to the evapotranspiration of the entire ecosystem (E_t) were both from 25 to 50% throughout the period analysed. These results suggest that E_u plays a very important role in the water cycle at this site. From snowmelt through the tree growth season (23 April to 19 August 2000), the total incoming water, comprised of the sum of precipitation and the water equivalent of the snow at the beginning of the melt season, was 228 mm. Total evapotranspiration from the forest, including interception loss and evaporation from the soil when the canopy was wet, was 208–254 mm. The difference between the incoming and outgoing amounts in the water balance was from +20 to ?26 mm. The water and energy exchanges of the pine and larch forest differed in that λE and H increased slowly in the pine forest, whereas λE increased rapidly in the larch forest and H decreased sharply after the melting season. Consequently, the shape of the Bowen ratio curves at the two sites differed over the period analysed, as a result of the differences in the species in each forest and in soil thawing. Copyright © 2003 John Wiley & Sons, Ltd.     

Relation between X-ray flux and radio flux from cosmic objects

The relationship between the X-ray flux and the radio flux from cosmic objects is investigated. We consider the emission from energetic electrons on the condition in which a plasma and a magnetic field exist. As energetic electrons under the circumstances emit both X-rays by the bremsstrahlung mechanism and radio waves by the gyrosynchrotron mechanism simultaneously, it is shown that the radio flux density is closely related to the X-ray flux density. Solving an integral equation describing the X-ray flux density at Earth, we obtain the energy spectrum of electrons in the emitting region. Inserting the result into equation of the radio flux density at Earth, we obtain the direct formula between the X-ray flux density and the radio flux density. The relation is independent of the distance between Earth and cosmic sources. Assuming a power-law X-ray spectrum, we evaluate the numerical relation between two flux densities.     

Use of colour to display the circular polarization in solar dynamic spectra

Equipment has been developed to display in colour any circular polarization in the dynamic spectra of solar radio emissions. The potential and limitations of this simple equipment are discussed on the basis of a sample record. Modifications, now under development, to improve the system are described.     

Spectroscopic Studies of Solar Corona VII. Formation of a Coronal Loop by Evaporation

We obtained time-sequence spectroscopic observations in (Fe x) 6374 Å and (Fe xiv) 5303 Å lines successively with the 25-cm coronagraph, and narrow-band and Doppler images in 5303 Å line by the 2-D 10-cm Doppler coronagraph NOGIS at the Norikura Solar Observatory, of a coronal region for about 7 h on 9 19–20, 2001. The raster scans were obtained with a quasi-periodicity of about 14 min and NOGIS obtained the images with an interval of about 1 min. The coronal region observed showed the formation of a coronal loop by a high-speed surge in the 6374 Å line rising from one of the footpoints of the loop. Off the limb spectroscopic observations in the 6374 Å line showed large velocities along the line of sight and vertical to the solar limb at the time of formation of the loop. The 5303 Å line observations showed negligible line-of-sight velocities and low vertical velocities when compared to those in the 6374 Å line. A hump in the intensity plots in 5303 Å with height appears to move up with respect to the solar limb with an average velocity of 4km s^–1. The FWHM of the 6374 Å showed a much smaller value of about 0.7 Å near the foot point as compared to a value of 1.2 Å at larger heights at the beginning of observations. Later as the loop developed, the FWHM of 6374 Å line showed a gradual decrease along the loop up to 70 from the limb, reached a minimum value of about 0.5 Å and then increased with height during the formation of the loop; this trend lasted for about 2 h. About 3 h after the beginning of the formation of the loop, the FWHM of 6374 Å emission line showed normal values and normal rate of increase with height with some fluctuations. The FWHM of the 5303 Å line did not show such variations along the loop and showed normal decrease in FWHM with height found earlier (Singh et al., 2003a). These observations suggest that a relatively cooler plasma at a temperature of about 0.7 MK or less (corresponding to minimum value of FWHM of 0.5 Å) was ejected from the transition region with a large velocity of about 48km s^–1, heated up in the corona by some process and formed a coronal loop with a height of about 200 above the limb that had lifetime greater than 4 h. It appears that the plasma moved from one of the footpoints and the loop was formed by evaporation of chromospheric plasma. No large-scale brightening and H flare were observed in this region during the observational period of 7 h.On leave from Indian Institute of Astrophysics, Bangalore 560034, India.     

An interpretation of the rotational temperature of the airglow hydroxyl emissions

The rotational temperature of the airglow hydroxyl emissions arising from various schemes of vibrational transitions was obtained by using spectroscopic data from six observational sources. The rotational temperature was found to depend systematically on the quantum number (ν') of the upper vibrational level from which the relevant band originates. It has a doubly degrading characteristic with respect to ν' taking maximal values at ν' = 6 and 9, which exceed considerably the atmospheric temperature. It drops off quickly as ν' decreases from 9 to 7, and then from 6 to 3 after making an abrupt rise at ν' = 6. This ν'-dependence of the rotational temperature is in favor of the hypothesis that there are two routes of excitation of the hydroxyl airglow: O₃ + H = OH(ν ? 9) + O₂, and HO₂ + O = OH(ν ? 6) + O₂. The present result implies also that the relaxation time of rotation of OH in the upper mesosphere is as long as 0.1 sec; a value an order of magnitude larger than that inferred in earlier laboratory experiments.     

A search for millimeter wave spectral lines from comet Sugano-Saigusa-Fujikawa (1983e)

The search for radio spectral lines from Comet Sugano-Saigusa-Fujikawa (1983e) was conducted using the 45-m telescope of Nobeyama Radio Observatory. The frequency ranges of 44.0–46.0 and 47.5–49.5 GHz were surveyed down to $\text{ΔT}{}_{\mathrm{<mtext>A</mtext>}}{}^1\text{(}\text{rms}\text{) = 20–30}\text{mK}$, with a beam size of ～35 arc sec. Upper limits have been established for spectral lines of atomic hydrogen, CS, OCS, SO₂, H₂CO, CH₃OH, HCCCCCN, HCOOCH₃, CH₃OCH₃, and CH₃CH₂CN. The J = 5?4 line from HCCCN in the vibrational ground state possibly has been detected but not confirmed. The suggested total amount of HCCCN in the coma is consistent with the possible picture that HCCCN is the main parent molecule of CN.     

Relationship of topography to surface water chemistry with particular focus on nitrogen and organic carbon solutes within a forested watershed in Hokkaido,Japan

We studied the relationships between streamwater chemistry and the topography of subcatchments in the Dorokawa watershed in Hokkaido Island, northern Japan, to examine the use of topography as a predictor of streamwater chemistry in a watershed with relatively moderate terrain compared with other regions of Japan. Topographic characteristics of the Dorokawa watershed and its subcatchments were expressed as topographic index (TI) values, which ranged from 4·5 to 20·4 for individual grid cells (50 × 50 m²), but averaged from 6·4 to 7·4 for the 20 subcatchments. Streamwater samples for chemical analyses were collected four times between June and October 2002 from 20 locations in the watershed. The pH of water that passed through the watershed increased from ～5·0 to 7·0, with major increases in Na⁺ and Ca²⁺ and marked decreases in NO₃^? and SO . Distinctive spatial patterns were observed for dissolved organic carbon (DOC), dissolved organic nitrogen (DON), and NO₃^? concentrations of streamwater across the watershed. Statistical analyses indicated significant linear relationships between the average TI values of subcatchments and DOC, DON, and NO₃^? concentrations. Furthermore, the proportion of DOC in streamwaters in the wet season increased with TI values relative to other nitrogen species, whereas NO₃^? concentrations decreased with TI. The gradients of soil wetness and the presence of wetlands explained many of the observed spatial and temporal patterns of DOC, DON, and NO₃^? concentrations in the surface waters of the Dorokawa watershed. Our results suggest that the TI is especially useful for predicting the spatial distribution of DOC, DON and NO₃^? in the surface waters of Hokkaido, where topographical relief is moderate and wetlands more common than in other regions of Japan. Copyright © 2006 John Wiley & Sons, Ltd.     

History of neutrino telescope/astronomy

Neutrinos represent a new window to the Universe. In this paper we discuss the attempts to detect neutrinos, starting with the Homestake experiment, which showed the deficit of solar neutrinos. The detection of neutrinos from SN 1987A gave a new impetus to neutrino research. By using successive generations of neutrino detectors it was possible to show that the solar neutrino deficit could be explained by a flavor change of massive neutrinos. With the latest detector, kamLAND, it is possible to investigate the interior of the Earth through the detection of geoneutrinos.