Contamination level of mercury in red meat products from cetaceans available from South Korea markets

Levels of total mercury (T-Hg) were surveyed in red meat (n=73) and liver (n=3) from toothed whales, dolphins and porpoises (odontocetes) sold for human consumption in the coastal cities of South Korea. High concentrations of T-Hg were found in the liver products of finless porpoises (18.7 and 156 microg/wet g) and common dolphins (13.2 microg/wet g). The T-Hg concentrations in red meat products were highest in the false killer whale (9.66+/-12.3 microg/wet g, n=9), bottlenose dolphin (10.6+/-12.6 microg/wet g, n=3) and killer whale (13.3 microg/wet g, n=1), and lowest in Cuvier's beaked whale and the harbour porpoise (0.4-0.5 microg/wet g). Thus, most of the products that originated from odontocetes exceeded the safety limit of 0.5 microg/wet g for T-Hg set by the South Korean health authorities for the fishery industry. Pregnant women and other vulnerable sectors of the population living in South Korea should therefore limit their consumption of odontocete products.     

Refinement of the Micro‐Distillation Technique for Isotopic Analysis of Geological Samples with pg‐Level Osmium Contents

In recent years, the ¹⁸⁷Re–¹⁸⁷Os isotope system has been increasingly used to study samples containing very small quantities of Os. For such samples, optimisation of measurement procedures is essential to minimise the loss of Os before mass spectrometric measurements. Micro‐distillation is a necessary purification step that is applied after the main Os chemical separation procedure, prior to Os isotope ratio measurements by negative‐thermal ionisation mass spectrometry (N‐TIMS). However, unlike the other separation steps, this procedure has not yet been optimised for small samples. In this study, we present a refined micro‐distillation method that achieved higher yields and allowed high‐precision R(¹⁸⁷Os/¹⁸⁸Os) expressed as ¹⁸⁷Os/¹⁸⁸Os measurements for small‐sized geological samples that contain only a few pg Os. The Os recovery in the micro‐distillation step was tested by changing the operating conditions including heating time and temperature, and amounts of oxidant and reductant. Recoveries were measured by the isotope dilution ICP‐MS method after the addition of ¹⁹⁰Os‐enriched spike solution. We found that the most critical factor controlling the chemical yield of Os during micro‐distillation is the extent of dilution of the reductant (HBr) by H₂O evaporated from the oxidant. A refined micro‐distillation method, in which the amount of oxidant solution is reduced from the conventional method, achieved an improved chemical yield of Os (~ 90%). This refined method was applied to the measurement of ¹⁸⁷Os/¹⁸⁸Os by N‐TIMS of varying test portions of the geological reference material BIR‐1a. The resulting ¹⁸⁷Os/¹⁸⁸Os ratios of BIR‐1a matched the literature data, with propagated uncertainties of 0.2, 1.1 and 11% digested sample quantities containing 150, 10 and 1 pg of Os, respectively.     

Surface lowering rates of uplifted limestone terraces estimated from the height of pedestals on a subtropical island of Japan

In Kikai‐jima, south‐western Japan, many pedestal rocks have developed on the surface of Holocene raised coral‐reef terraces with known dates of emergence. Pedestals are formed just under boulders, which are considered to have been transported by tsunami and settled on a reef flat before emergence. On the assumption that boulders protect the underlying limestone terrace from rainfall solution, the rate of surface lowering of these limestone terraces was evaluated from the height of pedestals and the period of their formation. The result showed that the mean lowering rate over 6000 years is 205 mm/ky. Copyright © 2007 John Wiley & Sons, Ltd.     

Construction of Wide Field Cryogenic Telescope

We constructed a wide field cryogenic telescope (WFCT) containing a whole Ritchey-Chrétien system and a focal plane array in a cryostat for near infrared observations to cover the field of view of 0.4°. The telescope has a primary mirror of 220 mm and an engineering grade 256 × 256 InSb array. The optical components such as two mirrors, filters, spiders, and radiation shield tube are cooled down to 180 K as well as the InSb array to 35 K by a mechanical refrigerator. We show the results of the background surface brightnesses and the limiting magnitudes at 3.3 and 3.67 μm measured at Sutherland, South Africa. We describe the on-going upgrade of this instrument, equipped with a 1024 × 1024 ALADDIN InSb science grade array. This revised version was published online in July 2006 with corrections to the Cover Date.     

Small-Amplitude Disturbances in a Radiating and ScatteringGrey MediumI. Solutions of Given Real Frequency ω

We reanalyze the propagation of one-dimensional small-amplitude disturbances of given real frequency ω in a radiating and scattering grey medium using the Eddington approximation, which has been studied previously by us (Kaneko et al., 1976). Numerical results reveals three frequency regimes to be distinguished, and two wave modes always appear in each frequency regime. The governing equations and analytic solutions are derived for all wave modes using Whitham's method modified into quadratic form and approximate methods based on radiation thermodynamics. In the high-frequency regime appear the radiation-wave and adiabatic sound modes, which are damped by opacity and radiative cooling, respectively. Wave patterns in the intermediate-frequency and low-frequency regimes depend critically on the importance of radiation, for which the criterion is given in terms of the ratio of total specific heats at constant pressure and constant volume. When the radition overwhelms the matter (radiation-dominated case), the radiative mode in the intermediate-frequency regime is the constant-volume diffusion mode. When the matter overwhelms the radiation (matter-dominated case), damped radiation-wave and damped radiation-diffusion modes newly appear between the radiation-wave and constant-volume diffusion modes. The acoustic mode in the intermediate-frequency regime is the isothermal sound mode,which is damped by radiative cooling at higher frequencies and by radiation-thermal drag force at lower frequencies. Two modes appearing in the low-frequency regime are the isentropic radiation-acoustic and constant-pressure diffusion modes. The absorption coefficient derived for the former is shown to be a radiation-thermodynamic extension of that of Landau and Lifshitz (1987). The transition frequencies between all adjacent two modes are also derived to discuss the implications of them. This revised version was published online in July 2006 with corrections to the Cover Date.     

GCM simulation of balloon trajectories on Titan

Possible trajectories of passive balloons in Titan's troposphere are simulated with the instantaneous wind field predicted by a GCM (general circulation model). In most areas the basic motion of a balloon is a predominantly eastward or westward drift, depending on altitude, latitude and season of the balloon release point. Some meridional oscillation is always superposed on this basic motion, resulting in a wavy trajectory, with a maximum extent (of 40^°) at high latitudes of the winter hemisphere. As a general rule, the meridional oscillation can be maximised if a balloon is deployed in altitudes and latitudes where the mean zonal wind is eastward and smaller than the phase speed of Saturn's gravitational tide on Titan. A balloon's groundtrack does not repeat as it makes successive circuits around Titan, but rather makes a spiral or braided pattern. The summer pole is rather difficult to access for a balloon not directly introduced there because of small meridional oscillation, while the winter pole can be readily accessed and left several times. A preferred zonal drift direction can be achieved by choosing a proper altitude and hemisphere, but choosing a preferred meridional direction is not possible.     

Infrared photometry of Venus: Variation during 10 years?

The infrared flux of Venus has been observed with a narrowband filter (λ = 3.6 μm, Δλ = 0.08 μm) from 1982 through 1984, covering a range of the phase angle α from 27 to 94°. Normalized values of flux at the Venus-Earth distance of 1 AU were (4.0–5.4) × 10^?17W/cm²/cm^?1 and the α dependence of the data is rather weak. Furthermore, when the evening terminator of Venus was seen, lower values of flux were obtained in contrast with higher values at the morning terminator. The α dependence is quite different from that of J.V. Martonchik and R. Beer (1975, J. Atmos. Sci.32, 1151–1156). Since we cannot find any significant problem in the two observational methods, the difference might suggest an intrinsic time variation of haze particles during these 10 years in the upper haze layer of the Venus cloud.     

Large-Eddy-Simulation Study of the Effects of Building-Height Variability on Turbulent Flows over an Actual Urban Area

Large-eddy simulation (LES) is used to investigate the effects of building-height variability on turbulent flows over an actual urban area, the city of Kyoto, which is reproduced using a 2-m resolution digital surface dataset. Comparison of the morphological characteristics of Kyoto with those of European, North American, and other Japanese cities indicates a similarity to European cities but with more variable building heights. The performance of the LES model is validated and found to be consistent with turbulence observations obtained from a meteorological tower and from Doppler lidar. We conducted the following two numerical experiments: a control experiment using Kyoto buildings, and a sensitivity experiment in which all the building heights are set to the average height over the computational region \(h_{all}\). The difference of Reynolds stress at height \(z=2.5h_{all}\) between the control and sensitivity experiments is found to increase with the increase in the plan-area index (\(\lambda _p\)) for \(\lambda _p > 0.32\). Thus, values of \(\lambda _p\approx 0.3\) can be regarded as a threshold for distinguishing the effects of building-height variability. The quadrant analysis reveals that sweeps contribute to the increase in the Reynolds stress in the control experiment at a height \(z= 2.5h_{all}\). The exuberance in the control experiment at height \(z=0.5h_{all}\) is found to decrease with increase in the building-height variability. Although the extreme momentum flux at height \(z=2.5h_{all}\) in the control experiment appears around buildings, it contributes little to the total Reynolds stress and is not associated with coherent motions.     

Geochemical characteristics of deposits from the 2011 Tohoku‐oki tsunami at Hasunuma,Kujukuri coastal plain,Japan

We examined the geochemical characteristics and temporal changes of deposits associated with the 2011 Tohoku‐oki tsunami. Stable carbon isotope ratios, biomarkers, and water‐leachable ions were measured in a sandy tsunami deposit and associated soils sampled at Hasunuma, Kujukuri coastal plain, Japan, in 2011 and 2014. At this site, the 2011 tsunami formed a 10–30 cm ‐thick layer of very fine to medium sand. The tsunami deposit was organic‐poor, and no samples contained any detectable biomarkers of either terrigenous or marine origin. In the underlying soil, we identified hydrocarbons and sterols derived from terrestrial plants, but detected no biomarkers of marine origin. In the samples collected in 2011, concentrations of tsunami‐derived water‐leachable ions were highest in the soil immediately beneath the tsunami deposit and then decreased gradually with depth. Because of its finer texture and higher organic content, the soil has a higher water‐holding capacity than the sandy tsunami deposit. This distribution suggests that ions derived from the tsunami quickly penetrated the sand layer and became concentrated in the underlying soil. In the samples collected in 2014, concentrations of water‐leachable ions were very low in both soil and sand. We attribute the decrease in ion concentrations to post‐tsunami rainfall, seepage, and seasonal changes in groundwater level. Although water‐leachable ions derived from seawater were concentrated in the soil beneath the tsunami deposit following the tsunami inundation, they were not retained for more than a few years. To elucidate the behavior of geochemical characteristics associated with tsunamis, further research on organic‐rich muddy deposits (muddy tsunami deposits and soils beneath sandy tsunami deposits) as well as sandy tsunami deposits is required.