High-pressure phase relations in the system CaAl4Si2O11–NaAl3Si3O11 with implication for Na-rich CAS phase in shocked Martian meteorites

High-pressure phase relations in the system NaAl₃Si₃O₁₁–CaAl₄Si₂O₁₁ were examined at 13–23 GPa and 1600–1900 °C, using a multianvil apparatus. A Ca-aluminosilicate with CaAl₄Si₂O₁₁ composition, designated CAS phase, is stable above about 13 GPa at 1600 °C. In the system NaAl₃Si₃O₁₁–CaAl₄Si₂O₁₁, the CAS phase dissolving NaAl₃Si₃O₁₁ component coexists with jadeite, corundum and stishovite below 22 GPa, above which the CAS phase coexists with Na-rich calcium ferrite, corundum and stishovite. At 1600 °C, the solubility of NaAl₃Si₃O₁₁ component in the CAS solid solution increases with increasing pressure up to about 50 mol% at about 22 GPa, above which the solubility decreases with pressure. The maximum solubility of NaAl₃Si₃O₁₁ component in the CAS phase increases with temperature up to around 70 mol% at 1900 °C at 22 GPa. The dissociation of NaAlSi₂O₆ jadeite to NaAlSiO₄ calcium ferrite plus stishovite occurs at about 22 GPa. Lattice parameters of the CAS phase with the hexagonal Ba-ferrite structure change with increase of the NaAl₃Si₃O₁₁ component: a-axis decreases and c-axis slightly increases, resulting in decrease of molar volume. Enthalpies of the CAS solid solutions were measured by high-temperature drop-solution calorimetry techniques. The results show that enthalpy of hypothetical NaAl₃Si₃O₁₁ CAS phase is much higher than the mixture of NaAlSi₂O₆ jadeite, corundum and stishovite and is close to that of the mixture of NaAlSiO₄ calcium ferrite, corundum and stishovite. When we adopt the Na:Ca ratio of 75:25 of the natural Na-rich CAS phase in a shocked Martian meteorite, Zagami, the phase relations determined above suggest that the natural CAS phase crystallized from melt at pressure around 22 GPa and temperature close to or higher than 2000–2200 °C. The inferred P, T conditions are consistent with those estimated using other high-pressure minerals in the shocked meteorite.     

Earthquake Nucleation on Faults with a Revised Rate- and State-Dependent Friction Law

Recently Nagata et al. (J Geophys Res 117:B02314, 2012) have proposed a new version of rate- and state-dependent friction law (RSF) that seems to have eventually resolved all the previously known discrepancies in the existing RSFs from laboratory observations. The values of a and b, empirical RSF parameters determined by fitting the same laboratory experiments, have been revised to be five times greater and a newly noticed weakening effect by shear stress with a coefficient c has been introduced. By using this revised RSF, we reinvestigated a problem of 2D quasi-static nucleation on faults. A crack-like nucleation-zone expansion known for the ‘aging’ version of RSF is not sustainable with the ‘Nagata’ law, which is understandable as the Nagata law does not produce a slip-weakening distance proportional to the involved strength reduction, an aging law’s feature that contradicts laboratory observations. The later stage of Nagata-law nucleation shows localization of quasi-static slip within a limited spatial extent, but the localization is much milder than that predicted by the ‘slip’ version of RSF. With an appropriate c parameter of the Nagata law, the nucleation size seems to be reduced only by a factor from that of the aging law.     

Simulation of tides in hydrocarbon lakes on Saturn’s moon Titan

Numerous hydrocarbon lakes have recently been detected on Saturn’s largest moon Titan, representing the only known large bodies of liquids on a planetary surface outside the Earth. In the context of comparative oceanography, tides and tidal currents in two representative lakes on Titan (Kraken Mare and Ontario Lacus) are simulated by a three-dimensional baroclinic ocean circulation model. Since the tide-generating force on Titan is an order of magnitude larger than on Earth and the gravitational acceleration is small, tides and currents are substantially larger than in Earth’s lakes and are more comparable with those in Earth’s oceans. The predicted maximum tidal range in Kraken Mare is 4 m. The tidal wave propagates around the basin of Kraken Mare, while a nearly standing tidal wave is excited in Ontario Lacus. Titan’s rotation is too slow to affect the tidal flow in any Titan’s lake. The tidal current velocity in Kraken Mare amounts to a few centimeters per second except in the vicinity of a narrow strait, where it is enhanced by an order of magnitude. In summer, when the lake is stratified, internal tides can develop. Seiches cannot be caused by tide. In the largest lakes, atmospheric tide may cause additional lake surface displacements.     

Spatial relations between preflares and flares

We have conducted an initial search for discrete preflare brightenings as observed in soft X-radiation by Yohkoh. The Yohkoh images allow us to identify, to within a few arc seconds, the location of a preflare event relative to the succeeding flare. Our initial motivation in this study was to search for early coronal brightenings leading to flare effects, as had been suggested by earlier studies; thus we concentrated on Yohkoh limb events. We find no evidence for such early coronal brightenings. Between 15% and 41% of the 131 suitable events matched our criteria for preflare brightening: the same active region; brightening within one hour of the flare peak; preflare brightness less than 30% of the flare peak. In the great majority of the preflare cases, we found that physically separate nearby structures brightened initially. Often these structures appeared to share a common footpoint location with the flare brightening itself. In a few cases the preflare could have occurred in exactly the same structure as the flare.     

Table of Contents

Volume Contents

Table of Contents     

V p/V s-ratios from the central Kolbeinsey Ridge to the Jan Mayen Basin,North Atlantic; implications for lithology,porosity and present-day stress field

The horizontal components from twenty Ocean Bottom Seismometers deployed along three profiles near the Kolbeinsey Ridge, North Atlantic, have been modelled with regard to S-waves, based on P-wave models obtained earlier. Two profiles were acquired parallel to the ridge, and the third profile extended eastwards across the continental Jan Mayen Basin. The modelling requires a thin (few 100 m) layer with very high V _p/V _s-ratio (3.5–9.5) at the sea-floor in the area lacking sedimentary cover. The obtained V _p/V _s-ratios for the remaining part of layer 2A, 2B, 3 and upper mantle, correspond to the following lithologies: pillow lavas, sheeted dykes, gabbro and peridotite, respectively. All crustal layers exhibit a decreasing trend in V _p/V _s-ratio away-from-the-axis, interpreted as decreasing porosity and/or crack density in that direction. A significant S-wave azimuthal anisotropy is observed within the thin uppermost layer of basalt near the ridge. The anisotropy is interpreted as being caused by fluid-filled microcracks aligned along the direction of present-day maximum compressive stress, and indicates crustal extension at the ridge itself and perpendicular-to-the-ridge compression 12 km off axis. Spreading along the Kolbeinsey Ridge has most likely been continuous since its initiation ca. 25 Ma: The data do not suggest the presence of an extinct spreading axis between the Kolbeinsey Ridge and the Aegir Ridge as has been proposed earlier. The V _p/V _s-ratios found in the Jan Mayen Basin are compatible with continental crust, overlain by a sedimentary section dominated by shale.     

Large-Eddy-Simulation Study of the Effects of Building-Height Variability on Turbulent Flows over an Actual Urban Area

Large-eddy simulation (LES) is used to investigate the effects of building-height variability on turbulent flows over an actual urban area, the city of Kyoto, which is reproduced using a 2-m resolution digital surface dataset. Comparison of the morphological characteristics of Kyoto with those of European, North American, and other Japanese cities indicates a similarity to European cities but with more variable building heights. The performance of the LES model is validated and found to be consistent with turbulence observations obtained from a meteorological tower and from Doppler lidar. We conducted the following two numerical experiments: a control experiment using Kyoto buildings, and a sensitivity experiment in which all the building heights are set to the average height over the computational region \(h_{all}\). The difference of Reynolds stress at height \(z=2.5h_{all}\) between the control and sensitivity experiments is found to increase with the increase in the plan-area index (\(\lambda _p\)) for \(\lambda _p > 0.32\). Thus, values of \(\lambda _p\approx 0.3\) can be regarded as a threshold for distinguishing the effects of building-height variability. The quadrant analysis reveals that sweeps contribute to the increase in the Reynolds stress in the control experiment at a height \(z= 2.5h_{all}\). The exuberance in the control experiment at height \(z=0.5h_{all}\) is found to decrease with increase in the building-height variability. Although the extreme momentum flux at height \(z=2.5h_{all}\) in the control experiment appears around buildings, it contributes little to the total Reynolds stress and is not associated with coherent motions.     

Effects of the introduction of rice on evapotranspiration in seasonal wetlands

Land use changes in wetland areas can alter evapotranspiration, a major component of the water balance, which eventually affects the water cycle and ecosystem. This study assessed the effect of introduced rice‐cropping on evapotranspiration in seasonal wetlands of northern Namibia. By using the Bowen ratio–energy balance method, measurements of evapotranspiration were performed over a period of 2.5 years at two wetland sites—a rice field (RF) and a natural vegetation field (NVF)—and at one upland field (UF) devoid of surface water. The mean evapotranspiration rates of RF (1.9 mm daytime^?1) and NVF (1.8 mm daytime^?1) were greater than that in UF (1.0 mm daytime^?1). RF and NVF showed a slight difference in seasonal variations in evapotranspiration rates. During the dry season, RF evapotranspiration was less than the NVF evapotranspiration. The net radiation in RF was less in this period because of the higher albedo of the non‐vegetated surface after rice harvesting. In the early growth period of rice during the wet season, evapotranspiration in RF was higher than that in NVF, which was attributed to a difference in the evaporation efficiency and the transfer coefficient for latent heat that were both affected by leaf area index (LAI). Evapotranspiration sharply negatively responded to an increase in LAI when surface water is present according to sensitivity analysis, probably because a higher LAI over a surface suppresses evaporation. The control of LAI is therefore a key for reducing evaporation and conserving water. Copyright © 2013 John Wiley & Sons, Ltd.