Separation of Heavy Lanthanoids by Flash Column Chromatography for Precise Determination of Er and Yb Isotope Compositions in Rock Samples

We present a new column chemistry technique for the quantitative separation of heavy lanthanoids by an ultra‐fine‐grained LN resin (20–50 µm) with a specific emphasis on the purification of Er and Yb for their isotopic analysis. To achieve the quantitative separation of Er and Yb within a reasonable timescale, flash column chromatography was applied, where the column was attached to a newly designed vacuum box system, thus accelerating the elution speed by ten times compared with that of the normal column procedure operated by gravity flow. The recovery yields of Er and Yb were confirmed to be approximately 100%, which is important to suppress the effect of the mass‐independent fractionation of the Er and Yb isotopes during chromatography. Additionally, we have developed precise Er and Yb isotope measurements by thermal ionisation mass spectrometry (TIMS) using multistatic and/or dynamic methods. Moreover, in most cases, the Er and Yb isotope compositions of the measured four terrestrial rock samples were indistinguishable from those of the commercially available Er and Yb Alfa Aesar solutions. The new method presented in this work will be useful for future studies on heavy lanthanoids in various geological materials.     

Gravity and S-wave modelling across the Jan Mayen Ridge,North Atlantic; implications for crustal lithology

The horizontal components from fourteen Ocean Bottom Seismometers deployed along four profiles focused along the western margin of the Jan Mayen microcontinent, North Atlantic, have been modelled with regard to S-waves, based on P-wave models obtained earlier. The seismic models have furthermore been constrained by 2D gravity modelling. High V _p/V _s-ratios (2.3–7.9) within the Cenozoic sedimentary section are attributed to significant porosities, whereas V _p/V _s-ratios in the order of 1.9–2.2 for the Mesozoic and Paleozoic sedimentary rocks indicate shale-dominated lithology throughout the area. The eastern side of the Jan Mayen Ridge is interpreted as a passive, volcanic margin, based on relatively high crustal V _p/V _s-ratios (1.9), whereas lower V _p/V _s-ratios (1.75–1.8) suggest the presence of intermediate composition crust and non-volcanic margin on the western side of the ridge. In the westernmost part of the Jan Mayen Basin, slightly increased upper mantle V _p/V _s-ratios may indicate some degree of serpentization of upper mantle peridotites.     

Large-Eddy Simulation Of Radiation Fog

In order to study the three-dimensional structure of radiation fogand to obtain a basic understanding of its generation mechanism,a numerical experiment is performed with a large-eddysimulation model and compared with the observation at Cabauw in the Netherlands. After confirming that the results are insatisfactory agreement with the observations, the structure of thefog and its generation mechanism are examined in more detail.Before the fog forms, the atmosphere is stable and an inversionlayer exists almost adjacent to the ground surface. As the fog grows, however, the stratification is destabilized and a mixed layerdevelops gradually. The longwave radiative cooling near thefog top contributes to the destabilization more than thecondensational heating does.The evolution of the fog can be classified into three stagesaccording to the behaviour of turbulent kinetic energy (TKE):formation, development, and dissipation stages.The fog layer has different flow structures at each stage.During the formation stage, longitudinal rolls similar tostreaks in channel flows appear near the ground surface.The development stage is characterized by an initiation oftransverse bands due to Kelvin–Helmholtz instability anda sudden increase of TKE. During the dissipation stage, longitudinalrolls and polygonal cells due to convective instability are organized.     

Compression of Na0.4Mg0.6Al1.6Si0.4O4 NAL and Ca-ferrite-type phases

Compression behaviors of two Al-rich phases in the lower mantle, hexagonal new aluminum-rich (NAL) phase and its high-pressure polymorph Ca-ferrite-type (CF) phase, were examined for identical Na_0.4Mg_0.6Al_1.6Si_0.4O₄ (40?% NaAlSiO₄–60?% MgAl₂O₄) composition. The volumes of the NAL and CF phases were obtained at room temperature up to 31 and 134?GPa, respectively, by a combination of laser-annealed diamond-anvil cell techniques and synchrotron X-ray diffraction measurements. Fitting of the third-order Birch–Murnaghan equation of state to such pressure–volume data yields bulk modulus K ₀?=?199(6) GPa at 1?bar and its pressure derivative K ₀′?=?5.0(6) for the NAL phase and K ₀?=?169(5) GPa and K ₀′?=?6.3(3) for the CF phase. These results indicate that the bulk modulus increases from 397 to 407 GPa across the phase transition from the NAL to CF phase at 43 GPa, where the NAL phase completely transforms into the CF phase on Na_0.4Mg_0.6Al_1.6Si_0.4O₄. Density also increases by 2.1?% across the phase transition.     

Aircraft Observations of the Development of Thermal Internal Boundary Layers and Scaling of the Convective Boundary Layer Over Non-Homogeneous Land Surfaces

This study investigates the convective boundary layer (CBL) that develops over anon-homogeneous surface under different thermal and dynamic conditions. Analysesare based on data obtained from a Russian research aircraft equipped with turbulentsensors during the GAME-Siberia experiment over Yakutsk in Siberia, from April to June 2000.Mesoscale thermal internal boundary layers (MTIBLs) that radically modified CBLdevelopment were observed under unstable atmospheric conditions. It was found thatMTIBLs strongly influenced the vertical and horizontal structures of virtual potentialtemperature, specific humidity and, most notably, the vertical sensible and latent heatfluxes. MTIBLs in the vicinity of the Lena River lowlands were confirmed by clouddistributions in satellite pictures.MTIBLs spread through the entire CBL and radically modify its structure if the CBL isunstable, and strong thermal features on the underlying surface have horizontal scalesexceeding 10 km. MTIBL detection is facilitated through the use of special parameterslinking shear stress and convective motion.The turbulent structure of the CBL with and without MTIBLs was scaled usingthe mosaic or flux aggregate approach. A non-dimensional parameterL_Rau/L_hetero (where L_Rau is Raupach's length and L_hetero is the horizontal scale of the surface heterogeneity)estimates the application limit of similarity and local similarity scaling models forthe mosaic parts over the surface. Normalized vertical profiles of wind speed, airtemperature, turbulent sensible and latent heat fluxes for the mosaic parts withL_RauL_hetero < 1 could be estimated by typical scalingcurves for the homogeneous CBL. Traditional similarity scaling models for the CBLcould not be applied for the mosaic parts with L_Rau/L_hetero > 1.For some horizontally non-homogeneous CBLs, horizontal sensible heat fluxes werecomparable with the vertical fluxes. The largest horizontal sensible heat fluxes occurred at the top of the surface layer and below the top of the CBL.Formerly affiliated to the Frontier Observational Research System for Global ChangeFormerly affiliated to the Frontier Observational Research System for Global Change     

Abundance, Biomass, Production and Trophic Roles of Micro- and Net-Zooplankton in Ise Bay, Central Japan, in Winter

We investigated the geographical variations in abundance and biomass of the major taxonomic groups of micro- and net-zooplankton along a transect through Ise Bay, central Japan, and neighboring Pacific Ocean in February 1995. The results were used to estimate their secondary and tertiary production rates and assess their trophic roles in this eutrophic embayment in winter. Ise Bay nourished a much higher biomass of both micro- and net-zooplankton (mean: 3.79 and 13.9 mg C m^–3, respectively) than the offshore area (mean: 0.76 and 4.47 mg C m^–3, respectively). In the bay, tintinnid ciliates, naked ciliates and copepod nauplii accounted for, on average, 69, 18 and 13% of the microzooplankton biomass, respectively. Of net-zooplankton biomass, copepods (i.e. Acartia, Calanus, Centropages, Microsetella and Paracalanus) formed the majority (mean: 63%). Average secondary production rates of micro- and net-zooplankton in the bay were 1.19 and 1.87 mg C m^–3d^–1 (or 23.1 and 36.4 mg C m^–2d^–1), respectively, and average tertiary production rate of net-zooplankton was 0.75 mg C m^–3d^–1 (or 14.6 mg C m^–2d^–1). Available data approximated average phytoplankton primary production rate as 1000 mg C m^–2d^–1 during our study period. The transfer efficiency from primary production to zooplankton secondary production was 6.0%, and the efficiency from secondary production to tertiary production was 25%. The amount of food required to support the zooplankton secondary production corresponded to 18% of the phytoplankton primary production or only 1.7% of the phytoplankton biomass, demonstrating that the grazing impact of herbivorous zooplankton was minor in Ise Bay in winter.     

Preface to the Special Issue on Summer 2020: Record Rainfall in Asia — Mechanisms,Predictability and Impacts

Throughout vast areas of Asia, the summer of 2020 was extraordinarily wet. After an exceptionally wet May in North-east India and Bangladesh, excessive rainfall hit at least 10 provinces in central and southern China in June and July, caus-ing extensive flooding in many rural and urban locations. Long standing rainfall, lake and river level records were con-sequently broken in several parts of the region with the Yangtze-Huaihe river valleys, particularly badly impacted, with con-sequential economic losses. Floods and landslides also affected parts of Japan with at least one location in Kumamoto province even experiencing a record-breaking 1000 mm of rainfall in just 3 days in early July. The 2020 wet season in South Korea was also exceptionally long, lasting 54 days, compared to their more usual 32.     

Near-field beam pattern measurement of qualification model of ALMA band 8 (385–500 GHz) cartridge receiver

We have developed a near-field vector beam measurement system covering the range of frequencies from 385 to 500 GHz. The measurement set-up is capable of measurements with dynamic range exceeding 50 dB and amplitude and phase stability respectively of 0.1 dB/h and 1 degree/5 min at room temperature. Beam patterns of the ALMA band 8 corrugated horns and receiver optics block were measured at room temperature and lately compared with physical optics calculations obtained in the far-field. Both co-polar and cross-polar beam patterns of a qualification model of the ALMA band 8 cartridge cooled in a cartridge-test-cryostat have also been measured in the near-field as a detector of a submillimeter vector network analyzer. The measurements presented in this work refer to the lowest, middle and upper frequencies of band 8. The comparisons between software model and experimental measurements at these frequencies show good agreement down to ?30 dB for the main polarization component. The cross-polarization level of the beam propagating through the receiver optics block was also characterized. We found that a cross-polarization level better than ?28 dB can be achieved at all measured frequencies. The measured beam pattern of this receiver corresponds to efficiency of greater than 92% at the sub reflector (diameter of 750 mm) of the ALMA 12 m optics.     

Plasma motions in the flare of 1982 June 6 (X12)

This paper analyzes soft X-ray spectra obtained from the Hinotori spacecraft for the investigation of plasma motions during the initial phase of the great flare, 1982 June 6. The wavelength calibration of the scanning spectrometers is determined from information on the spacecraft attitude and from the position of the Fexxv resonance line during the decay phase. Hard X-ray bursts, nonthermal line broadenings and blueshifted components in X-ray lines are temporally correlated with time differences of 0–30 s. The possible contribution of the blueshifted component to the line width decreases more rapidly than the nonthermal broadening, which suggests dominant plasma motions are taking place at higher and higher altitude in the corona, because of the increase of electron density in flaring loops. The evolution of the input kinetic energy content to the thermal plasma inferred from line broadenings in the impulsive phase resembles that of the thermal energy content in the source of the Fexxvi emission, which is different from that deduced for Fexxv source. This suggests that the origins of the nonthermal line broadening and Fexxvi source are closely coupled.