Reaction of forsterite with hydrogen molecules at high pressure and temperature

High pressure and temperature reactions of a mixture of forsterite and hydrogen molecules have been carried out using a laser heated diamond anvil cell at 9.8–13.2 GPa and ~1,000 K. In situ X-ray diffraction measurements showed no sign of decomposition or phase transitions of the forsterite under these experimental conditions, indicating that the olivine structure was maintained throughout all runs. However, a substantial expansion of the unit cell volume of the forsterite was observed for samples down to ~3 GPa upon quenching to ambient pressure at room temperature. The Raman spectroscopy measurements under pressure showed significant shifts of the Raman peaks of the Si–O vibration modes for forsterite and of the intramolecular vibration mode for H₂ molecules toward a lower frequency after heating. Additionally, no OH vibration modes were observed by Raman and FT-IR spectroscopic measurements. These lines of evidence show that the observed volume expansion in forsterite is not explained by the incorporation of hydrogen atoms as hydroxyl, but suggest the presence of hydrogen as molecules in the forsterite structure under these high pressure and temperature conditions.     

Differences in Ecosystem Dynamics between the Northern and Southern Parts of the Japan Sea: Analyses with Two Ecosystem Models

Differences in ecosystem dynamics between the northern and southern parts of the Japan Sea have been investigated with two nitrogen based ecosystem models forced by climatological mixed layer depth and euphotic layer depth. Models having 4 and 9 compartments with the same biochemical parameters were applied to the northern and southern parts. The spring bloom in the southern part is earlier and smaller than that in the northern part according to both models, which is supported by satellite ocean color images. The difference of the timing is related to the variation of mixed layer depth, and the magnitude of blooming is also related to the concentrations of surface nutrient and herbivorous zooplankton in early spring. The simulated seasonal variations of ecosystem characteristics (standing stock of each compartment, primary production and the ratio of export flux of organic particles to the primary production) are not significantly different between two models. The ratio of export flux of organic particles to the primary production are about 36% and 23% in the northern and southern parts according to the 4-compartment model, while the values are 31% and 18% by 9-compartment model. These results suggest that the biological pump in the northern part is more active than that in the southern part of the Japan Sea. Sensitivity analyses have been carried out to examine the differences of the response to the models.     

减饱和砂土缓倾场地的液化性状分析

减饱和法是一种通过减小砂土地基的饱和度,从而提高地基抗液化强度的新方法。基于减饱和砂土中流体模量同步更新的改进算法对减饱和砂土离心机振动台试验进行了数值分析,并与单一流体模量的简化算法进行了对比分析。结果表明：由于改进算法中考虑了因孔压变化引起的等效流体模量的变化,其计算结果更接近试验结果,而简化算法低估了减饱和砂土的孔压积累。基于改进算法开展了不同饱和度、倾斜角度的缓倾场地上液化变形的数值模拟研究,分析发现超孔隙水压力增长的速度及其峰值随着饱和度的增加而增大,饱和度从100%降低至96.4%,同一深度处的超孔压峰值降低约20%～65%,加速度响应的峰值也有明显的降低;沿地基深度0.75 m到9.00 m,侧向位移减少约20%～50%,表明饱和度的降低对抑制倾斜场地上可液化砂土层的侧向变形有显著效果,随着地基深度的减小,饱和度对于侧向位移的影响越来越明显。     

An excitation mechanism for the free 'core nutation'

Summary. The Earth is believed to possess a free nutational mode due to its rotating, elliptical, fluid core, with an eigenfrequency of approximately (1 + 1/460) cycle sidereal day⁻¹ as seen from the sidereally rotating Earth. This free 'core nutation' has not yet been undisputably observed. Furthermore, there has been considerable doubt that any known mechanism could excite this mode to an observable level. We show here that diurnal atmospheric and oceanic loading of the Earth's surface provide an efficient excitation mechanism which depends critically on the physical damping of the mode. Possible effects of the mode on geodetic measurements are discussed. We also consider the effects of 'wobble' and 'nutation' on astrometric observations.     

P–V–T equation of state of Ca3Al2Si3O12 grossular garnet

The thermoelastic parameters of synthetic Ca₃Al₂Si₃O₁₂ grossular garnet were examined in situ at high-pressure and high-temperature by energy dispersive X-ray diffraction, using a Kawai-type multi-anvil press apparatus coupled with synchrotron radiation. Measurements have been conducted at pressures up to 20 GPa and temperatures up to 1,650 K: this P, T range covered the entire high-P, T stability field of grossular garnet. The analysis of room temperature data yielded V _0,300 = 1,664 ± 2 ?³ and K ₀ = 166 ± 3 GPa for K^￠₀ K^{\prime}_{0} fixed to 4.0. Fitting of our P–V–T data by means of the high-temperature third order Birch–Murnaghan or the Mie–Grüneisen–Debye thermal equations of state, gives the thermoelastic parameters: (∂K _0,T /∂T) _P  = −0.019 ± 0.001 GPa K⁻¹ and α _0,T  = 2.62 ± 0.23 × 10⁻⁵ K⁻¹, or γ ₀ = 1.21 for fixed values q ₀ = 1.0 and θ ₀ = 823 (Isaak et al. Phys Chem Min19:106–120, 1992). From the comparison of fits from two different approaches, we propose to constrain the bulk modulus of grossular garnet and its pressure derivative to K _T0 = 166 GPa and K^￠_T0 K^{\prime}_{T0}  = 4.03–4.35. Present results are compared with previously determined thermoelastic properties of grossular-rich garnets.     

A numerical study on the formation and variation of a clockwise-circulation during winter in the Yellow Sea

In the Yellow Sea, the north-westerly wind dominates in winter and the existence of horizontal clockwise circulation has been suggested (Yanagi and Takahashi, 1993). The formation and variation mechanisms of this clockwise circulation is investigated using the wind forced numerical model which has a simplified basin configuration of the Yellow Sea. The model results show that two vortices (an anticlockwise vortex off Chinese coast and a clockwise vortex off Korean coast) are generated by the uniform north-westerly wind. Both vortices propagate along the shelf slope as the first mode shelf waves. An anti-clockwise vortex can not grow because it does not balance to the wind forcing. On the other hand, a clockwise vortex can grow and it reaches to the equilibrium condition at the northern part of the Yellow Sea, because this circulation can balance to the wind forcing. The time scale to become into the equilibrium condition is about 2 days. From this fact, it is ascertained that a clockwise circulation in the basin is generated periodically according to the variable wind forcing with 4 days period. The steady part of the current field exists with the fluctuating one which is induced by the periodical north-westerly wind.     

Electrical conduction and polarization of calcite single crystals

The electrical conductivity and polarization properties of calcite single crystals with three orientations, namely, a (00.1) plane perpendicular to the crystallographic c axis (10.0) plane parallel to the crystallographic c axis, and a (10.4) cleavage plane, were studied by both complex impedance and thermally stimulated depolarization current (TSDC) measurements. Conductivities for (00.1)-, (10.0)-, and (10.4)-oriented single calcite crystals at 400–600?°C were 1.16?×?10^?7?–?1.05?×?10^?5, 7.40?×?10^?8?–?4.27?×?10^?6, and 4.27?×?10^?7?–?2.86?×?10^?5 Ω^?1 m^?1, respectively, and the activation energies for conduction were 112, 103, and 101?kJ?mol^?1, respectively. The TSDC spectra verified the electrical polarizability of calcite crystals. The activation energy for depolarization, estimated from TSDC spectra, of the (00.1)-, (10.0)-, and (10.4)-oriented calcite substrates were 112, 119, and 114?kJ?mol^?1, respectively. Considering the correlation between the processes of conduction and electric polarization, we proposed the mechanisms of conduction and polarization in calcite on the assumption of oxide ion transport.     

Surface chlorophyll-a dynamics in the upper Gulf of Thailand revealed by a coupled hydrodynamic-ecosystem model

Although plankton bloom incidents in the upper Gulf of Thailand (UGoT) have been reported, no dynamic investigation of the phenomenon has been conducted. To address this need, a simple pelagic ecosystem model coupled with the Princeton Ocean Model (POM) was employed to investigate seasonal variations in surface chlorophyll-a (chl-a) distributions to clarify phytoplankton dynamics in this area. The results revealed patterns of seasonal chl-a distribution that correspond to local wind, water movement and river discharge. High chl-a patchiness was found to be concentrated near the western coast following westward circulation near the northern coast developed during the northeast monsoon. During the southwest monsoon high concentrations were observed around the northeastern coast due to eastward flow. The simulated results could explain the seasonal shifting of phytoplankton blooms, which typically arise along the western and eastern coasts during the northeast and the southwest monsoons, respectively. Sensitivity analyses of simulated chl-a distributions demonstrate that water stability, including wind-induced vertical currents and mixing, plays significant roles in controlling phytoplankton growth. Nutrients in the water column will not stimulate strong plankton blooms unless upwelling develops or vertical diffusivity is low. This finding suggests an alternative aspect of the mechanism of phytoplankton bloom in this region.     

High-temperature and high-pressure equation of state for the hexagonal phase in the system NaAlSiO4 – MgAl2O4

Thermal equation of state of an Al-rich phase with Na_1.13Mg_1.51Al_4.47Si_1.62O₁₂ composition has been derived from in situ X-ray diffraction experiments using synchrotron radiation and a multianvil apparatus at pressures up to 24 GPa and temperatures up to 1,900 K. The Al-rich phase exhibited a hexagonal symmetry throughout the present pressure–temperature conditions and the refined unit-cell parameters at ambient condition were: a=8.729(1) Å, c=2.7695(5) Å, V ₀=182.77(6) Å³ (Z=1; formula weight=420.78 g/mol), yielding the zero-pressure density ρ₀=3.823(1) g/cm³ . A least-square fitting of the pressure-volume-temperature data based on Anderson’s pressure scale of gold (Anderson et al. in J Appl Phys 65:1534–543, 1989) to high-temperature Birch-Murnaghan equation of state yielded the isothermal bulk modulus K ₀=176(2) GPa, its pressure derivative K ₀ ^′ =4.9(3), temperature derivative (?K _T /?T) _P =?0.030(3) GPa K^?1 and thermal expansivity α(T)=3.36(6)×10^?5+7.2(1.9)×10^?9 T, while those values of K ₀=181.7(4) GPa, (?K _T /?T) _P =?0.020(2) GPa K^?1 and α(T)=3.28(7)×10^?5+3.0(9)×10^?9 T were obtained when K ₀ ^′ was assumed to be 4.0. The estimated bulk density of subducting MORB becomes denser with increasing depth as compared with earlier estimates (Ono et al. in Phys Chem Miner 29:527–531 2002; Vanpeteghem et al. in Phys Earth Planet Inter 138:223–230 2003; Guignot and Andrault in Phys Earth Planet Inter 143–44:107–128 2004), although the difference is insignificant (<0.6%) when the proportions of the hexagonal phase in the MORB compositions (～20%) are taken into account.