Relationship among titanium,rare earth elements,U–Pb ages and deformation microstructures in zircon: Implications for Ti-in-zircon thermometry

A zircon grain in an orthopyroxene–garnet–phlogopite–zircon–rutile-bearing xenolith from Udachnaya, Siberia, preserves a pattern of crystallographic misorientation and subgrain microstructure associated with crystal–plastic deformation. The zircon grain records significant variations in titanium (Ti) from 2.6 to 30 ppm that corresponds to a difference in calculated Ti-in-zircon temperatures of over several hundred degrees Celsius. The highest Ti concentration is measured at subgrain centres (30 ppm), and Ti is variably depleted at low-angle boundaries (down to 2.6 ppm). Variations in cathodoluminescence coincide with the deformation microstructure and indicate localised, differential enrichment of rare earth elements (REE) at low-angle boundaries. Variable enrichment of U and Th and systematic increase of Th/U from 1.61 to 3.52 occurs at low-angle boundaries. Individual SHRIMP-derived U–Pb ages from more deformed zones (mean age of 1799 ± 40, n = 22) are systematically younger than subgrain cores (mean age of 1851 ± 65 Ma, n = 7), and indicate that open system behaviour of Ti–Th–U occurred shortly after zircon growth, prior to the accumulation of significant radiogenic Pb. Modelling of trace-element diffusion distances for geologically reasonable thermal histories indicates that the observed variations are ~ 5 orders of magnitude greater than can be accounted for by volume diffusion. The data are best explained by enhanced diffusion of U, Th and Ti along deformation-related fast-diffusion pathways, such as dislocations and low-angle (< 5°) boundaries. These results indicate chemical exchange between zircon and the surrounding matrix and show that Ti-in-zircon thermometry and U–Pb geochronology from deformed zircon may not yield information relating to the conditions and timing of primary crystallisation.     

Volatile loss from melt inclusions in pyroclasts of differing sizes

We have investigated the loss of H₂O from olivine-hosted melt inclusions (MIs) by designing an experiment using tephra samples that cooled at different rates owing to their different sizes: ash, lapilli, and bomb samples that were deposited on the same day (10/17/74) of the sub-Plinian eruption of Volcán de Fuego in Guatemala. Ion microprobe, laser ablation-ICPMS, and electron probe analyses show that MIs from ash and lapilli record the highest H₂O contents, up to 4.4 wt%. On the other hand, MIs from bombs indicate up to 30 % lower H₂O contents (loss of ~1 wt% H₂O) and 10 % post-entrapment crystallization of olivine. This evidence is consistent with the longer cooling time available for a bomb-sized clast, up to 10 min for a 3–4-cm radius bomb, assuming conductive cooling and the fastest H diffusivities measured in olivine (D~10^?9 to 10^?10 m²/s). On the other hand, several lines of evidence point to some water loss prior to eruption, during magma ascent and degassing in the conduit. Thus, results point to both slower post-eruptive cooling and slower magma ascent affecting MIs from bombs, leading to H₂O loss over the timescale of minutes to hours. The important implication of this study is that a significant portion of the published data on H₂O concentrations in olivine-hosted MIs may reflect unrecognized H₂O loss via diffusion. This work highlights the importance of reporting clast and MI sizes in order to assess diffusive effects and the potential benefit of using water loss as a chronometer of magma ascent.     

http://www.sciencedirect.com/science/article/pii/S1674987113000595

Magmatic oxide deposits in the～260 Ma Emeishan Large Igneous Province(ELIP),SW China and northern Vietnam,are important sources of Fe,Ti and V.Some giant magmatic Fe-Ti-V oxide deposits, such as the Panzhihua,Hongge,and Baima deposits,are well described in the literature and are hosted in layered mafic-ultramafic intrusions in the Panxi region,the central ELIP.The same type of ELIP- related deposits also occur far to the south and include the Anyi deposit,about 130 km south of Panzhihua,and the Mianhuadi deposit in the Red River fault zone.The Anyi deposit is relatively small but is similarly hosted in a layered mafic intrusion.The Mianhuadi deposit has a zircon U-Pb age of～260 Ma and is thus contemporaneous with the ELIP.This deposit was variably metamorphosed during the Indosinian orogeny and Red River faulting.Compositionally,magnetite of the Mianhuadi deposit contains smaller amounts of Ti and V than that of the other deposits,possibly attributable to the later metamorphism.The distribution of the oxide ore deposits is not related to the domal structure of the ELIP.One major feature of all the oxide deposits in the ELIP is the spatial association of oxide-bearing gabbroic intrusions,syenitic plutons and high-Ti flood basalts.Thus,we propose that magmas from a mantle plume were emplaced into a shallow magma chamber where they were evolved into a field of liquid immiscibility to form two silicate liquids,one with an extremely Fe-Ti-rich gabbroic composition and the other syenitic.An immiscible Fe-Ti-(P) oxide melt may then separate from the mafic magmas to form oxide deposits.The parental magmas from which these deposits formed were likely Fe-Ti-rich picritic in composition and were derived from enriched asthenospheric mantle at a greater depth than the magmas that produced sulfide-bearing intrusions of the ELIP.     

Book reviews

APPLIED GEOGRAPHY: Issues, Questions and Concerns (Geo Journal Library Vol. 15) edited by M. S. Kenzer. 16 × 24 cm, x and 210 pages. Kluwer: Dordrecht 1989 (ISBN 0 7923 04381).

WINE AND THE VINE: An Historical Geography of Viticulture and the Wine Trade by T. Unwin. 16 × 24 cm, xvi and 409 pages. Routledge: London 1991 (ISBN 0 415 13120 6) $A155.00 (hard); distributed by The Law Book Co.

WATERFRONT SYDNEY 1860–1920 by G. Aplin and J. Storey. 26 × 18 cm. 144 pages. Allen & Unwin: Sydney 1991 (first published 1984) (ISBN 1 86373 098 2) $A24.95 (soft).

Australian Geographer 23 (2), November 1992

INDUSTRIAL LOCATION: Principles and Policies (Second Edition) by K. Chapman and D. F. Walker. 15 × 23 cm, xiii and 322 pages. Basil Black‐well: Oxford 1991 (ISBN 0 631 16789 7) $A39.95 (soft).

INTERNATIONALISATION OF AUSTRALIA'S SERVICE INDUSTRIES by J. V. Langdale. 17 × 25 cm, iv and 373 pages. Australian Government Publishing Service, for Department of Industry, Technology and Commerce: Canberra 1991 (ISBN 0 644 13841 6).

TOURISM AND GOLD IN KAKADU: The Impact of Current and Potential Natural Resource Use on the Northern Territory Economy by B. Knapman, O. Stanley and J. Lea. 21 × 29 cm, vi and 49 pages. North Australia Research Unit, Australian National University: Darwin 1991 (ISBN 0 7315 1179 4).

ABORIGINAL AUSTRALIA AND THE ‘NEW FEDERALISM’ INITIATIVE (Discussion Paper No. 2) by G. J. Crough. 14 × 21 cm, 42 pages. North Australia Research Unit, Australian National University: Darwin 1991 (ISBN 0 7315 1325 8).

AUSTRALIAN NATIONHOOD AND OUTBACK INDIGENOUS PEOPLES (Discussion Paper No. 1) by P. Jull. 14 × 21 cm, 38 pages. North Australia Research Unit, Australian National University: Darwin 1991 (ISBN 0 7315 1309 6).

MIGRATION AND DEVELOPMENT IN THE SOUTH PACIFIC (Pacific Research Monograph No. 24) edited by J. Connell. 17 × 25 cm, xii and 199 pages. National Centre for Development Studies, Australian National University: Canberra 1990 (ISBN 0 07315 0668 5) $A25.00 (soft).

POPIULESIN BLONG HONIARA: Olketa Popiulesin Map Blong 1986 Sensis. HONIARA: 1986 Census Atlas (Statistics Office Occasional Paper No. 4 / Board of Development Studies Monograph No. 1) by A.C. Walsh. 21 × 29 cm, vii and 95 pages. Department of Statistics: Honiara and Board of Development Studies, Massey University: Palmerston North 1990 (ISSN 0114 8834) $NZ34.00 in New Zealand, $NZ38.00 elsewhere (soft).

DOI MOI: Vietnam's Renovation Policy and Performance (Political and Social Change Monograph No. 14) edited by D. K. Forbes, T. H. Hull, D. G. Marr and B. Brogan. 15 × 22 cm, xiv and 263 pages. Department of Political and Social Change, Australian National University: Canberra 1991 (ISBN 0 7315 1303 7).     

An evaluation of the health status of the Lavaca Bay, Texas ecosystem using Crassostrea virginica as the sentinel species

Locational risks for compromised ecosystem health for the eastern oysters (Crassostrea virginica) harvested from Lavaca Bay, Texas were estimated. Flow cytometric evaluation of variations in DNA content and the lysosomal destabilization assay were used for evaluation of genotoxicity and stress, respectively. Bayesian geo-statistical methods were utilized to estimate and evaluate spatial effects. For models with spatial risks, continuous surface maps of predicted parameter values were created to evaluate risk location. Lysosomal destabilization assay results were spatially oriented whereas flow cytometry results were fit best with the random effects model. While not spatially oriented, the highest levels of variations in DNA content were also present near industrial facilities. Locational risks of increased biomarkers of genotoxicity and stress in the eastern oyster (Crassostrea virginica) were increased with proximity to industrial facilities     

Monitored Natural Attenuation of Manufactured Gas Plant Tar Mono- and Polycyclic Aromatic Hydrocarbons in Ground Water: A 14-Year Field Study

Site 24 was the subject of a 14-year (5110-day) study of a ground water plume created by the disposal of manufactured gas plant (MGP) tar into a shallow sandy aquifer approximately 25 years prior to the study. The ground water plume in 1988 extended from a well-defined source area to a distance of approximately 400 m down gradient. A system of monitoring wells was installed along six transects that ran perpendicular to the longitudinal axis of the plume centerline. The MGP tar source was removed from the site in 1991 and a 14-year ground water monitored natural attenuation (MNA) study commenced. The program measured the dissolved mono- and polycyclic aromatic hydrocarbons (MAHs and PAHs) periodically over time, which decreased significantly over the 14-year period. Naphthalene decreased to less than 99% of the original dissolved mass, with mass degradation rates of 0.30 per year (half-life 2.3 years). Bulk attenuation rate constants for plume centerline concentrations over time ranged from 0.33 ± 0.09 per year (half-life 2.3 ± 0.8 years) for toluene and 0.45 ± 0.06 per year (half-life 1.6 ± 0.2 years) for naphthalene. The hydrogeologic setting at Site 24, having a sandy aquifer, shallow water table, clay confining layer, and aerobic conditions, was ideal for demonstrating MNA. However, these results demonstrate that MNA is a viable remedial strategy for ground water at sites impacted by MAHs and PAHs after the original source is removed, stabilized, or contained.     

Profiles of Fecal Porphyrins in River Otters Following the Exxon Valdez Oil Spill

Median levels of Coproporphyrin III (Copro III) in fecal samples of river otters (Lontra canadensis) collected from an oiled area in Prince William Sound, Alaska, USA, during 1990 were significantly higher than in samples collected from the same oiled area during 1996 (p=0.011, one way analysis of variance), a nonoiled reference area in Prince William Sound during 1996 (p=0.002) and a reference area in southeast Alaska during 1998 (p=0.004). An overall test of significance that combined probabilities from the statistical analysis of this porphyrin study with those from other biomarker studies revealed a significant difference in physiological response of river otters between oiled and nonoiled areas of the Sound for 1990 (p < 0.01). We demonstrated that changes in levels of fecal porphyrins may serve as a biomarker that may contribute to a health assessment of wild river otters.     

澳大利亚造山型金矿和侵入岩有关金矿系统流体包裹体资料和矿化过程的比较

We have examined the fluid inclusion data and fluid chemistry of Australian orogenic and intrusion-related gold deposits to determine if similar mineralization processes apply to both styles of deposits.The fluid inclusion data from the Yilgarn craton,the western subprovince of the Lachlan orogen,the Tanami,Tennant Creek and Pine Creek regions,and the Telfer gold mine show that mineralization involved fluids with broadly similar major chemical components(i.e.H_2O NaCl CO_2±CH_4±N_2).These deposits formed over a wide range of temperature-pressure conditions(<200 to>500℃,<100～400MPa).Low salinity, CO_2-bearing inclusions and low salinity aqueous inclusions occur in both systems but the main difference between these two types of deposits is that most intrusion-related gold deposits also contain at least one population of high-salinity aqueous brine.Oxygen and hydrogen isotope data for both styles of deposit usually cannot distinguish between a magmatic or metamorphic source for the ore-bearing fluids.However,sulfur and lead isotope data for the intrusion-related gold deposits generally indicate either a magmatic source or mixing between magmatic and sedimentary sources of fluid.The metamorphic geothermal gradients associated with intrusion-related gold deposits are characterized by low pressure,high temperature metamorphism and high crustal geothermal gradients of>30/km.Where amphibole breakdown occurs in a granite source region,the spatially related deposits are more commonly associated with Cu-Au deposits rather than Au-only deposits that are associated with lower temperature granites.The dominant processes thought to cause gold precipitation in both types of deposits are fluid-rock interaction(e.g.desulfidation)or phase separation.Consideration of the physical and chemical properties of the H_2O-NaCl-CO_2 system on the nature of gold precipitation mechanisms at different crustal levels infers different roles of chemical(fluid-rock interaction)versus rheological(phase separation and/or fluid mixing)host-rock controls on gold deposition.This also implies that at the site of deposition,similar precipitation mechanisms operate at similar crustal levels for both orogenic and intrusion-related gold deposits.     

Book reviews

AUSTRALIA AND ITS URBAN “CENTRES (Urbanization of the Earth No. 6) by B. Hofmeister. 19 × 28 cm, xii and 254 pages. Gebruder Borntraeger: Berlin 1988 (ISBN 3 443 37008 X) DM130 (hard).

CONTEMPORARY AUSTRALIA: Explorations in Economy, Society and Geography by D. J. Walmsley and A. D. Sorenson. 19 × 25 cm, xxiv and 328 pages. Longman Cheshire: Melbourne 1988 (ISBN 0 58271150 9) $A29.95 (soft).

WATERING THE GARDEN STATE: Water, Land and Community in Victoria 1834–1988 by J. M. Powell. 16 × 24 cm, xv and 319 pages. Allen & Unwin: Sydney 1989 (ISBN 0 04 3600 74 3) SA39.95 (hard); (ISBN 0 04 364024 9) SA24.95 (soft).

THE BUREAUCRATS DOMAIN. Space and the Public Interest in Victoria 1836–1884 by R. Wright. 15 × 23 cm, xv and 350 pages. Oxford University Press: Melbourne 1989 (ISBN 0 19 554866 3) $A39.95 (hard).

SOUTHERN APPROACHES: Geography in New Zealand edited by P. G. Holland and W. B. Johnston. 17 × 25 cm, 361 pages. New Zealand Geographical Society: Christchurch 1987 (ISBN 0 9597 863 0 9) $A56.50 (soft).