The use of proxy chemical records in Coral skeletons to ascertain past environmental conditions in Florida Bay

This paper will discuss the use of chemical proxies in coral skeletons to reconstruct the history of salinity (from the δ¹⁸O of the skeleton) and nutrients in the water (from the δ¹³C) in Florida Bay between 1824 and 1994. Monthly salinity and water temperature data collected since 1989 were used to establish a correlation between salinity, temperature, and the δ¹⁸O of the skeleton of the coralSolenastrea bournoni from Lignumvitae Basin in Florida Bay. This relationship explains over 50% of the variance in the δ¹⁸O of the skeleton. Assuming that interannual variations in the temperature of the water are small, we have applied this relationship to the δ¹⁸O measured in the coral skeleton collected from Lignumvitae Basin which has a record between 1824 and 1993. These data provide a revised estimate of salinity variation in Lignumvitae Basin for the period when historical records for salinity were not available, and show that the highest salinity events occurred in the past 30 yr. Using the relationships between the salinity in Lignumvitate Basin and other basins, obtained using a modern dataset, we are able to estimate ranges in salinity for other portions of Florida Bay. Skeletons of specimens of the coral speciesSiderastrea radians collected from other areas of Florida Bay show similar patterns in the δ¹⁸O over the past 10 yr, indicating that corals in most portions of Florida Bay are recording salinity variations in their skeletons and therefore support the idea that salinity variations in different portions of Florida Bay can be related. Fluorescence analysis of the coral from Lignumvitae Basin shows a large change in the magnitude of the 10-yr signal coincident with the construction of the railway, confirming that this event had a significant impact upon Florida Bay. The δ¹³C of the coral skeletons reveals a long-term history of the oxidation of organic material, fixation of carbon by photosynthesis (algal blooms), and the intrusion of marine water into the bay. Since the construction of the railway from Miami to Key West there has been a long-term decrease in the δ¹³C of the coral skeleton from Lignumvitae Basin, suggesting the increased oxidation of organic material in this area. This decrease in δ¹³C appears to have reached a minimum value around 1984 and has increased since this time in the western portions of Florida Bay. The increase may be related to the algal blooms prevalent in the area or alternatively could result from intrusion of more marine water. In the eastern areas, a small increase in the δ¹⁸C between 1984 and 1988 was followed by further decline suggesting more oxidation of organic material. We have also attempted to use the concentration of barium in the coral skeleton as a proxy indicator of the nutrient status in Florida Bay.     

Investigation and Remediation of a 1,2-Dichloroethane Spill Part II: Documentation of Natural Attenuation

A release of 1,2-dichloroethane. also known as ethylene dichloride (EDC), resulted in shallow subsurface freephase contamination of a Gulf Coast site in the southern United States. The site stratigraphy consists primarily of a low permeability, surficial peat. silt, and clay zone underlain by fractured clay; a confined 12 in deep sand ground water flow zone; a confined 21 m deep fine sand zone of limited ground water flow, followed by a deep aquitard. The Gumbo clay and sandy clay aquitard below the release area overlies and protects the 61 m deep Upper Chicot Aquifer, which is a confined regional aquifer. An ongoing recovery and hydraulic containment program from the primary impacted and laterally and vertically restricted shallow 40-foot sand zone has effectively recovered dense nonaqueous phase liquid (DNAPL) and contained dissolved phase EDC.
Natural attenuation of EDC was demonstrated through (1) a laboratory microcosm study substantiating the ability of the native microbial population in the deeper aquifer lo degrade EDC under anaerobic environmental conditions found at the site. (2) field investigations showing reductions in EDC concentrations over time in many of the wells on site, and (3) an evaluation of the ground water for EDC and its degradation products and oilier geo-chemical parameters such as dissolved oxygen, redox potential, and pH. Degradation products of EDC found in the field investigations included 2-chloroeihanol, ethanol. ethene, and ethane. Dissolved EDC concentrations in selected wells between the first recorded samples and the fourth quarter of 1997 ranged from greater than 4% to 99% reductions. First-order exponential decay half-lives ranged from 0.21 to 4.2 years for wells showing decreases in FDC concentrations over time. Elevated methane concentrations indicated carbon dioxide to be the major terminal electron acceptor.     

MoisturEC: A New R Program for Moisture Content Estimation from Electrical Conductivity Data

Noninvasive geophysical estimation of soil moisture has potential to improve understanding of flow in the unsaturated zone for problems involving agricultural management, aquifer recharge, and optimization of landfill design and operations. In principle, several geophysical techniques (e.g., electrical resistivity, electromagnetic induction, and nuclear magnetic resonance) offer insight into soil moisture, but data‐analysis tools are needed to “translate” geophysical results into estimates of soil moisture, consistent with (1) the uncertainty of this translation and (2) direct measurements of moisture. Although geostatistical frameworks exist for this purpose, straightforward and user‐friendly tools are required to fully capitalize on the potential of geophysical information for soil‐moisture estimation. Here, we present MoisturEC, a simple R program with a graphical user interface to convert measurements or images of electrical conductivity (EC) to soil moisture. Input includes EC values, point moisture estimates, and definition of either Archie parameters (based on experimental or literature values) or empirical data of moisture vs. EC. The program produces two‐ and three‐dimensional images of moisture based on available EC and direct measurements of moisture, interpolating between measurement locations using a Tikhonov regularization approach.     

Colloid particle sizes in the Mississippi River and some of its tributaries,from Minneapolis to below New Orleans

An on-board technique was developed that combined discharge-weighted pumping to a high-speed continuous-flow centrifuge for isolation of the particulate-sized material with ultrafiltration for isolation of colloid-sized material. In order to address whether these processes changed the particle sizes during isolation, samples of particles in suspension were collected at various steps in the isolation process to evaluate changes in particle size. Particle sizes were determined using laser light-scattering photon correlation spectroscopy and indicated no change in size during the colloid isolation process. Mississippi River colloid particle sizes from twelve sites from Minneapolis to below New Orleans were compared with sizes from four tributaries and three seasons, and from predominantly autochthonous sources upstream to more allochthonous sources downstream. © 1998 John Wiley & Sons, Ltd.     

An ethnoarchaeological study of chemical residues in the floors and soils of Q'eqchi' Maya houses at Las Pozas,Guatemala

This ethnoarchaeological study at the Q'eqchi' Maya village of Las Pozas, Guatemala, aimed to refine the understanding of the relationship between soil chemical signatures and human activities for archaeological applications. The research involved phosphorus, exchangeable ion (calcium, potassium, magnesium, sodium), and trace element analysis of soils and earth floors extracted by Mehlich II, ammonium acetate, and DTPA chelate solutions, respectively. The results showed high levels of phosphorus, potassium, magnesium, and pH in food preparation areas, as well as high phosphorus concentrations and low pH in food consumption areas. The traffic areas exhibited low phosphorus and trace element contents, whereas refuse disposal areas were enriched. These results provide important information for the understanding of space use in ancient settlements. © 2002 Wiley Periodicals, Inc.     

Rare earth element composition of Paleogene vertebrate fossils from Toadstool Geologic Park,Nebraska, USA

Fossil bones and teeth from terrestrial environments encode unique rare earth and trace element (REE and TE) signatures as a function of redox conditions, pH, concentrations of complexing ligands, and water-colloid interactions. This signature is set early in the fossilization process and serves as a paleoenvironmental and paleoclimatic proxy. These signatures can also be used to interpret temporal and spatial averaging within vertebrate accumulations, and can help relocate displaced fossil bones back into stratigraphic context. Rare earth elements in vertebrate fossils from upper Eocene and Oligocene strata of Toadstool Geologic Park, northwestern Nebraska, record mixing and evolution of Paleogene vadose or groundwaters and variations in paleoenvironments. REE signatures indicate that HREE-enriched alkaline groundwater reacted with LREE- and MREE-enriched sediments to produce 3-component mixtures. REE signatures become increasingly LREE- and MREE-enriched toward the top of the studied section as the paleoenvironment became cooler and drier, suggesting that REE signatures may be climate proxies. Time series analysis suggests that REE ratios are influenced by cycles of ca. 1050, 800, 570, 440, and 225 ka, similar to some previously determined Milankovitch astronomical and climate periodicities.     

Strike-slip fault patterns on Europa: Obliquity or polar wander?

Variations in diurnal tidal stress due to Europa’s eccentric orbit have been considered as the driver of strike-slip motion along pre-existing faults, but obliquity and physical libration have not been taken into account. The first objective of this work is to examine the effects of obliquity on the predicted global pattern of fault slip directions based on a tidal-tectonic formation model. Our second objective is to test the hypothesis that incorporating obliquity can reconcile theory and observations without requiring polar wander, which was previously invoked to explain the mismatch found between the slip directions of 192 faults on Europa and the global pattern predicted using the eccentricity-only model. We compute predictions for individual, observed faults at their current latitude, longitude, and azimuth with four different tidal models: eccentricity only, eccentricity plus obliquity, eccentricity plus physical libration, and a combination of all three effects. We then determine whether longitude migration, presumably due to non-synchronous rotation, is indicated in observed faults by repeating the comparisons with and without obliquity, this time also allowing longitude translation. We find that a tidal model including an obliquity of 1.2°, along with longitude migration, can predict the slip directions of all observed features in the survey. However, all but four faults can be fit with only 1° of obliquity so the value we find may represent the maximum departure from a lower time-averaged obliquity value. Adding physical libration to the obliquity model improves the accuracy of predictions at the current locations of the faults, but fails to predict the slip directions of six faults and requires additional degrees of freedom. The obliquity model with longitude migration is therefore our preferred model. Although the polar wander interpretation cannot be ruled out from these results alone, the obliquity model accounts for all observations with a value consistent with theoretical expectations and cycloid modeling.     

Modeling Variably Saturated Subsurface Solute Transport with MODFLOW‐UZF and MT3DMS

The MT3DMS groundwater solute transport model was modified to simulate solute transport in the unsaturated zone by incorporating the unsaturated‐zone flow (UZF1) package developed for MODFLOW. The modified MT3DMS code uses a volume‐averaged approach in which Lagrangian‐based UZF1 fluid fluxes and storage changes are mapped onto a fixed grid. Referred to as UZF‐MT3DMS, the linked model was tested against published benchmarks solved analytically as well as against other published codes, most frequently the U.S. Geological Survey's Variably‐Saturated Two‐Dimensional Flow and Transport Model. Results from a suite of test cases demonstrate that the modified code accurately simulates solute advection, dispersion, and reaction in the unsaturated zone. Two‐ and three‐dimensional simulations also were investigated to ensure unsaturated‐saturated zone interaction was simulated correctly. Because the UZF1 solution is analytical, large‐scale flow and transport investigations can be performed free from the computational and data burdens required by numerical solutions to Richards' equation. Results demonstrate that significant simulation runtime savings can be achieved with UZF‐MT3DMS, an important development when hundreds or thousands of model runs are required during parameter estimation and uncertainty analysis. Three‐dimensional variably saturated flow and transport simulations revealed UZF‐MT3DMS to have runtimes that are less than one tenth of the time required by models that rely on Richards' equation. Given its accuracy and efficiency, and the wide‐spread use of both MODFLOW and MT3DMS, the added capability of unsaturated‐zone transport in this familiar modeling framework stands to benefit a broad user‐ship.