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11.
Terry L. Wade Yousra Soliman Stephen T. Sweet Gary A. Wolff Bobby J. Presley 《Deep Sea Research Part II: Topical Studies in Oceanography》2008,55(24-26):2585
The concentrations of polycyclic aromatic hydrocarbons (PAHs) and trace elements were determined for surface (top 2 cm) sediment samples collected during the deep Gulf of Mexico benthos (DGoMB) study .These elements and compounds are known to be toxic to organisms at high concentrations and may affect biological communities. There is no indication of major anthropogenic input of the elements Be, Co, Cr, Fe, Si, Tl, V, K, Mg, Ca, Sr and Zn, based on normalization to Al. The concentrations of these metals in the sediment are a function of the relative amounts of trace-metal-rich Mississippi River-derived silicate material and trace-metal-poor plankton-derived carbonate. This is not true for the elements Ba, Ni, Pb, Cd, As, Cu and Mn, whose concentrations show considerable scatter when normalized to Al and a general enrichment. On a normalized basis, Mn is enriched 5–10 fold, Cu and Ni 2–3 fold and Pb 2 fold over Mississippi River-derived material. These enrichments are likely the result of remobilization of metals from depths in the sediment column where reducing conditions exist. The Ba concentrations at selected sites are higher than those of average clay-rich sediments, but are typical of sediments from near oil well platforms in the northern Gulf of Mexico. In the case of Ba, it seems likely that the enrichments, as high as a factor of 10, are due to disposal of oil well drilling mud. The Ba-enriched samples are from the three shallowest water sites in the Mississippi Trough (sites MT1, 2 and 3) and from site C1 and WC5. All are in an area of intense petroleum exploration and development. PAH concentrations are also elevated at MT1, MT3 and C1. The total PAH concentration ranged from not detected (ND) to 1033 ng/g with a mean of 140 ng/g. Even at the sites most enriched in PAHs and trace elements, the concentrations are not at the levels expected to adversely affect the biota. However, these predicted non-effects are based on research using mostly near-shore estuarine species, not on the indigenous species at the sampling sites. 相似文献
12.
The frictional behavior of lizardite and antigorite serpentinites: Experiments,constitutive models,and implications for natural faults 总被引:2,自引:0,他引:2
Laboratory studies of the frictional behavior of rocks can provide important information about the strength and sliding stability of natural faults. We have conducted friction experiments on antigorite and lizardite serpentinites, rocks common to both continental and oceanic crustal faults. We conducted both velocity-step tests and timed-hold tests on bare surfaces and gouge layers of serpentinite at room temperature. We find that the coefficient of friction of lizardite serpentinite is quite low (0.15–0.35) and could explain the apparent low stresses observed on crustal transform faults, while that of antigorite serpentinite is comparable to other crustal rocks (0.50–0.85). The frictional behavior of both types of serpentinite is well described by a two-mechanism model combining state-variable-dominated behavior at high slip velocities and flow-dominated behavior at low velocities. The two-mechanism model is supported by data from velocity-step tests and timed-hold tests. The low velocity behavior of serpentinite is strongly rate strengthening and should result in stable fault creep on natural faults containing either antigorite or lizardite serpentinite. 相似文献
13.
Christian E. Schlekat Beth L. McGee Eli Reinharz David J. Velinsky Terry L. Wade 《Estuaries and Coasts》1994,17(2):334-344
Sediment toxicity and benthic macroinvertebrate community structure were measured as one component of a study cohceived to determine the distribution and effect of sediment contamination in tidal freshwater portions of the Potomac and Anacostia rivers in the Washington, D.C., area. Samples were collected at 15 sites. Analyses included a partial life cycle (28 d) whole sediment test using the amphipod Hyalella azteca (Talitridae) and an assessment of benthic community structure. Survival and growth (as estimated by amphipod length) were experimental endopoints for the toxicity test. Significant mortality was observed in 5 of 10 sites in the lower Anacostia River basin and at the main channel Potomac River site. Sublethal toxicity, as measured by inhibition of amphipod growth, was not observed. Toxicity test results were in general agreement with synoptically measured sediment contaminant concentrations. Porewater total ammonia (NH3+NH4 +) appears to be responsible for the toxicity of sediments from the Potomac River, while correlation analysis and simultaneously extracted metals: acid volatile sulfide (SEM∶AVS) results suggest that the toxicity associated with Anacostia River sediments was due to organic compounds. Twenty-eight macroinvertebrate taxa were identified among all sites, with richness varying from 5 to 17 taxa per site. Groups of benthic assemblages identified by group-average cluster analysis exhibited variable agreement with sediment chemical and sediment toxicity results. Integration of toxicological, chemical, and ecological components suggests that adverse environmental effects manifest in the lower Anacostia River benthos result from chemical contamination of sediment. 相似文献
14.
15.
Majid Ehteshami Richard C. Peralta Hubert Eisele Howard Deer Terry Tindall 《Ground water》1991,29(6):862-868
16.
Water-column surveys by combined nephelometer/CTD (NCTD) tows contributed to the 1985 discovery of the first black smokers on the Mid-Atlantic Ridge. Subsequent regional water-column mapping has helped define the extent, mass and interactions of the suspended particulate matter phase (SPM) of the hydrothermal plumes emanating from the known and other nearby sources. The results of 29 NCTD cast/tows, covering 25–30 km2 of ridge segment, indicate the presence of as many as two additional sources based on SPM concentration gradients and plume-top doming over source areas. Plume doming, documented here for the first time from field observations, conforms strikingly with laboratory experiments and can serve as a marker for source field location. A comparison of the plumes' SPM with potential temperature and salinity distributions indicates close correlation in water-column anomaly patterns for each, confirming modification of the regional potential temperature and salinity structure by hydrothermal plumes, which is expressed by wide separation and sloping of isotherms and isohalines. 相似文献
17.
The style of deformation in thin-skinned fold-and-thrust belts is critically dependent upon the resistance to sliding along the detachment between the mass of deforming sediments and the underlying rocks. Evaporites can provide an extremely weak horizon within which a basal detachment can form and along which only a relatively small shear traction can be supported. Fold-and-thrust belts that form atop a salt layer, such as the Appalachian Plateau, the Franklin Mountains in northwestern Canada, and the Jura of the Alps, among others, share several readily observable characteristics. As predicted by a simple mechanical model for fold-and-thrust belts, a detachment in salt permits a thrust belt to have an extremely narrow cross-sectional taper. In addition, predicted orientations of the principal stress axes over a salt décollement are consistent with the commonly observed lack of a consistently dominant vergence direction of structures within the thrust belt. Other common attributes of salt-basal thin-skinned deformation include the presence of several widely but regularly spaced folds and abrupt changes in deformational style at the edge of the salt basin. 相似文献
18.
Weathered granite extends 70 m deep at Hi Vista in the arid central Mojave Desert of southern California. The low strength of this granite is due to the alteration of biotite and chlorite montmorillonite. Deep weathering probably occurs in most granites, although we cannot rule out some anomalous mechanisms at Hi Vista. Geophysical instruments set in these slightly altered rocks are limited by the unstable behavior of the rocks. Thus, tectonic signals from instruments placed in shallow boreholes give vague results. Geophysical measurements of these weathered rocks resemble measurements of granitic rocks near major faults. The rheology of the rocks in which instruments are placed limits the useful sensitivity of the instruments. 相似文献
19.
20.
Chemical and mineralogical studies of fresh and hydrothermally altered rhyolitic material in Upper and Lower Geyser Basins, Yellowstone National Park, show that all the altered rocks are enriched in Cs and that Cs is selectively concentrated in analcime. The Cs content of unaltered rhyolite lava flows, including those from which the altered sediments are derived, ranges from 2.5 to 7.6 ppm. The Cs content of analcime-bearing altered sedimentary rocks is as high as 3000 ppm, and in clinoptilolite-bearing altered sedimentary rocks Cs content is as high as 180 ppm. Altered rhyolite lava flows which were initially vitrophyres, now contain up to 250 ppm Cs, and those which were crystallized prior to hydrothermal alteration contain up to 14 ppm. Mineral concentrates of analcime contain as much as 4700 ppm Cs. The Cs must have been incorporated into the analcime structure during crystallization, rather than by later cation substitution, because analcime does not readily exchange Cs. The of the fluids circulating through the hydrothermal system varies, suggesting that Cs is not always a conservative ion and that Cs is lost from upflowing thermal waters due to water-rock interaction resulting in crystallization of Cs-bearing analcime.The source of Cs for Cs enrichment of the altered rocks is from leaching of rhyolitic rocks underlying the geyser basins, and from the top of the silicic magma chamber that underlies the area.Analcime is an important natural Cs sink, and the high Cs concentrations reported here may prove to be an important indicator of the environment of analcime crystallization. 相似文献