Triassic stretching directions in Iberia and North Africa inferred from magnetic fabrics

During the Triassic, Iberia and western North Africa displayed a unique situation in relation with the Central and North Atlantic opening and westward expansion of the Tethys. Unravelling the stretching direction in Triassic deposits of the studied area can help in our understanding of this scenario. The tectonic setting is characterized by localized basins with strong thickness variations greatly influenced by previous post‐Variscan mechanical discontinuities. In this work, we revise and compile magnetic fabric data from eight Triassic depocentres in terms of defining the stretching direction (i.e. magnetic lineation), resulting from extensional deformation of this period. Data show the importance of the opening of the Atlantic rift as the leading process during the Triassic. Dextral transtension can explain the deflection of the extensional direction observed in most studied depocentres that is caused by the activity of previous major oblique faults.     

Stratigraphic evolution of the Triassic–Jurassic succession in the Western Southern Alps (Italy): the record of the two-stage rifting on the distal passive margin of Adria

The Triassic–Lower Jurassic succession of the Southern Alps is characterized by rapid thickness changes, from an average of about 5000 m east of Lago Maggiore to about 500 m in the Western Southern Alps. The stratigraphy reflects the Triassic evolution of the Tethyan Gulf and the Early Jurassic rifting responsible for the Middle Jurassic break‐up of Adria from Europe. The succession of the Western Southern Alps starts with Lower Permian volcanics directly covered by Anisian sandstones. The top of the overlying Ladinian dolostones (300 m) records subaerial exposure and karstification. Locally (Gozzano), Upper Sinemurian sediments cover the Permian volcanics, documenting pre‐Sinemurian erosion. New biostratigraphic data indicate a latest Pliensbachian–Toarcian age for the Jurassic synrift deposits that unconformably cover Ladinian or Sinemurian sediments. Therefore, in the Western Southern Alps, the major rifting stage that directly evolved into the opening of the Penninic Ocean began in the latest Pliensbachian–Toarcian. New data allowed us to refine the evolution of the two previously recognized Jurassic extensional events in the Southern Alps. The youngest extensional event (Western Southern Alps) occurred as tectonic activity decreased in the Lombardy Basin. During the Sinemurian the Gozzano high represents the western shoulder of a rift basin located to the east (Lombardy). This evolution documents a transition from diffuse early rifting (Late Hettangian–Sinemurian), controlled by older discontinuities, to rifting focused along a rift valley close to the Pliensbachian–Toarcian boundary. This younger rift bridges the gap between the Hettangian–Sinemurian diffuse rifting and the Callovian–Bathonian break‐up. The late Pliensbachian–Toarcian rift, which eventually lead to continental break‐up, is interpreted as the major extensional episode in the evolution of the passive margin of Adria. The transition from diffuse to focused extension in the Southern Alps is comparable to the evolution of the Central Austroalpine during the Early Jurassic and of the Central and Northern Atlantic margins.     

Modelling and migration with orthogonal isochron rays

For increasing time values, isochrons can be regarded as expanding wavefronts and their perpendicular lines as the associated orthogonal isochron rays. The speed of the isochron movement depends on the medium velocity and the source-receiver position. We introduce the term equivalent-velocity to refer to the speed of isochron movement. In the particular case of zero-offset data, the equivalent velocity is half of the medium velocity. We use the concepts of orthogonal isochron-rays and equivalent velocity to extend the application of the exploding reflector model to non-zero offset imaging problems. In particular, we employ these concepts to extend the use of zero-offset wave-equation algorithms for modelling and imaging common-offset sections. In our imaging approach, the common-offset migration is implemented as a trace-by-trace algorithm in three steps: equivalent velocity computation, data conditioning for zero-offset migration and zero-offset wave-equation migration. We apply this methodology for modelling and imaging synthetic common-offset sections using two kinds of algorithms: finite-difference and split-step wavefield extrapolation. We also illustrate the isochron-ray imaging methodology with a field-data example and compare the results with conventional common-offset Kirchhoff migration. This methodology is attractive because it permits depth migration of common-offset sections or just pieces of that by using wave-equation algorithms, it extends the use of robust zero-offset algorithms, it presents favourable features for parallel processing, it permits the creation of hybrid migration algorithms and it is appropriate for migration velocity analysis.     

Comparison of marine and river water humic substances in a Patagonian environment (Argentina)

Structural aspects of humic substances (HSs) in marine waters of Engaño Bay (Atlantic Ocean) and water from the Chubut River (Patagonia, Argentina) were compared. The HSs were isolated, purified, and analyzed using a multiple-method approach for structural characterization: elemental analysis, nuclear magnetic resonance (¹³C and ¹H NMR), infrared spectroscopy (FTIR), UV-visible absorption and fluorescence. Similarities between the marine and freshwater components were evaluated on the basis of N and O contents, H/C and C/N atomic ratios, infrared bands from nitrogen-containing and carboxylic groups, percentage of functional groups obtained from NMR spectra, spectral slope coefficient of absorption spectra, absorbance ratios at 250 and 365 nm (E ₂/E ₃), aromaticity, excitation–emission matrices and fluorescence quantum yield. Both the Engaño Bay and Chubut River waters have HSs that are mainly composed of fulvic acids (FAs); although they are very similar, they may be distinguished from one another. Similarities include the predominance of aliphatic carbon content (low aromatic content); however, the water bodies differed in their content of proteins and carboxylic acids. The Engaño Bay FAs have mainly an aquatic origin; although the Chubut River FAs suggest a similar aquagenic origin, there is also evidence of contributions from pedogenic FAs.     

The distal segment of Etna’s 2001 basaltic lava flow

Etna’s 2001 basaltic lava flow provided a good example of the distal flow segment between the flow front and stable channel, across which the flow evolves from channel-contained to dispersed. This zone was mapped with meter precision using LIDAR data collected during 2004 and 2005. These data, supported by field mapping, show that the flow front comprised eight lobes each 10 to 20 m high. The flow front appears to have advanced not as a single unit, but as a series of lobes moving forward one lobe at a time. Primary lobes were centered on the channel axis and marginal lobes were off-axis. The lobes advanced as breakouts of low-yield-strength lava from the flow core of the stalled flow front. Marginal lobes were abandoned and contributed to marginal levees flanking the transitional channel. For Etna’s 2001 flow, the transitional channel is 140 m wide, 700 m long and fed a 240-m-long zone of dispersed flow; the change from stable to transitional channel occurred at a major reduction in slope. Above this, the stable channel is 5.2 km long, 55 to 105 m wide and bounded by 15- to 25-m-high levees, and the stable channel is located over a previous channel. In a final stage of activity, lava ponding at the break-in-slope that marks the terminus of the stable channel put pressure on the eastern levee, causing it to fail. Liberated lava then fed a final break-out to the east. Similar flow front-features occur at other volcanoes, indicating that similar processes are characteristic of dispersed flow zones.     

Inorganic As speciation and bioavailability in estuarine sediments of Todos os Santos Bay, BA, Brazil

The spatial distribution of As (total As, As (III) and As (V)) in estuarine sediments from the main tributaries of Todos os Santos Bay, BA, Brazil, was evaluated under high and low flow conditions. The concentrations of As were determined using a slurry sampling procedure with hydride generation atomic absorption spectrometry (HG-AAS). The highest concentrations were observed at estuary mouths, and exceeded conservative lower threshold value (Threshold Effects Level; TEL). Due to the oxic conditions and abundance of Mn and Fe (oxyhydr)oxides in the sediments, most inorganic arsenic in the Subaé and Paraguaçu estuaries was present as As (V). Nevertheless, the concentration of As (III) at several locations along the Jaguaripe River were also above the TEL value, suggesting that As may be toxic to biota. In the Subaé estuary, antropogenic activities are the main source of As. At the Jaguaripe and at Paraguaçu estuaries, nevertheless, natural sources of As need to be considered to explain the distribution patterns.     

Assessing Seismic Damage Through Stochastic Simulation of Ground Shaking: The Case of the 1998 Faial Earthquake (Azores Islands)

In July 1998, an M _w = 6.2 earthquake struck the islands of Faial, Pico and San Jorge (in the Azores Archipelago), registering VIII on the Modified Mercalli Intensity scale and causing major destruction in the northeastern part of Faial. The main shock was located offshore, 8 km North East of the island, and it triggered a seismic sequence that lasted for several weeks. The existing data for this earthquake include both the general tectonic environment of the region and the teleseismic information. This is accompanied by one strong-motion record obtained 15 km from the epicentre, the epicentre location of aftershocks, and a large collection of the damage inflicted to the building stock (as poor rubble masonry, of 2–3 storeys). The present study was carried out in two steps: first, with a finite-fault stochastic simulation method of ground motion at sites throughout the affected islands, for two possible locations of the rupturing fault and for a large number of combinations of rupture mechanisms (as a parametric analysis); secondly, the damage to buildings was modelled using a well-known macroseismic method that considers the building typologies and their associated vulnerabilities. The main intent was to integrate different data (geological, seismological and building features) to produce a scenario model to reproduce and justify the level of damage generated during the Faial earthquake. Finally, through validation of the results provided by these different approaches, we obtained a complete procedure for the parameters of a first model for the production of seismic damage scenarios for the Azores Islands region.     

Geomorphic indices and relative tectonic uplift in the Guerrero sector of the Mexican forearc

Tectonically active areas, such as forearc regions, commonly show contrasting relief, differential tectonic uplift, variations in erosion rates, in river incision, and in channel gradient produced by ongoing tectonic deformation. Thus, information on the tectonic activity of a defined area could be derived via landscape analysis. This study uses topography and geomorphic indices to extract signals of ongoing tectonic deformation along the Mexican subduction forearc within the Guerrero sector. For this purpose, we use field data, topographical data, knickpoints, the ratio of volume to area (R_VA), the stream-length gradient index (SL), and the normalized channel steepness index (k_sn).The results of the applied landscape analysis reveal considerable variations in relief, topography and geomorphic indices values along the Guerrero sector of the Mexican subduction zone. We argue that the reported differences are indicative of tectonic deformation and of variations in relative tectonic uplift along the studied forearc. A significant drop from central and eastern parts of the study area towards the west in values of R_VA (from ～500 to ～300), SL (from ～500 to ca. 400), maximum SL (from ～1500–2500 to ～1000) and k_sn (from ～150 to ～100) denotes a decrease in relative tectonic uplift in the same direction. We suggest that applied geomorphic indices values and forearc topography are independent of climate and lithology. Actual mechanisms responsible for the observed variations and inferred changes in relative forearc tectonic uplift call for further studies that explain the physical processes that control the forearc along strike uplift variations and that determine the rates of uplift. The proposed methodology and results obtained through this study could prove useful to scientists who study the geomorphology of forearc regions and active subduction zones.     

Magnetic properties of surface sediments as proxies of recent anthropogenic pollution in the Anllóns riverbed (NW Spain)

A study of surface sediments from the Anllóns riverbed (northwestern Spain) was conducted to assess the use of their magnetic properties as proxies of recent trace element contamination (i.e., As, Zn, Pb, Cr, Ni and Cu). Thermomagnetic curves, hysteresis parameters, specific magnetic susceptibility χ, frequency-dependent magnetic susceptibility κ _FD%, magnetic remanence and saturation isothermal remanent magnetization ratios (i.e., S and SIRM/χ) reveal the presence of mostly fine-grained magnetite and maghemite in these samples. The Tomlinson Pollution Load Index (PLI), as well as the magnetic parameters χ, κ _FD%, SIRM/χ and S-ratios, vary more or less in agreement to each other when they are sequentially arranged throughout a 30-km-long transect that goes from the town of Carballo to the river mouth in Ponteceso. From that profile, it is possible to identify an anomaly of χ that lies between two small peaks of the PLI and seems to define a contaminated area probably linked to a diffuse low-impact source of pollution. There is also a conspicuous peak of the PLI that is likely associated to a nearby gold mine. The variations of the κ _FD%’s along the transect are the ones that best reflect the changes in the PLI values, regardless of the level of contamination. This result suggests that adsorption is the main mechanism of trace elements removal by Fe oxides in these samples. Direct signal analyses, used to decompose the isothermal remanent magnetization curves, reveal the presence of four magnetic fractions, with varying relative concentrations all over the profile, namely single-domain magnetite, close to the superparamagnetic threshold (SD/SP) and/or maghemite (\(\log B_{1/2}\) ca 1.2), single-domain magnetite (\(\log B_{1/2}\) ca 2), hematite (\(\log B_{1/2}\) ca 2.5) and goethite (\(\log B_{1/2}\) ca 3.5). Integrating all the available information, it was sketched out a likely sequence of events that included magnetic minerals neoformation in parent soils, their subsequent chemical transformations and the contamination episodes that affected the region.     

Topological redundancy and ‘small‐world’ patterns in a food web in a subtropical ecosystem of Brazil

According to graph theory, the frequency distribution of trophic interactions within a food web has deep structural implications, as it can highlight the presence of patterns associated with the web and indicate whether the properties of the web are independent of its size. A hypothesis is that ‘small‐world’ food webs are sensitive to the loss of species with the highest values. Therefore, the present work aimed to evaluate the degree to which a subtropical food web in Southern Brazil displays small‐world patterns and their resistance. As part of the assessment, we evaluated the topological redundancy values of species in the food web and then we simulated the exclusion of these species (such as sharks and sea birds), and also the exclusion of high centrality species (such as squids Loligo sp., portunid swimming crabs and the cutlassfish Trichiurus lepturus). The food web showed a ‘broad‐scale’ distribution of connections by node, and a small‐world pattern. As expected, a simplification of the network was observed after elimination of some species with high centrality. However, the food web was resistant to the loss of species with low topological redundancy, probably because these species occupy a high trophic level and do not participate in lots of routes within the food web. We highlight however, the importance of the application of multiple analyses to evaluate the importance of components in food webs, and fisheries management plans should consider both species of high centrality values and species with low topological redundancy.