Mineralogical characterization of Baptistina Asteroid Family: Implications for K/T impactor source

Bottke et al. [Bottke, W.F., Vokrouhlicky, D., Nesvorný, D., 2007. Nature 449, 48–53] linked the catastrophic formation of Baptistina Asteroid Family (BAF) to the K/T impact event. This linkage was based on dynamical and compositional evidence, which suggested the impactor had a composition similar to CM2 carbonaceous chondrites. However, our recent study [Reddy, V., Emery, J.P., Gaffey, M.J., Bottke, W.F., Cramer, A., Kelley, M.S., 2009. Meteorit. Planet. Sci. 44, 1917–1927] suggests that the composition of (298) Baptistina is similar to LL-type ordinary chondrites rather than CM2 carbonaceous chondrites. This rules out any possibility of it being related to the source of the K/T impactor, if the impactor was of CM-type composition. Mineralogical study of asteroids in the vicinity of BAF has revealed a plethora of compositional types suggesting a complex formation and evolution environment. A detailed compositional analysis of 16 asteroids suggests several distinct surface assemblages including ordinary chondrites (Gaffey SIV subtype), primitive achondrites (Gaffey SIII subtype), basaltic achondrites (Gaffey SVII subtype and V-type), and a carbonaceous chondrite. Based on our mineralogical analysis we conclude that (298) Baptistina is similar to ordinary chondrites (LL-type) based on olivine and pyroxene mineralogy and moderate albedo. S-type and V-type in and around the vicinity of BAF we characterized show mineralogical affinity to (8) Flora and (4) Vesta and could be part of their families. Smaller BAF asteroids with lower SNR spectra showing only a ‘single’ band are compositionally similar to (298) Baptistina and L/LL chondrites. It is unclear at this point why the silicate absorption bands in spectra of asteroids with formal family definition seem suppressed relative to background population, despite having similar mineralogy.     

Caveats on tomographic images

Geological and geodynamic models of the mantle often rely on joint interpretations of published seismic tomography images and petrological/geochemical data. This approach tends to neglect the fundamental limitations of, and uncertainties in, seismic tomography results. These limitations and uncertainties involve theory, correcting for the crust, the lack of rays throughout much of the mantle, the difficulty in obtaining the true strength of anomalies, choice of what background model to subtract to reveal anomalies, and what cross‐sections to select for publication. The aim of this review is to provide a relatively non‐technical summary of the most important of these problems, collected together in a single paper, and presented in a form accessible to non‐seismologists. Appreciation of these issues is essential if final geodynamic models are to be robust, and required by the scientific observations.     

Imaging heterogeneity of the crust adjacent to the Dead Sea fault using ambient seismic noise tomography

For the purpose of studying the Earth’s crust by means of tomography, we investigated cross-correlation functions emerging from long-term observations of propagating ambient seismic noise at pairs of broadband stations in Israel and Jordan. The data was provided by the eight permanent broadband stations of the Israel Seismic Network evenly distributed over Israel and the 30 stations of the DESERT2000 experiment distributed across the Arava Fault (South of the Dead Sea basin). To eliminate the influence of earthquakes and explosions, we have applied the methodology of Bensen et al. (Geophys J Int 169:1239–1260, 2007), including bandpass filtering and amplitude normalization in time and frequency domain. The cross-correlation functions estimated from continuous recordings of a few months were used to extract Rayleigh waves group velocity dispersion curves using automatic version of the frequency–time analysis procedure. Subsequently, these curves have been converted into the Rayleigh wave group velocity maps in the period range 5–20 s and S waves velocity maps in the depth range 5–15 km. In these maps, four velocity anomalies are prominent. Two of them are outlined by the previous reflection-refraction profiles and body wave tomography studies, i.e. a low velocity anomaly corresponds to the area of the extremely deep (down to 14 km) sedimentary infill in the Southern Dead Sea Basin and a high velocity anomaly in the Southern Jordan corresponds to the area of the Precambrian crystalline rocks of the Nubian Shield on the flanks of the Red Sea. The two other anomalies have not been reported before - the high velocity zone close to the Beersheba city and the low velocity anomaly in the region of Samaria-Carmel mountains - Southern Galilee. They have relatively low resolution and hence need further investigations for approving and contouring. The highest contrast between the average Rayleigh wave group velocity (2.7 km/s) and the anomalies is 10–13 %, comparable, however, to the level of noise in the data. The results have been verified by modeling the revealed anomalies which showed that all the four zones mentioned above could be detected by the tomography study.     

An initial formal model for spatial data infrastructures

The Commission on Spatial Data Standards of the International Cartographic Association is working to define formal models and technical characteristics of Spatial Data Infrastructures (SDI). To date, this work has been restricted to the Enterprise and Information Viewpoints from the ISO Reference Model for Open Distributed Processing standard. The Commission has developed models for these two viewpoints. These models describe how the different parts of an SDI fit together in the viewpoints in question. These models should be seen as a contribution towards the overall model of the SDI and its technical characteristics. During the model development process, the roles of the different Actors in an SDI in the Enterprise and Information Viewpoints have also been identified in Use Case diagrams of an SDI. All the models have been developed using the Unified Modeling Language.     

Vegetation indices changes in the cloud forest of La Gomera Island (Canary Islands) and their hydrological implications

Vegetation indices derived from remote sensing data still remain to be used for analysing the relationship between climatic factors and vegetation seasonal phenology in middle latitudes with subtropical conditions forests such as the Canarian laurel forest. The Garajonay National Park, located in the La Gomera Island, protects one of the best preserved examples of the Macaronesian laurel forest, due to the cloud banks produced by trade winds, with rainfall and temperature field data showing a clear Mediterranean climatic pattern. We have analysed seasonal vegetation indices trend for different types of forest inside the Garajonay National Park using normalized difference vegetation index (NDVI) and enhanced vegetation index (EVI) products derived from moderate resolution imaging spectrometer (MODIS) Aqua data for two hydrological years (October 2003 to September 2005) in relationship with the existing field climatic data: rainfall, net fog water and temperature. Maximum annual EVI maps show the highest vegetation indices in the laurel forest of La Gomera that occur during the dry season, mainly in late spring to early summer, with EVI temporal profiles showing that valley‐bottom laurel forest areas have the most clear seasonal trend. Difference maps of EVI values between months with the lowest and highest rainfall of each hydrological year clearly confirm the highest photosynthetic activity in the laurel forest during the dry season. In addition, these forests show a significative temporal correlation between EVI values and the temperature in the forest (p < 0·001). Our results prove the absence of summer drought stress in the laurel forest implying that the fog drip income is high enough to maintain enough soil moisture to allow the forest fully transpire when temperatures are higher. As the laurel forest of La Gomera occurs in the main recharge area of the island's aquifer system, our analysis of EVI data suggests that fog drip constitutes a key hydrological factor. Copyright © 2010 John Wiley & Sons, Ltd.     

Analytical Constraints on the Measurement of the Sulfur Isotopic Composition and Concentration of Trace Sulfate in Phosphorites: Implications for Sulfur Isotope Studies of Carbonate and Phosphate Rocks

The aim of this study was to evaluate the existing methods for extracting trace sulfate from francolite and measuring its concentration and sulfur isotope composition. Phosphatic rocks were chemically and thermally treated to remove non‐structural SO₄^2? in francolite, which would otherwise be inadvertently included in geochemical analyses of the structurally‐bound sulfate. Acetic acid (10% v/v) proved to be effective in removing calcite, dolomite and ankerite without affecting francolite. To remove all ‘easily’ soluble sulfates, such as Ca‐sulfates and adsorbed sulfate, rinsing with 10% v/v NaCl had to be repeated several times for most samples. For subsequent S isotope determination sample combustion at 600 °C was found to be an efficient way to remove non‐francolite S‐bearing phases. From a number of SO₄^2? detection methods tested, ICP‐AES proved to be the most accurate. For francolite‐sulfate recovery, our recommended protocol involved repeated rinsing of powdered phosphorites with 10% NaCl as well as NaOCl, and testing of the filtrate for SO₄^2? in each wash. If only S isotope compositions are needed, combustion at 600 °C with a subsequent de‐ionised water rinse could be undertaken instead of repeated NaOCl rinsing for studies of both francolite and carbonate. Re‐analysis of previously published data, using the new protocol, provided evidence that the use of this protocol considerably improves data quality.     

Structure and dynamics of distinct fish assemblages in three reaches (upper,middle and lower) of an open tropical estuary in Brazil

We collected fishes and environmental variables in three zones (upper, middle and lower) of a small open tropical estuary during flood tide. The aim was to test for differences in fish assemblages along a gradient from freshwater to marine waters and to detect any seasonal variation in fishes and environmental variables across these zones. A total of 111 species (18 in the upper, 50 in the middle and 66 in the lower estuary) were recorded, forming three distinct fish assemblages, with the family Eleotridae dominating in the upper, Gerreidae in the middle, and Sciaenidae in the lower estuary. Only two species (Geophagus brasiliensis in the upper and the middle zones, and Eucinostomus argenteus in the middle and the lower zones) composed more than 1% of the total number of individuals in more than a single zone. Short‐term (tidal) changes in salinity in the middle estuary were associated with different assemblages in the three estuarine zones, even in winter, when the differences in salinity are lowest between the middle and the lower zones. Seasonal variation in salinity was irrelevant, except in a protected sidewater lagoon in the middle estuary. Low salinity seasonal change may be related to the lack of seasonal variation in the structure of fish assemblages in all estuarine zones.     

Coastal risk management: How to motivate individual economic decisions to lower flood risk?

Coastal flood risk is defined as a product of probability of event and its effect, measured in terms of damage. The paper is focused on coastal management strategies aimed to decrease risk by decreasing potential damage. We review socio-economic literature to show that total flood damage depends on individual location choices in the housing market and on individual flood risk awareness. Low flood risk awareness leads to inefficient spatial developments and increased flood risk. We show that personal experience, risk communication, financial instruments like insurance from flooding and technical instruments like building on high elevations, are factors that increase individual risk awareness. Evidence that these factors indeed affect housing prices and land use patterns is provided. We discuss proactive instruments that can be used in coastal zone management in the Netherlands to increase individual risk awareness. We argue that policy-makers may create incentives giving individuals a possibility to make location choices that lead to less total flood risk in the coastal zone area.     

Groundwater flow model of the Pipiripau watershed, Federal District of Brazil

In order to understand the groundwater dynamics and to improve the management of water resources in the Federal District of Brazil, this research proposes a 3D groundwater flow model to represent the groundwater level and flow system. The selected test site was the Pipiripau catchment. The development of the model was based on available geological, hydrogeological, geomorphological, climatological and pedological data. Geological and hydrogeological data were used to generate the 3D groundwater flow model. The 3D mesh elements of the domain were generated through the Groundwater Modeling System software, based on the logs of the well materials. The numerical simulation of the finite element method was implemented in the framework of the scientific software OpenGeoSys. With the 3D mesh-appropriated boundary conditions, annual average infiltration data and hydrogeological parameters were incorporated. Afterwards, the steady-state model was calibrated by the PEST software using available data of the water level from wells. The results showed the distribution of the steady-state hydraulic heads in the model domain, where the highest values occurred in the east and west recharge areas and the lowest values were found in the southwest of the basin. The results of this study can be a used as initial condition for the transient groundwater flow simulation and to provide a scientific basis for water resource management.     

Refractory calcium‐aluminum‐rich inclusions and aluminum‐diopside‐rich chondrules in the metal‐rich chondrites Hammadah al Hamra 237 and Queen Alexandra Range 94411

Abstract— The metal‐rich chondrites Hammadah al Hamra (HH) 237 and Queen Alexandra Range (QUE) 94411, paired with QUE 94627, contain relatively rare (<1 vol%) calcium‐aluminum‐rich inclusions (CAIs) and Al‐diopside‐rich chondrules. Forty CAIs and CAI fragments and seven Al‐diopside‐rich chondrules were identified in HH 237 and QUE 94411/94627. The CAIs, ～50–400 μm in apparent diameter, include (a) 22 (56%) pyroxene‐spinel ± melilite (+forsterite rim), (b) 11 (28%) forsterite‐bearing, pyroxene‐spinel ± melilite ± anorthite (+forsterite rim) (c) 2 (5%) grossite‐rich (+spinel‐melilite‐pyroxene rim), (d) 2 (5%) hibonite‐melilite (+spinel‐pyroxene ± forsterite rim), (e) 1 (2%) hibonite‐bearing, spinel‐perovskite (+melilite‐pyroxene rim), (f) 1 (2%) spinel‐melilite‐pyroxene‐anorthite, and (g) 1 (2%) amoeboid olivine aggregate. Each type of CAI is known to exist in other chondrite groups, but the high abundance of pyroxene‐spinel ± melilite CAIs with igneous textures and surrounded by a forsterite rim are unique features of HH 237 and QUE 94411/94627. Additionally, oxygen isotopes consistently show relatively heavy compositions with Δ¹⁷O ranging from ?6%0 to ?10%0 (1σ = 1.3%0) for all analyzed CAI minerals (grossite, hibonite, melilite, pyroxene, spinel). This suggests that the CAIs formed in a reservoir isotopically distinct from the reservoir(s) where “normal”, ¹⁶O‐rich (Δ¹⁷O < ?20%0) CAIs in most other chondritic meteorites formed. The Al‐diopside‐rich chondrules, which have previously been observed in CH chondrites and the unique carbonaceous chondrite Adelaide, contain Al‐diopside grains enclosing oriented inclusions of forsterite, and interstitial anorthitic mesostasis and Al‐rich, Ca‐poor pyroxene, occasionally enclosing spinel and forsterite. These chondrules are mineralogically similar to the Al‐rich barred‐olivine chondrules in HH 237 and QUE 94411/94627, but have lower Cr concentrations than the latter, indicating that they may have formed during the same chondrule‐forming event, but at slightly different ambient nebular temperatures. Aluminum‐diopside grains from two Al‐diopside‐rich chondrules have O‐isotopic compositions (Δ¹⁷O ? ?7 ± 1.1 %0) similar to CAI minerals, suggesting that they formed from an isotopically similar reservoir. The oxygen‐isotopic composition of one Ca, Al‐poor cryptocrystalline chondrule in QUE 94411/94627 was analyzed and found to have Δ¹⁷O ? ?3 ± 1.4%0. The characteristics of the CAIs in HH 237 and QUE 94411/94627 are inconsistent with an impact origin of these metal‐rich meteorites. Instead they suggest that the components in CB chondrites are pristine products of large‐scale, high‐temperature processes in the solar nebula and should be considered bona fide chondrites.