Toxic metal (Pb, Cd and Hg) levels in the nearshore surface sediments from the European and Anotolian Shores of Bosphorus, Turkey

In this study, some toxic metal such as Pb, Cd and Hg analyzes have been done in the nearshore surface sediments. Sediment samples have been collected from five parts from the European and Anotolian Shores of the Bosphorus during 2003-2004. Total Pb, Cd and Hg contents vary between <0.01μgg(-1) and 238μgg(-1); <0.01μgg(-1) and 0.92μgg(-1); 0.001μgg(-1) and 0.45μgg(-1), respectively. Contamination Factor (CF) values of Pb and Cd range between 1 and 3 whilst CF values of Hg are lower than 1 in all the stations. It means that there are no Hg metal enrichment by natural or anthropogenic inputs contrary to moderately contamination for Pb and Cd metals throughout the Bosphorus sediments.     

Speciation and Determination of Inorganic Mercury and Methylmercury by Headspace Single Drop Microextraction and Electrothermal Atomic Absorption Spectrometry in Water and Fish

In this study, headspace single drop microextraction (HS‐SDME) method in combination with electrothermal atomic absorption spectrometry (ETAAS) method was developed and validated for the speciation and determination of inorganic mercury (iHg) and methylmercury (MeHg). MeHg and iHg species were reduced to volatile methylmercury hydride (CH₃HgH) and elemental mercury, respectively, in the presence of NaBH₄ and trapped onto a drop of acceptor phase in the tip of a microsyringe. Thiourea and ammonium pyrrolydinedithiocarbamate (APDC) were tested as the acceptor phase. The experimental parameters of the method such as microextraction time, temperature, NaBH₄ concentration, acceptor phase concentration, and pH of the medium were investigated to obtain distinctive conditions for mercury species. Possible interference effects have also been investigated. In order to validation of the method, analytical figures of merits such as accuracy, precision, limit of detection (LOD), limit of quantitation (LOQ), and linear working range have been evaluated. Accuracy of the method has been verified by analyzing certified reference materials (BCR 453 Tuna fish) and spiked samples. The proposed method was applied for the speciation and determination of mercury species in water and fish samples. Mercury species (MeHg and iHg) have been determined in the real samples with a relative error less than 10%.     

Lentil Straw: A Novel Adsorbent for Removing of Hazardous Dye – Sorption Behavior Studies

Sorption behavior of Lanaset Red (LR) G on lentil straw (LS) was studied as a function of particle size, adsorbent dose, initial pH value, initial dye concentration, and contact time. Sorption kinetics data was well described by logistic model. Modified logistic equation can be used to explain effects of initial dye concentrations and contact time on the sorption of LR G with high R² value. Freundlich model was found to be excellent in representing the equilibrium data. Thermodynamic parameters like free energy (ΔG⁰), enthalpy (ΔH⁰), and entropy (ΔS⁰) were calculated by the use of Langmuir constant. Thermodynamic data showed that the sorption processes were spontaneous and endothermic in nature. Desorption process suggested that strong binding and weak interactions could be formed between adsorbent surface and dye molecules. Results revealed that LS has a remarkable potential for the sorption of LR G.     

Source parameters for the M<Subscript>w</Subscript> = 6.6, 03 February 2002, Çay Earthquake (Turkey) and aftershocks from GPS,Southwestern Turkey

The 03 February 2002 Çay Earthquake (M_w ～6.7) occurred on the fault segment between Eber and Ak?ehir Lakes followed by a large aftershock (M_w ～5.6) near the western end of the fault and two sequential aftershocks. We computed the coseismic surface displacements from static GPS measurements to determine the fault geometry parameters and uniform slip components. The coseismic displacements were obtained through combining the regional pre-earthquake and post-earthquake GPS data. Fault geometry and slips were acquired through the inversion of GPS data modeling the events as elastic dislocations in a half-space and assuming all four events took place on the same fault plane. Results suggest that one-segment fault of ～33 km length and dipping ～43° northward suffices to model the dislocation, assuming uniform slip distribution with 0.51 m dip slip, 0.26 m left-lateral slip extending to a depth down to ～11.5 km which is consistent with seismological evidence. The results also verify the normal faulting in the eastern flank of Isparta Angle which has long been assumed as a thrusting structure. While the available data cannot identify the four individual events on the same day, an attempted distributed slip model differentiates dip slip and left-lateral slips near the hypocenter with maximum values of ～1 and 0.6 m, respectively.     

Site classification of Turkish national strong-motion stations

Since 1973, the General Directorate of Disaster Affairs of Turkey has deployed several strong-motion accelerographs at selected sites. Within the framework of the project entitled Compilation of National Strong Ground Motion Database in Accordance with International Standards, site conditions were investigated within the upper 30-m depth by surface seismic and standard penetration tests. Preliminary characterization of the sites is made by making use of both geophysical and geotechnical criteria of NEHRP Provisions and Eurocode-8 site classification systems. The liquefaction susceptibility of those sites which comprise saturated cohesionless deposits is also determined. Mean shear-wave velocity, mean penetration resistance, site class, and liquefaction susceptibility of each site are tabulated. The Turkish strong-motion database supplemented by detailed information on site conditions is a valuable source of information particularly for those studies that put emphasis on the relationship between site conditions and strong-motion parameters.