Insights into operation of the subduction factory from the oxygen isotopic values of the southern Izu–Bonin–Mariana Arc

Abstract Oxygen is the most abundant element in the earth, and isotopic analysis of this element in island arc lavas potentially provides sensitive constraints on the proportion of oxygen recycled from subducted material, relative to that extracted from the mantle. Here we report on 225 new oxygen isotopic analyses of whole‐rock and glass samples, and clinopyroxene separates, from lavas collected from the southernmost 1500 km of the Izu–Bonin–Mariana (IBM) convergent margin. Whole‐rock samples clustered around a mean of 6.11 ± 0.47‰, whereas Mariana Trough glasses and mafic melts, calculated to be in equilibrium with mafic phenocrysts, clustered narrowly around a mean of 5.7‰. These data demonstrate that unequivocal identification of magmatic oxygen requires analysis of fresh glass or mafic minerals, and that the source of southern IBM Arc melts is entirely, or almost entirely, in equilibrium with normal mantle oxygen. If the elemental enrichments characteristic of the subduction component originate in subducted materials, these oxygen isotopic data are most consistent with the interaction of a small amount of sediment melt (<4%; mostly less than 1%) with mantle peridotite to yield the hybrid mantle that melts to form IBM Arc magmas.     

Garnet-ilmenite-perovskite transitions in the system Mg4Si4O12-Mg3Al2Si3O12 at high pressures and high temperatures: phase equilibria, calorimetry and implications for mantle structure

Phase relations in the system Mg₄Si₄O₁₂-Mg₃Al₂Si₃O₁₂ were examined at pressures of 19-27 GPa and relatively low temperatures of 800-1000 °C using a multianvil apparatus to clarify phase transitions of pyroxene-garnet assemblages in the mantle. Both of glass and crystalline starting materials were used for the experiments. At 1000 °C, garnet solid solution (s.s.) transforms to aluminous ilmenite s.s. at 20-26 GPa which is stable in the whole compositional range in the system. In Mg₄Si₄O₁₂-rich composition, ilmenite s.s. transforms to a single-phase aluminous perovskite s.s., while Mg₃Al₂Si₃O₁₂-rich ilmenite s.s. dissociates into perovskite s.s. and corundum s.s. These newly determined phase relations at 1000 °C supersede preliminary phase relations determined at about 900 °C in the previous study. The phase relations at 1000 °C are quite different from those reported previously at 1600 °C where garnet s.s. transforms directly to perovskite s.s. and ilmenite is stable only very close to Mg₄Si₄O₁₂. The stability field of Mg₃Al₂Si₃O₁₂ ilmenite was determined at 800-1000 °C and 25-27 GPa by reversed phase boundaries. In ilmenite s.s., the a-axis slightly increases but the c-axis and molar volume decrease substantially with increasing Al₂O₃ content. Enthalpies of ilmenite s.s. were measured by differential drop-solution calorimetry method using a high-temperature calorimeter. The excess enthalpy of mixing of ilmenite s.s. was almost zero within the errors. The measured enthalpies of garnet-ilmenite and ilmenite-perovskite transitions at 298 K were 105.2±10.4 and 168.6±8.2 kJ/mol, respectively, for Mg₄Si₄O₁₂, and 150.2±15.9 and 98.7±27.3 kJ/mol, respectively, for Mg₃Al₂Si₃O₁₂. Thermodynamic calculations using these data give rise to phase relations in the system Mg₄Si₄O₁₂-Mg₃Al₂Si₃O₁₂ at 1000 and 1600 °C that are generally consistent with those determined experimentally, and confirm that the single-phase field of ilmenite expands from Mg₄Si₄O₁₂ to Mg₃Al₂Si₃O₁₂ with decreasing temperature. The earlier mentioned phase relations in the simplified system as well as those in the Mg₂SiO₄-Fe₂SiO₄ system are applied to estimate mineral proportions in pyrolite as a function of depth along two different geotherms: one is a horizontally-averaged temperature distribution in a normal mantle, and the other being 600 °C lower than the former as a possible representative geotherm in subducting slabs. Based on the previously described estimated mineral proportions versus depth along the two geotherms, density and compressional and shear wave velocities are calculated as functions of depth, using available mineral physics data. Along a normal mantle geotherm, jumps of density and velocities at about 660 km corresponding to the post-spinel transition are followed by steep gradients due to the garnet-perovskite transition between 660 and 710 km. In contrast, along a low-temperature geotherm, the first steep gradients of density and velocities are due to the garnet-ilmenite transition between 610 and 690 km. This is followed by abrupt jumps at about 690 km for the post-spinel transition, and steep gradients between 700 and 740 km that correspond to the ilmenite-perovskite transition. In the latter profile along the low-temperature geotherm, density and velocity increases for garnet-ilmenite and ilmenite-perovskite transitions are similar in magnitude to those for the post-spinel transition. The likely presence of ilmenite in cooler regions of subducting slabs is suggested by the fact that the calculated velocity profiles along the low-temperature geotherm are compatible with recent seismic observations indicating three discontinuities or steep velocity gradients at around 600-750 km depth in the regions of subducting slabs.     

Solar radiation management and ecosystem functional responses

Geoengineering such as solar radiation management (SRM) can be an emergent option to avoid devastating climatic warming, but its ramifications are barely understood. The perturbation of the Earth’s energy balance, atmospheric dynamics, and hydrological cycling may exert unexpected influences on natural and human systems. In this study, I evaluate the impacts of SRM deployment on terrestrial ecosystem functions using a process-based ecosystem model (the Vegetation Integrative Simulator for Trace gases, VISIT) driven by the climate projections by multiple climate models. In the SRM-oriented climate projections, massive injection of sulphate aerosols into the stratosphere lead to increased scattering of solar radiation and delayed anthropogenic climate warming. The VISIT simulations show that canopy light absorption and gross primary production are enhanced in subtropics in spite of the slight decrease of total incident solar radiation. The retarded temperature rise during the deployment period leads to lower respiration, and consequently, an additional net terrestrial ecosystem carbon uptake by about 20%. After the SRM termination, however, along with the temperature rise, this carbon is released rapidly to the atmosphere. As a result of altered precipitation and radiation budget, simulated runoff discharge is suppressed mainly in the tropics. These SRM-induced influences on terrestrial ecosystems occurr heterogeneously over the land surface and differed among the ecosystem functions. These responses of terrestrial functions should be taken into account when discussing the costs and benefits of geoengineering.     

Large kinetic power in FRII radio jets

We investigate the total kinetic powers (L _j) and ages (t _age) of powerful jets of four FR II radio sources (Cygnus A, 3C 223, 3C 284, and 3C 219) by the detail comparison of the dynamical model of expanding cocoons with observed ones. It is found that these sources have quite large kinetic powers with the ratio of L _j to the Eddington luminosity (L _Edd) resides in 0.02<L _j/L _Edd<10. Reflecting the large kinetic powers, we also find that the total energy stored in the cocoon (E _c) exceed the energy derived from the minimum energy condition (E _min): 2<E _c/E _min<160. This implies that a large amount of kinetic power is carried by invisible components such as thermal leptons (electron and positron) and/or protons.     

Transformation textures,mechanisms of formation of high‐pressure minerals in shock melt veins of L6 chondrites,and pressure‐temperature conditions of the shock events

Abstract— The high‐pressure polymorphs of olivine, pyroxene, and plagioclase in or adjacent to shock melt veins (SMVs) in two L6 chondrites (Sahara 98222 and Yamato 74445) were investigated to clarify the related transformation mechanisms and to estimate the pressure‐temperature conditions of the shock events. Wadsleyite and jadeite were identified in Sahara 98222. Wadsleyite, ringwoodite, majorite, akimotoite, jadeite, and lingunite (NaAlSi₃O₈‐hollandite) were identified in Yamato 74445. Wadsleyite nucleated along the grain boundaries and fractures of original olivine. The nucleation and growth of ringwoodite occurred along the grain boundaries of original olivine, and as intracrystalline ringwoodite lamellae within original olivine. The nucleation and growth of majorite took place along the grain boundaries or fractures in original enstatite. Jadeite‐containing assemblages have complicated textures containing “particle‐like,” “stringer‐like,” and “polycrystalline‐like” phases. Coexistence of lingunite and jadeite‐containing assemblages shows a vein‐like texture. We discuss these transformation mechanisms based on our textural observations and chemical composition analyses. The shock pressure and temperature conditions in the SMVs of these meteorites were also estimated based on the mineral assemblages in the SMVs and in comparison with static high‐pressure experimental results as follows: 13–16 GPa, >1900 °C for Sahara 98222 and 17–24 GPa, >2100 °C for Yamato 74445.     

Origin of the metamorphosed clasts in the CV3 carbonaceous chondrite breccias of Graves Nunataks 06101, Vigarano,Roberts Massif 04143, and Yamato‐86009

We observed metamorphosed clasts in the CV3 chondrite breccias Graves Nunataks 06101, Vigarano, Roberts Massif 04143, and Yamato‐86009. These clasts are coarse‐grained polymineralic rocks composed of Ca‐bearing ferroan olivine (Fa_24–40, up to 0.6 wt% CaO), diopside (Fs_7–12Wo_44–50), plagioclase (An_52–75), Cr‐spinel (Cr/[Cr + Al] = 0.4, Fe/[Fe + Mg] = 0.7), sulfide and rare grains of Fe‐Ni metal, phosphate, and Ca‐poor pyroxene (Fs₂₄Wo₄). Most clasts have triple junctions between silicate grains. The rare earth element (REE) abundances are high in diopside (REE ~3.80–13.83 × CI) and plagioclase (Eu ~12.31–14.67 × CI) but are low in olivine (REE ~0.01–1.44 × CI) and spinel (REE ~0.25–0.49 × CI). These REE abundances are different from those of metamorphosed chondrites, primitive achondrites, and achondrites, suggesting that the clasts are not fragments of these meteorites. Similar mineralogical characteristics of the clasts with those in the Mokoia and Yamato‐86009 breccias (Jogo et al. 2012 ) suggest that the clasts observed in this study would also form inside the CV3 chondrite parent body. Thermal modeling suggests that in order to reach the metamorphosed temperatures of the clasts of >800 °C, the clast parent body should have accreted by ~2.5–2.6 Ma after CAIs formation. The consistency of the accretion age of the clast parent body and the CV3 chondrule formation age suggests that the clasts and CV3 chondrites could be originated from the same parent body with a peak temperature of 800–1100 °C. If the body has a peak temperature of >1100 °C, the accretion age of the body becomes older than the CV3 chondrule formation age and multiple CV3 parent bodies are likely.     

Characteristics of evapotranspiration from a permafrost black spruce forest in interior Alaska

Here, the year 2011 characteristics of evapotranspiration and the energy budget of a black spruce forest underlain by permafrost in interior Alaska were explored. Energy balance was nearly closed during summer, and the mean value of the daily energy balance ratio (the ratio of turbulent energy fluxes to available energy) from June to August was 1.00, though a large energy balance deficit was observed in the spring. Such a deficit was explained partly by the energy consumed by snowmelt. Ground heat flux played an important role in the energy balance, explaining 26.5% of net radiation during summer. The mean daily evapotranspiration of this forest during summer was 1.37 mm day^?1 – considered typical for boreal forests. The annual evapotranspiration and sublimation yielded 207.3 mm year^?1, a value much smaller than the annual precipitation. Sublimation accounted for 8.8% (18.2 mm year^?1) of the annual evapotranspiration and sublimation; thus, the sublimation is not negligible in the annual water balance in boreal forests. The daytime average decoupling coefficient was very small, and the mean value was 0.05 during summer. Thus, evapotranspiration from this forest was mostly explained by the component from the dryness of the air, resulting from the aerodynamically rough surface of this forest.     

Age, geology, geophysics, and geochemistry of Mahukona Volcano, Hawai`i

The size, shape, and magmatic history of the most recently discovered shield volcano in the Hawaiian Islands, Mahukona, have been controversial. Mahukona corresponds to what was thought to be a gap in the paired sequence (Loa and Kea trends) of younger Hawaiian volcanoes (<4?Ma). Here, we present the results of marine expeditions to Mahukona where new bathymetry, sidescan sonar, gravity data, and lava samples were collected to address these controversies. Modeling of bathymetric and gravity data indicate that Mahukona is one of the smallest Hawaiian volcanoes (～6,000?km³) and that its magmatic system was not focused in a long-lived central reservoir like most other Hawaiian volcanoes. This lack of a long-lived magmatic reservoir is reflected by the absence of a central residual gravity high and the random distribution of cones on Mahukona Volcano. Our reconstructed subsidence history for Mahukona suggests it grew to at least ～270?m below sea level but probably did not form an island. New ⁴⁰Ar–³⁹Ar plateau ages range from 350 to 654?ka providing temporal constraints for Mahukona’s post-shield and shield stages of volcanism, which ended prematurely. Mahukona post-shield lavas have high ³He/⁴He ratios (16–21?Ra), which have not been observed in post-shield lavas from other Hawaiian volcanoes. Lava compositions range widely at Mahukona, including Pb isotopic values that straddle the boundary between Kea and Loa sequences of volcanoes. The compositional diversity of Mahukona lavas may be related to its relatively small size (less extensive melting) and the absence of a central magma reservoir where magmas would have been homogenized.     

Oxygen isotopic SIMS analysis in Allende CAI: details of the very early thermal history of the solar system

The oxygen isotopic micro-distributions within and among minerals in a coarse-grained Ca, Al-rich inclusion (CAI), 7R-19-1 from the Allende meteorite, were measured by in situ using secondary ion mass spectrometry (SIMS). All values of O isotopic ratios in 7R-19-1 minerals fall along the carbonaceous chondrite anhydrous mineral mixing (CCAM) line on a δ¹⁷O_SMOW vs. δ¹⁸O_SMOW plot. Major refractory minerals (spinel, fassaite and melilite) in 7R-19-1 showed large negative anomalies of Δ¹⁷O in the order, spinel (−21‰) > ¹⁶O-rich melilite (∼−18‰) > fassaite (−15 to +1‰) > ¹⁶O-poor melilite (−8 to +2‰). However, the lower limit values of Δ¹⁷O are similar at about −21‰, a value commonly observed in CAIs. The similarity in the extreme values of the isotope anomaly anomalies suggests that crystallization of all CAIs started from an ¹⁶O enrichment of 21‰ (Δ¹⁷O) relative to terrestrial values. The order of the O isotopic anomalies observed for 7R-19-1, except for ¹⁶O-poor melilite, is parallel to the crystallization sequence determined by experiment from CAI liquid (Stolper, 1982), indicating that the O isotopic exchange in 7R-19-1 occurred between CAI melt and surrounding gas while 7R-19-1 was crystallizing from the ¹⁶O enriched CAI liquid (∼−21‰ in Δ¹⁷O) in the ¹⁶O-poor solar nebula. However, the a single crystallization sequence during the cooling stage cannot explain the existence of ¹⁶O-poor melilite. The presence of ¹⁶O-poor melilite suggests that multiple heating events occurred during CAI formation. The sharp contact between ¹⁶O-rich and ¹⁶O-poor melilite crystals and within ¹⁶O-rich melilite indicates that these multiple heatings occurred quickly. Based on the O isotopic and chemical compositions, fassaite crystals were aggregates of relic crystals formed from CAI melt whichthat have had various O isotopic compositions from the remelting processes. The results of intra-mineral distributions of O isotopes also support multiple heating events during CAI formation.     

Decreases in turbidity during neap tides initiate late winter blooms of Eucampia zodiacus in a macrotidal embayment

Eucampia zodiacus Ehrenberg is harmful, as it causes reduction in the quality of the aquacultured Porphyra thalli owing to nutrient depletions during dense blooms in the late winter in the macrotidal Ariake Sea, Japan. To understand the mechanism of bloom development, changes in the abundance of E. zodiacus during a bloom were investigated along vessel transects from February to April 2012. In addition, marine environmental variables were continuously monitored by the Ariake Sea Monitoring Tower, which revealed that turbidity periodically decreased during neap tides. During the 16 February neap tide, a high Secchi depth (4.3 m) was recorded at offshore stations and the Z _1% depth, at which the light intensity attenuates to 1 % of that at the sea surface, exceeded the water depth. On 16 February, the abundance of E. zodiacus was 52–732 cells mL^?1, peaking at 7.0 m depth offshore. Subsequently, abundance increased at all stations. During the 22 February spring tide, abundance became vertically uniform. On 19 March, abundance at the tower reached 3758 cells mL^?1 at the surface. We conclude that an improvement in light conditions in the deeper layer triggered the bloom, although the size and the duration of the bloom were determined by nutrient availability. Thus, decreases in turbidity during neap tides and subsequent strong vertical mixing during spring tides may be instrumental in the population dynamics of the large diatom E. zodiacus in macrotidal environments.