Juxtaposition of adakite, boninite, high-TiO2 and low-TiO2 basalts in the Devonian southern Altay, Xinjiang, NW China

We present petrographic and geochemical data on representative samples of the Devonian adakite, boninite, low-TiO₂ and high-TiO₂ basalts and associated rocks in the southern Altay areas, Xinjiang, NW China. These volcanic rocks mostly occur as tectonic blocks within suture zones between the Siberian and Junggar plates. Adakite occurs in the Suoerkuduke area ca. 40 km south of Fuyun, and actually represents a poorly-sorted massive volcaniclastic deposit, mostly consisting of a suite of hornblende andesite to pyroxene andesite. The geochemical features of the adakite suggest its generation by melting of subducted oceanic crust. Boninite occurs in the Saerbulake area ca. 20 km southwest of Fuyun, as pillowed lava or pillowed breccia. It is associated with high-TiO₂ basalt/gabbro and low-TiO₂ basalt. The boninites are metamorphosed, but contain relict clinopyroxene with Mg# (=100*Mg/(Mg+Fe)) of 90–92, and Cr₂O₃ contents of 0.5–0.7 wt% and chromian spinel with Cr/(Cr+Al) ratio of 0.84. The bulk rock compositions of the boninites are characterized by low and U-shaped REE with variable La/Yb ratios. They are classified as high-Ca boninite. The Cr-rich cpx phenocryst and Chromian spinel suggests that the boninites were formed by melting of mildly refractory mantle peridotite fluxed by a slab-derived fluid component under normal mantle potential temperature conditions. Basaltic rocks occur as massive flows, pillowed lavas, tuff breccia, lapilli tuff and blocks in tectonic mélanges. Together with gabbros, the basaltic rocks are classified into high-TiO₂ (>1.7 wt%) and low-TiO₂ (<1.5 wt%) types. They show variable trace element compositions, from MORB-type through transitional back-arc basin basalt to arc tholeiite, or within plate alkalic basalt. A notable feature of the Devonian formations in the southern Altay is the juxtaposition of volcanic rocks of various origins even within a limited area; i.e. the adakite and the boninites are associated with high-TiO₂ and low-TiO₂ basalts and/or gabbros, respectively. This is most likely produced by complex accretion and tectonic processes during the convergence in the Devonian–Carboniferous paleo-Asian Ocean between the Siberian and Junggar plates.     

Timing of atmospheric precipitation in the Zagros Mountains inferred from a multi-proxy record from Lake Mirabad, Iran

A sediment core 7.2 m long from Lake Mirabad, Iran, was examined for loss-on-ignition, mineralogy, oxygen-isotopic composition of authigenic calcite, and trace-element composition of ostracodes to complement earlier pollen and ostracode-assemblage studies. Pollen, ostracode-inferred lake level, and high Sr/Ca ratios indicate that the early Holocene (10000 to 6500 cal yr BP) was drier than the late Holocene. Low δ¹⁸O values during this interval are interpreted as resulting from winter-dominated precipitation, characteristic of a Mediterranean climate. Increasing δ¹⁸O values after 6500 cal yr BP signal a gradual increase in spring rains, which are present today. A severe 600-yr drought occurred at ca. 5500 cal yr BP, shortly after the transition from pistachio-almond to oak forest. During the late Holocene, two milder droughts occurred at about 1500 and 500 cal yr BP. Within the resolution of the record, no drought is evident during the collapse of the Akkadian empire (4200–3900 cal yr BP). Rather, a decrease in δ¹⁸O values to early-Holocene levels may indicate the return to a Mediterranean precipitation regime.     

Cr diffusion in orthopyroxene: Experimental determination, Mn-Cr thermochronology, and planetary applications

We have determined Cr diffusion coefficients (D) in orthopyroxene parallel to the a-, b-, and c-axial directions as a function temperature at f(O₂) corresponding to those of the wüstite-iron (WI) buffer. Diffusion is found to be significantly anisotropic with D(//c) > D(//b) > D(//a), conforming to an earlier theoretical prediction. Increase of f(O₂) from WI buffer conditions to 4.5 log unit above the buffer at 950 and 1050 °C leads to decrease of D(Cr) by a factor of two to three, possibly suggesting significant contribution from an interstitial diffusion mechanism. We have used the diffusion data to calculate the closure temperatures (T_c) of the Mn-Cr decay system in orthopyroxene as a function of initial temperature (T₀), grain size (a) and cooling rate for spherical and plane sheet geometries. We also present graphical relations that permit retrieval of cooling rates from knowledge of the resetting of Mn-Cr ages in orthopyroxene during cooling, T₀ and a. Application of these relations to the Mn-Cr age data of the cumulate eucrite Serra de Magé yields a T_c of 830-980 °C, and cooling rates of 2-27 °C/Myr at T_c and ∼1-13 °C/Myr at 500 °C. It is shown that the cooling of Serra de Magé to the closure temperature of the Mn-Cr system took place at its original site in the parent body, and thus implies a thickness for the eucrite crust in the commonly accepted HED parent body, Vesta, of greater than 30 km. This thickness of the eucrite crust is compatible only with a model of relatively olivine-poor bulk mineralogy in which olivine constitutes 19.7% of the total asteroidal mass.     

Late Paleozoic adakites and Nb-enriched basalts from northern Xinjiang, northwest China: Evidence for the southward subduction of the Paleo-Asian Oceanic Plate

Abstract   Volcanic rocks consisting of adakite and Nb-enriched basalt are found in the early Devonian Tuoranggekuduke Group in the northern margin of the Kazakhstan-Junggar Plate, northern Xinjiang, northwest China. The geochemical characteristics of the andesitic and dacitic rocks in this area resemble that of adakites. The relatively high Al₂O₃, Na₂O and MgO content and Mg^♯ values indicate that the adakites were generated in relation to oceanic slab subduction rather than the partial melting of basaltic crust. A slightly higher SrI and a lower ɛ _Nd( t  = 375 Ma) compared to adakites of mid-oceanic ridge basalt (MORB) imply that slab sediments were incorporated into these adakites during slab melting. The Nb-enriched basalt lavas, which are intercalated in adakite lava suite, are silica saturated and are distinguished from the typical arc basalts by their higher Nb and Ti content (high field strength element enrichment). They are derived from the partial melting of the slab melt-metasomatized mantle wedge peridotite. Apparently, positive Sr anomalies and a slightly higher heavy rare earth element content in these adakites compared to their Cenozoic counterparts indicate that the geothermal gradient in the Paleo-Asian Oceanic subduction zone and the depth of the Paleo-Asian Oceanic slab melting are between those of their Archean and Cenozoic counterparts. The distribution of the adakites and Nb-enriched basalts in the northern margin of the Kazakhstan-Junggar Plate, northern Xinjiang, indicates that the Paleo-Asian Oceanic Plate subducted southward beneath the Kazakhstan-Junggar Plate in the early Devonian period.     

Crustal thickness along the western Galápagos Spreading Center and the compensation of the Galápagos hotspot swell

Wide-angle refraction and multichannel reflection seismic data show that oceanic crust along the Galápagos Spreading Center (GSC) between 97°W and 91°25′W thickens by 2.3 km as the Galápagos plume is approached from the west. This crustal thickening can account for ∼52% of the 700 m amplitude of the Galápagos swell. After correcting for changes in crustal thickness, the residual mantle Bouguer gravity anomaly associated with the Galápagos swell shows a minimum of −25 mGal near 92°15′W, the area where the GSC is intersected by the Wolf-Darwin volcanic lineament (WDL). The remaining depth and gravity anomalies indicate an eastward reduction of mantle density, estimated to be most prominent above a compensation depth of 50-100 km. Melting calculations assuming adiabatic, passive mantle upwelling predict the observed crustal thickening to arise from a small increase in mantle potential temperature of ∼30°C. The associated thermal expansion and increase in melt depletion reduce mantle densities, but to a degree that is insufficient to explain the geophysical observations. The largest density anomalies appear at the intersection of the GSC and the WDL. Our results therefore require the existence of compositionally buoyant mantle beneath the GSC near the Galápagos plume. Possible origins of this excess buoyancy include melt retained in the mantle as well as mantle depleted by melting in the upwelling plume beneath the Galápagos Islands that is later transported to the GSC. Our estimate for the buoyancy flux of the Galápagos plume (700 kg s⁻¹) is lower than previous estimates, while the total crustal production rate of the Galápagos plume (5.5 m³s⁻¹) is comparable to that of the Icelandic and Hawaiian plumes.     

A late Middle Pleistocene temperate–periglacial–temperate sequence (Oxygen Isotope Stages 7–5e) near Marsworth, Buckinghamshire, UK

River-channel and colluvial deposits, near Marsworth, Buckinghamshire, record a temperate-periglacial-temperate sequence during the late Middle Pleistocene. The deposits of a lower channel contain tufa clasts bearing leaf impressions that include Acer sp., and Sorbus aucuparia and containing temperate arboreal pollen attributed to ash-dominated woodland. The tufa probably formed at the mouth of a limestone spring before being redeposited in a small river whose deposits contain plant remains, Mollusca, Coleoptera, Ostracoda and vertebrate bones of temperate affinities. The sediments, sedimentary structures and limited biological remains above the Lower Channel deposits indicate that fluvial deposition preceded climatic cooling into periglacial conditions. Fluvial deposition recurred during a later temperate episode, as shown by the mammalian bone assemblage in stratigraphically higher channel deposits. The Upper Channel deposits are confidently attributed to Oxygen Isotope Sub-Stage 5e (Ipswichian) on the basis of their vertebrate remains. However, the age of the Lower Channel deposits is less clear. The mammalian and coleopteran remains in the Lower Channel strongly suggest correlation with Oxygen Isotope Stage 7 on the basis of their similarities to other sites whose stratigraphy is better known and the clear difference of the Lower Channel assemblage from well-established faunas of Ipswichian or any other age. By contrast, U–Th dating of the tufa clasts suggests an age post 160 ka BP, while Aile/Ile ratios on Mollusca point to an Ipswichian age and younger. Four ways of interpreting this age discrepancy are considered, the preferred one correlating the Lower Channel deposits with Oxygen Isotope Stage 7.     

Estimating the permeability of the Nojima Fault Zone by a hydrophone vertical seismic profiling experiment

Abstract A multi-offset hydrophone vertical seismic profiling (VSP) experiment was done in a 747 m deep borehole at Nojima Hirabayashi, Hyogo prefecture, Japan. The borehole was drilled to penetrate the Nojima Fault, which was active in the 1995 Hyogo-ken Nanbu earthquake. The purpose of the hydrophone VSP is to detect subsurface permeable fractures and permeable zones and, in the present case, to estimate the permeability of the Nojima Fault. The analysis was based on a model by which tube waves are generated when incident P-waves compress the permeable fractures (or permeable zones) intersecting the borehole and a fluid in the fracture is injected into the borehole. Permeable fractures (or permeable zones) are detected at the depths of tube wave generation, and fracture permeability is calculated from the amplitude ratio of tube wave to incident P-wave. Several generations of tube waves were detected from the VSP sections. Distinct tube waves were generated at depths of the fault zone that are characterized by altered and deformed granodiorite with a fault gouge, suggesting that permeable fractures and permeable zones exist in the fault zone. Tube wave analysis shows that the permeability of the fault gouge from 624 m to 625 m is estimated to be approximately 2 × 10⁻¹² m².     

Internal structure of the Nojima Fault zone from the Hirabayashi GSJ drill core

Abstract The internal structures of the Nojima Fault, south-west Japan, are examined from mesoscopic observations of continuous core samples from the Hirabayashi Geological Survey of Japan (GSJ) drilling. The drilling penetrated the central part of the Nojima Fault, which ruptured during the 1995 Kobe earthquake (Hyogo-ken Nanbu earthquake) ( M 7.2). It intersected a 0.3 m-thick layer of fault gouge, which is presumed to constitute the fault core (defined as a narrow zone of extremely concentrated deformation) of the Nojima Fault Zone. The rocks obtained from the Hirabayashi GSJ drilling were divided into five types based on the intensities of deformation and alteration: host rock, weakly deformed and altered granodiorite, fault breccia, cataclasite, and fault gouge. Weakly deformed and altered granodiorite is distributed widely in the fault zone. Fault breccia appears mostly just above the fault core. Cataclasite is distributed mainly in a narrow (≈1 m wide) zone in between the fault core and a smaller gouge zone encountered lower down from the drilling. Fault gouge in the fault core is divided into three types based on their color and textures. From their cross-cutting relationships and vein development, the lowest fault gouge in the fault core is judged to be newer than the other two. The fault zone characterized by the deformation and alteration is assumed to be deeper than 426.2 m and its net thickness is > 46.5 m. The fault rocks in the hanging wall (above the fault core) are deformed and altered more intensely than those in the footwall (below the fault core). Furthermore, the intensities of deformation and alteration increase progressively towards the fault core in the hanging wall, but not in the footwall. The difference in the fault rock distribution between the hanging wall and the footwall might be related to the offset of the Nojima Fault and/or the asymmetrical ground motion during earthquakes.     

Compressional wave velocity of granite and amphibolite up to melting temperatures at 1 GPa

Compressional wave velocities (V_P) at above-solidus temperatures and at 1 GPa were obtained for a granite and amphibolite, which are considered to be major constituents of the continental crust. The temperature variation of velocities showed that the V_P values of granite decreased with rising temperature, but substantially increased beyond the melting temperature (850–900 °C). Such an increase may be caused by the α–β transition of quartz. The velocities of amphibolite decreased linearly with increasing temperature and dropped sharply at temperatures above the solidus (700 °C), indicating that partial melting of amphibolite acts to significantly lower the seismic velocities.     

Sequential processes in a landslide hazard at a slate quarry in Okayama,Japan

The 12 March 2001 landslide at a slate quarry in Okayama, Japan killed three workers. Composite studies based on field surveys of the landslide slope, interviews with local residents and quarry workers, and inspections of hydrological and seismological data have been used to clarify the causes of this slide and its movements. The results indicate that the landslide was enabled firstly by the steepness of the slope, which had been undercut by river; secondly, the structure was that of a dip-slope that was prone to deep-seated slides along bedding planes; thirdly, numerous joints and faults were present. Surprisingly, rainfall, earthquakes, and explosions do not appear to have played any role in the triggering of this slide. The interviews demonstrated that the frequency of precursory failures increased over a period of several hours before the 12 March 2001 landslide. Inspection of the seismograph records and the eyewitness evidence both indicate that the main part of the landslide consisted of two phases of slope failure within 23 s. After the slide, the frequency of the failures gradually decreased with time over a period of several days. Three new terms are proposed for landslides: foreslide, mainslide, and afterslide, following the terms foreshock, main shock, and aftershock used in seismology.