The effect of iron on montmorillonite stability. (I) Background and thermodynamic considerations

It is envisaged that high-level nuclear waste (HLW) will be disposed of in underground repositories. Many proposed repository designs include steel waste canisters and bentonite backfill. Natural analogues and experimental data indicate that the montmorillonite component of the backfill could react with steel corrosion products to produce non-swelling Fe-rich phyllosilicates such as chamosite, berthierine, or Fe-rich smectite. In K-bearing systems, the alteration of montmorillonite to illite/glauconite could also be envisaged. If montmorillonite were altered to non-swelling minerals, the swelling capacity and self-healing properties of the bentonite backfill could be reduced, thereby diminishing backfill performance. The main aim of this paper was to investigate Fe-rich phyllosilicate mineral stability at the canister-backfill interface using thermodynamic modelling. Estimates of thermodynamic properties were made for Fe-rich clay minerals in order to construct approximate phase-relations for end-member/simplified mineral compositions in logarithmic activity space. Logarithmic activity diagrams (for the system Al₂O₃-FeO-Fe₂O₃-MgO-Na₂O-SiO₂-H₂O) suggest that if pore waters are supersaturated with respect to magnetite in HLW repositories, Fe(II)-rich saponite is the most likely montmorillonite alteration product (if f_O2(g) values are significantly lower than magnetite-hematite equilibrium). Therefore, the alteration of montmorillonite may not be detrimental to nuclear waste repositories that include Fe, as long as the swelling behaviour of the Fe-rich smectite produced is maintained. If f_O2(g) exceeds magnetite-hematite equilibrium, and solutions are saturated with respect to magnetite in HLW repositories, berthierine is likely to be more stable than smectite minerals. The alteration of montmorillonite to berthierine could be detrimental to the performance of HLW repositories.     

Closed Circuit Television (CCTV) Earthquake Behaviour Coding Methodology: analysis of Christchurch Public Hospital video data from the 22 February Christchurch earthquake event

Earthquake epidemiological research indicates that the behavioural response influences the nature and severity of injuries sustained. However, there is no observational evidence of the actions individuals engage in during and immediately following earthquake shaking, and the context in which earthquake injuries and deaths are caused. Closed Circuit Television Earthquake Behaviour Coding Methodology has been developed as a tool to classify human behaviour during and immediately following earthquake shaking using real event video data. The coding methodology was applied to security video data captured during the 22 February 2011 M_w6.3 ‘Christchurch’ earthquake event from the Christchurch Public Hospital which experienced shaking intensity of MM9 lasting approximately 12–15 s. We applied this coding methodology to determine: demography, trans-event behavioural responses, post-event behavioural responses, influence of social context on behaviour, and influence of behaviour on injuries. A total of 213 individuals from 31 different camera views were analysed. Sixty-six per cent of the individuals were adult-aged females. The primary trans-event responses were to hold (26%) onto furniture, walls, and/or other people close to them and to look around (30%). No individuals were observed to perform all ‘Drop, Cover, Hold’ actions, the recommended action during strong earthquake shaking in New Zealand. Post-event behaviour included: running, walking, providing assistance, moving towards others, visual communication, and some individuals gave instructions. Social contextual behaviour varied depending on the role of the adult. There were no serious injuries linked to behaviour. The results of this initial study indicate the coding methodology can record the distribution of and variation in human behaviours. Therefore, objective observation of earthquake video data can provide a useful quantitative measure of human behaviour. Significantly, the process will enable researchers to look more closely at behaviours, as well as the social and physical contexts associated with injury risk during and immediately following earthquake shaking.     

Coronal changes associated with a disappearing filament

This paper describes Skylab/ATM observations of the events associated with a disappearing filament near the center of the solar disk on January 18, 1974. As the filament disappeared, the nearby coronal plasma was heated to a temperature in excess of 6 × 10⁶K. A change in the pattern of coronal emission occurred during the 11/3 hr period that the soft X-ray flux was increasing. This change seemed to consist of the formation and apparent expansion of a loop-like coronal structure which remained visible until its passage around the west limb several days later. The time history of the X-ray and microwave radio flux displayed the well-known gradual-rise-and-fall (GRF) signature, suggesting that this January 18 event may have properties characteristic of a wide class of X-ray and radio events.In pursuit of this idea, we examined other spatially-resolved Skylab/ATM observations of long-duration X-ray events to see what characteristics they may have in common. Nineteen similar long-lived SOLRAD X-ray events having either the GRF or post-burst radio classification occurred during the nine-month Skylab mission. Sixteen of these occurred during HAO/ATM coronagraph observations, and 7 of these 16 events occurred during observations with both the NRL/ATM slitless spectrograph and the MSFC-A/ATM X-ray telescope. The tabulation of these events suggests that all long-lived SOLRAD X-ray bursts involve transients in the outer corona and that at least two-thirds of the bursts involve either the eruption or major activation of a prominence. Also, these observations indicate that long-lived SOLARD events are characterized by the appearance of new loops of emission in the lower corona during the declining phase of the X-ray emission. However, sometimes these loops disappear after the X-ray event (like the post-flare loops associated with a sporadic coronal condensation), and sometimes the loops remain indefinitely (like the emission from a permanent coronal condensation).Visiting Scientist, Kitt Peak National Observatory, Tucson, Ariz. 85726, U.S.A. operated by the Association of Universities for Research in Astronomy, Inc., under contract with the National Science Foundation.Presently located at NASA/MSFC, Space Sciences Laboratory, Marshall Space Flight Center, Ala. 35812, U. S.A.     

The effects of hazard zone information on judgements about earthquake damage

This study investigates the extent to which people's views on the causes and preventability of earthquake damage might be influenced by their degree of exposure to hazard as well as what information they have been given about the hazard. The results show that the provision of hazard zoning information influences judgements on preventability and causes of damage, but this effect depends on the degree of hazard faced by residents. In low hazard zones, information leads to the view that causes are manageable, whereas in high hazard zones information may induce a degree of fatalism. The use of public information in risk management needs to take into account the degree of risk faced by the recipients.     

Erosive flood events on the surface of Mars: Application to Mangala and Athabasca Valles

We address key factors involved in determining water flow conditions in outflow channels on Mars, including the temperature of the sub-surface water being released and the environmental conditions of low temperature, low atmospheric pressure, and low acceleration due to gravity. We suggest how some of the assumptions made in previous work may be improved. Our model considers the thermodynamic effects of simultaneous evaporation and freezing of water, and fluid dynamical processes including changes in flow rheology caused by assimilation of cold rock and ice eroded at the channel bed, and ice crystal growth due to water freezing. We model how far initially turbulent water could flow in a channel before it erodes and entrains enough material to become laminar, and subsequently ceases to erode the bed. An ice raft will begin to form on the flood while transition occurs between turbulent and laminar flow. Estimates are given for water transit times, ～17–19 h, initial water depths, 50–62 m, and average flow speeds, 5–12 m s^?1, in the Mangala and Athabasca Valles. We show that these two outflow channels, and by implication others like them, could plausibly have been formed in single water release events. Resulting mean erosion rates are approximately 0.7 mm s^?1, a factor of three greater than previous estimates based on combinations of estimates of flood duration and required water volumes. This is explained by the consideration of the effects of eroded ice and the physics of thermal erosion in the present study.     

Growth of ferruginous oncoliths in the Bajocian (Middle Jurassic) of Europe

Limonitic oncoliths from the Bajocian of Europe, widely known as ‘snuff-boxes’, grew by accretion of bundles of laminae on one side, followed by overturning and accretion of laminae on the other side. A diverse hard-substrate encrusting fauna grew interleaved with the ferruginous laminations. The palaeoecological preferences of this fauna indicate that its growth, and hence the accumulation of the laminations, took place on the gloomy undersides of the oncoliths. This upsidedown growth is supported by characteristics of the lamination bundles themselves, and by the predominant present-day orientations of the snuff-boxes. The abundance of the associated fauna and the lack of carbonate-dissolving macroborers cutting the laminae suggest an original ferric composition. Precipitation was probably under the control of non-photosynthetic microorganisms that inhabited the microenvironments represented by the oncoliths' lower surfaces.     

Prerift and synrift sedimentation during early fault segmentation of a Tertiary carbonate platform, Indonesia

Eocene carbonate deposits of the Barru area, Sulawesi, Indonesia, provide a rare insight into sedimentation prior to and during propagation of normal faults to the surface. Three main successions; late prerift, latest prerift/earliest synrift and synrift, are characterised by distinctive facies associations and sequence development. Shallow water foraminiferal shoals and intervening lower energy depositional environments occurred during the late prerift in areas which latter formed footwall highs and hangingwall depocentres, respectively. During the latest prerift/earliest synrift, shallow water shelves deepened laterally into slope environments in developing hangingwall depocentres. In both these sequences, sections in developing hangingwall areas are thickest, deepen up-section and thin laterally towards growing footwall highs. Active faulting resulted in rapid drowning of hangingwall depocentres and massive reworking of material derived from collapse of the platform margin and adjacent shallow water/emergent footwall highs.Differential subsidence, controlling water depths and accommodation space, types of carbonate producers and active faulting were the main factors affecting depositional environments and facies distributions. Carbonate producers are extremely sensitive indicators of depositional water depth and energy, hence rapid lateral and vertical facies variations in the Barru area provide quantifiable insight into environmental changes prior to and during active faulting.