西藏错那洞电气石花岗岩中电气石化学组成、硼同位素特征及意义

为了对西藏错那洞电气石花岗岩源区进一步约束,利用显微镜、电子探针和激光剥蚀多接收等离子质谱仪,对错那洞电气石花岗岩中电气石的形态、成分及硼同位素组成进行了研究.结果表明,错那洞电气石花岗岩中的电气石为碱族黑/铁电气石,直接结晶自富硼熔体,与熔体之间未发生明显的硼同位素分馏.电气石δ11B值主要在-6.91‰^-9.17‰之间,与大陆地壳平均δ11B值(-10‰±3‰)相近,表明错那洞电气石花岗岩主要源自变质沉积岩的部分熔融.然而,与起源于变质沉积岩的花岗岩相比,样品的δ11B值明显偏高,而与前人报道的雅拉香波淡色花岗岩(源自石榴石角闪岩部分熔融)的δ11B值相似.因此,错那洞电气石花岗岩源区中,除了变质沉积岩外,可能还混入了少量石榴石角闪岩.     

四川某崩塌区危岩稳定性评价

汶川地震后,在地震灾区及影响区形成了大量的危岩崩塌地质灾害。通过对崩塌区地质灾害的调查,结合所收集的地质资料,分析了崩塌地质灾害的形成机制以及危害性,并选择区内典型危岩及断面,采用危岩体平面滑动法及岩有限元应力分析法,对崩塌区危岩体在各种工况条件下的稳定性进行评价。评价结果表明:有限元应力分析法与公式计算结果基本吻合,与实际情况基本一致。此结果可为崩塌灾害防治提供依据。     

煤储层渗透率动态预测模型适用性评价

基于比较理论推导建立的4个煤层渗透率计算模型,对我国煤层气盆地已有物性参数进行计算,以预测其煤储层渗透率。将模型预测结果与现场试井渗透率数据进行对比分析,得出了4个模型的预测精度,在此基础上研究了煤储层渗透率动态预测模型对我国煤层气部分区块的适用性。计算结果表明:在煤层气开发后期,汪-张模型的适用性较好,预测结果与现场数据基本一致,对煤层气开采有一定指导意义。     

新疆阿尔泰阿勒泰组沉积时代及其形成环境

阿勒泰组变质碎屑岩局部夹变质火山岩广泛分布于南阿尔泰的冲乎尔、克兰和麦兹盆地,其沉积时代和构造环境对于研究阿尔泰造山带的演化过程有重要意义。阿勒泰组碎屑锆石的年代学研究表明,碎唐锆石年龄主要集中在417-383 Ma和507-445 Ma,并出现少量元古宙和太古宙碎屑锆石。少数锆石年龄为380-354 Ma,与阿勒泰组凝灰岩和流纹岩年龄一致(376~354 Ma)。综合研究认为阿勒泰组时代为中-晚泥盆世(382-354 Ma)。阿勒泰组长石石英砂岩分选性和磨圆度较差,为近源沉积,物源岩石主要来自泥盆纪火山岩,其次是晚寒武一早奥陶世火山岩和奥陶纪花岗岩。长石石英砂岩样品具有高的La/Sc(3.9-6.3),La/Y(1.0~1.6),较低的Sc/Cr(0.2~0.4)比值,类似于大陆岛弧相关环境碎屑沉积物,结合Th-Co-Zr/10和Th-Sc-Zr/10以及La-Th-Sc判别图,认为阿勒泰组形成于与岛弧相关的构造环境(弧后盆地),为研究阿尔泰造山带泥盆纪构造演化提供了重要证据。     

张北6.2级地震的水化前兆异常分析及有关问题讨论

张北地震前、在中期阶段,多井水氡出现负异常变化;短期阶段出现区域水氡差分异常的月频次增加;短临阶段则出现怀来４井水汞的多次突跳。大同地震前多井出现水氡的趋势性正常,是张北地震水化前兆最显著的不同之处。本文分析了张北地震水化方法预报失误的原因。讨论认为,水氡负异常做为中期前兆的信度较低;为提高水化预报地震的效能,必须与其它前兆手段相结合。     

基于EMD小波阈值滤波的地磁数据去噪分析

采用小波阈值滤波、经验模态分解滤波和基于经验模态分解的小波阈值滤波3种方法,对磁通门磁力仪观测数据进行去噪,有效去除或抑制郫县地震台地磁数据的地电干扰.     

上海及邻近地区介质参数的研究

在频率域里研究了上海及邻近地区的Q值、小震震源参数,初步得到如下结果:①以上海佘山为中心,平均直达P波Q值呈方向性分布。在相同震中距下,上海西面溧阳方向(?)值较高,上海北部南黄海方向(?)值较低;溧阳和南黄海地震活跃区域的(?)值比其邻近地震相对不活跃区域的偏高,②相同震级的地震相比之下,上海—溧阳方向的地震破裂尺度小,上海—南黄海方向的地震破裂尺度大;并且震级在2.5—4.0级之间的地震,破裂尺度的数值溧阳的比较集中,南黄海的则比较离散。     

Mineral and fluid inclusions in zircon of UHP metamorphic rocks from the CCSD-main drill hole: A record of metamorphism and fluid activity

The Chinese Continental Scientific Drilling (CCSD) main drill hole (0–3000 m) in Donghai, southern Sulu orogen, consists of eclogite, paragneiss, orthogneiss, schist and garnet peridotite. Detailed investigations of Raman, cathodoluminescence, and microprobe analyses show that zircons from most eclogites, gneisses and schists have oscillatory zoned magmatic cores with low-pressure mineral inclusions of Qtz, Pl, Kf and Ap, and a metamorphic rim with relatively uniform luminescence and eclogite-facies mineral inclusions of Grt, Omp, Phn, Coe and Rt. The chemical compositions of the UHP metamorphic mineral inclusions in zircon are similar to those from the matrix of the host rocks. Similar UHP metamorphic P–T conditions of about 770 °C and 32 kbar were estimated from coexisting minerals in zircon and in the matrix. These observations suggest that all investigated lithologies experienced a joint in situ UHP metamorphism during continental deep subduction. In rare cases, magmatic cores of zircon contain coesite and omphacite inclusions and show patchy and irregular luminescence, implying that the cores have been largely altered possibly by fluid–mineral interaction during UHP metamorphism.

Abundant H₂O–CO₂, H₂O- or CO₂-dominated fluid inclusions with low to medium salinities occur isolated or clustered in the magmatic cores of some zircons, coexisting with low-P mineral inclusions. These fluid inclusions should have been trapped during magmatic crystallization and thus as primary. Only few H₂O- and/or CO₂-dominated fluid inclusions were found to occur together with UHP mineral inclusions in zircons of metamorphic origin, indicating that UHP metamorphism occurred under relatively dry conditions. The diversity in fluid inclusion populations in UHP rocks from different depths suggests a closed fluid system, without large-scale fluid migration during subduction and exhumation.     

Effect of some additives on synthesis of zeolite from coal fly ash

Hydrothermal conversion of fly ash into zeolites was conducted and the effects of the addition of sodium halide and waste solutions produced after zeolitization of fly ash, as well as the adjustment of the Si/Al ratio prior to synthesis process on the formation and cation exchange capacity (CEC) of zeolite product were evaluated. Both the addition of NaCl and NaF ameliorated the crystallinity and CEC of synthesized zeolite, but NaF had a better improvement effect. Na⁺ was considered to enhance the crystallization of zeolite, while F⁻ favored the dissolution of fly ash. The type of zeolite formed depended on the Si/Al ratio of the starting material prior to the nucleation and crystallization of zeolite. The adjustment of the Si/Al ratio of fly ash by addition of Na₂SiO₄ and Al(OH)₃ changed the type and CEC of zeolite. Waste solutions contained large amount of Si and little Al due to the formation of a zeolite named NaP1 in zeolite terminology with the Joint Committee of Powder Diffraction Standard (JCPDS) code of 39-0219. The alkalinity decreased largely. As a result, the CEC value of zeolite products synthesized with waste solution as alkali source decreased. The supplementation of new alkali to adjust the alkalinity of waste solution could enhance the CEC of synthesized product. It was concluded that: (1) addition of sodium halide and adjustment of the Si/Al ratio prior to synthesis can improve the quality of zeolite; (2) waste solutions produced following the zeolitization of fly ash can be reused as an alkali source in the activation of fly ash; zero-emission of waste solution in the synthesis of zeolite from fly ash is possible.     

Constraining the hydrocarbon expulsion history of the coals in Qinshui Basin, North China, from the analysis of fluid inclusions

From the comprehensive study on the homogenization temperatures and the occurrence of fluid inclusions in the framework minerals of the strata between or above the Carboniferous–Permian coals in the Qinshui basin, Shanxi, three stages are predicted of hydrocarbon expulsion from the coals. Combined with the known history of basin evolution, it is deduced that the expulsion of hydrocarbons happened during the J₁ (210–180 Ma), the early K₁ (150–130 Ma) and K₂E₁ (110–60 Ma). In the early stage, the coals produced and discharged coal-generated oils. The average GOI value of four sandstone samples is relatively high, as they have been exposed to high paleo-oil saturation in the strata between or above the coals. The biomarker compositions of oil-bearing fluid inclusions are similar to those of extracts from the coals, and so it is concluded that those oils were derived from the same family of the coals.