活性白云粉生产工艺及其物化性能研究

活性白云粉（ABP）是在白云岩经过破碎、细粉碎、表面改性的基础上得到的一种新型改性功能填料。本文利用河南辉县市的拍石头和张村两地产出的白云岩作为实验原料,对其表面改性的实验方法、改性剂选择及用量、改性条件及改性效果等方面进行了一定的探讨,并且对改性前后的白云石粉体的粒度、比表面积等性能及红外光谱特征做了对比研究。生产工艺和物性测试研究表明：活性白云粉代替轻质碳酸钙作橡胶填料前景广阔;与轻钙相比,活性白云粉的粒度不够均匀,经优化和改善生产工艺条件,可望进一步提高其应用价值。     

渤海湾盆地沙河街组钙质超微化石古生态及沉积环境

渤海湾盆地沙河街组中钙质超微化石的发现,表明这一时期渤海湾盆地与海水有过联系。对钙质超微化石古生态及沉积环境研究表明,化石主要产出时代为始新世晚期至渐新世早中期,属“间冰期”亚热带气候型。这一问题的深入研究,对于渤海湾盆地的石油勘探有重要意义。     

潍北-莱州湾凹陷郯庐断裂带新生代走滑特征

横切潍北-莱州湾凹陷郯庐断裂带的地震反射剖面和断裂带内的凹陷断层、沉积相和油气特征,直接或间接显示了郯庐断裂带的延伸、运动性质和活动时限。郯庐断裂带在海域和陆上的几何形态及其组合基本一致,根据切过断裂带的剖面和平面上断层的组合特征,判断其为兼具垂直位移的走滑运动断层系。走滑断裂带的活动控制着凹陷内同构造沉积以及构造样式,表明郯庐断裂带的活动时限具分段性,相当于渤海湾盆地孔店组(E1?2k)-沙四段(E2?3s4)沉积期(古新世-早始新世)-孔店组-沙二段(E2?3s2)沉积期(古新世-始新世)-孔店组-沙一段(E2?3s1)(古新世-渐新世)沉积时期,走滑拉分活动由南向北迁移; 活动方式也由古新世-早始新世的左旋走滑活动,被早始新世之后的右旋走滑活动所替代。     

刍议枣庄因采矿引起的地质灾害及预防

1 枣庄矿产资源开采史 枣庄市矿产资源的开采有着悠久的历史.据当地甘泉寺的碑碣记载,1308年就有人在该地区挖窑采煤.13世纪中叶,民间采煤业逐渐兴盛起来.明代诗人满碧山"磨塘山欲尽,煤井地皆空"的诗句,就是对枣庄地区的采矿描述.开采陶土烧瓷的历史约有1400年;开采铁矿石手工冶铁也有500多年的历史.改革开放以来,枣庄地区的采矿业有了较快的发展,采矿品种由单一转向多种,现已达15个矿种.全市年产原煤2 000多万吨.县、乡(镇)、村办和个体办采石厂300多家,年采矿石量1 600万t,黏土、河砂等采矿点200余处,全市从事采矿业人员达16万余人.     

自然与人类活动叠加影响下晋祠泉域岩溶地下水动态特征

为了查明山西省晋祠泉泉水断流、泉口水位下降及近年来泉口水位回升的原因,为泉水复流工作提供理论参考,以长系列气象、水文、开采量、泉流量、地下水位等资料为基础,在详细分析了晋祠泉域不同水动力分区年内、年际动态特征的基础上,从自然气候与人类活动两方面出发,阐述了不同历史时期晋祠泉域岩溶水位变化的影响因素。结果表明：1956-1994年,因20世纪80、90年代人工开采量达到历史高峰期,一度超过2.4 m³/s,且80年代以后我国北方干旱化发展趋势较为严重,晋祠泉水流量逐渐减小直至断流;1994-2008年,人工开采量虽有一定程度减少,但仍维持在2.0 m³/s左右,且恰逢连续枯水年,降水量、河流径流量较多年平均值分别减小了11%和27%,此阶段泉口水位快速下降至历史最低值;2008年以后进入相对丰水期,在采取多项措施减少泉域岩溶水开采量的同时,汾河二库蓄水水位逐步抬高,其对岩溶水的渗漏补给量在经历了约2 a的滞后期后到达泉域排泄区,晋祠泉口水位近年来逐步回升。     

Basaltic and Solution Reference Materials for Iron,Copper and Zinc Isotope Measurements

Iron, Cu and Zn stable isotope systems are applied in constraining a variety of geochemical and environmental processes. Secondary reference materials have been developed by the Institute of Geology, Chinese Academy of Geological Sciences (CAGS), in collaboration with other participating laboratories, comprising three solutions (CAGS‐Fe, CAGS‐Cu and CAGS‐Zn) and one basalt (CAGS‐Basalt). These materials exhibit sufficient homogeneity and stability for application in Fe, Cu and Zn isotopic ratio determinations. Reference values were determined by inter‐laboratory analytical comparisons involving up to eight participating laboratories employing MC‐ICP‐MS techniques, based on the unweighted means of submitted results. Isotopic compositions are reported in per mil notation, based on reference materials IRMM‐014 for Fe, NIST SRM 976 for Cu and IRMM‐3702 for Zn. Respective reference values of CAGS‐Fe, CAGS‐Cu and CAGS‐Zn solutions are as follows: δ⁵⁶Fe = 0.83 ± 0.07 and δ⁵⁷Fe = 1.20 ± 0.13, δ⁶⁵Cu = 0.57 ± 0.06, and δ⁶⁶Zn = ?0.79 ± 0.12 and δ⁶⁸Zn = ?1.65 ± 0.24, respectively. Those of CAGS‐Basalt are δ⁵⁶Fe = 0.15 ± 0.07, δ⁵⁷Fe = 0.22 ± 0.10, δ⁶⁵Cu = 0.12 ± 0.08, δ⁶⁶Zn = 0.17 ± 0.13, and δ⁶⁸Zn = 0.34 ± 0.26 (2s).     

Antioxidant system responses in two co-occurring green-tide algae under stress conditions

Green tides have occurred every year from 2007 to 2014 in the Yellow Sea. Ulva prolifera(Müller) J. Agardh has been identified as the bloom-forming alga,co-occurring with U. intestinalis. We observed distinct strategies for both algal species during green tides. U. prolifera exhibited a high abundance initially and then decreased dramatically,while U. intestinalis persisted throughout. The antioxidant system responses of these two macroalgae were compared in the late phase of a green tide(in-situ) and after laboratory acclimation. Lipid peroxidation and antioxidant system responses differed significantly between the two. Malondialdehyde and hydrogen peroxide contents increased significantly in-situ in U. prolifera,but not in U. intestinalis. In U. prolifera,we observed a significant decrease in total antioxidant ability(T-AOC),antioxidant enzymes(SOD and Apx),and non-enzyme antioxidants(GSH and As A) in-situ. U. intestinalis showed the same pattern of T-AOC and SOD,but its Gpx,Apx,and GSH responses did not differ significantly. The results suggest that U. prolifera was more susceptible than U. intestinalis to the harsh environmental changes during the late phase of a Yellow Sea green tide. The boom and bust strategy exhibited by U. prolifera and the persistence of U. intestinalis can be explained by differences in enzyme activity and antioxidant systems.     

The Characteristic Patterns of Macrofaunal Fouling Assemblages in Nearshore Waters of the South China Sea

The spatio-temporal patterns of macrofaunal fouling assemblages were quantitatively investigated in the nearshore waters of the South China Sea. The work was undertaken by deploying seasonal panels at two sites (H-site, L-site) for one year, and the fouling communities on the panels were examined and analyzed. The results indicated that species composition of assemblages was obviously different between the two sites. At both sites the assemblages were characteristic with solitary dominant species throughout the year, with Amphibalanus reticulates dominating at H-site and Hydroides elegans at L-site. Shannon index and biomass of the assemblages varied with depth and season at both sites. At H-site the total biomass in summer and autumn were significantly higher than those in spring and winter, while at L-site the assemblage biomass also differed significantly among the four seasons, and the greatest biomass occurred at the depth of 2.0 m in winter. The abundance of all seasonal samples in non-metric multidimensional scaling was clustered as one group at L-site and three groups at H-site. The environmental factors were more likely to be related to the variation of fouling assemblages. Furthermore, it also suggests that in tropical seas the integrated adaptability would qualify a species for dominating a fouling assemblage despite its short life cycle, rather than the usually assumed only species with long life span. This study reveals the complexity and characteristic dynamics of macrofaunal fouling assemblages in the tropical habitats, and the results would provide valuable knowledge for biodiversity and antifouling research.     

承德地区石炭-二叠系层序岩相古地理

将层序地层学方法应用于岩相古地理研究中,首先建立承德地区石炭一二叠系层序地层格架,然后以四级层序为基本编图单元,编制岩相古地理图。分析了石炭一二叠系的沉积演化特征,讨论了层序地层、岩相古地理与聚煤作用的关系。在研究区识别出2个三级层序、5个四级层序、8个五级层序;揭示了海平面升降变化对成煤沼泽发育的控制,认为层序DS1的海侵或海退最大点处的四级层序Ⅲ控制了研究区两个主采煤层的发育。该结论对该区聚煤规律的研究和煤炭资源预测有一定的参考价值。