东江下游河段溯源侵蚀特征与机理

1980年以来,东江下游及三角洲发生了高强度的采沙活动,由此导致水文条件发生显著变异,河床形态出现溯源变形,根据不同历史时期的地形与水文资料的对比分析,东江下游段溯源变形特征主要表现为:①大规模采沙直接引起同流量条件下水位大幅下降,尤以枯水期表现最为显著,博罗站水位~流量关系曲线表现为逐年右偏;②采沙引起河床高程大规模降低,即为一级溯源变形,其显著的特征是水面比降大,由此引起河床发生强烈冲刷,遂派生出河床演变的二级溯源变形,二级溯源变形的长期发展将使河床变形趋于平缓;③采沙河段必然发生河床断面形态及尺度的物理变形,按其发生的时间过程分为各具特色的3段:变形完成段(东江网河区)、变形进行段(石龙到博罗段)及变形影响段(博罗以上河段).     

大孔径闪烁仪观测数据在陆面模式验证中的应用初探

将大孔径闪烁仪(LAS)观测数据应用在陆面模式验证中对更好地认识和描述陆面过程在气候变化中的作用有着重要意义.以中国北方2个LAS观测站--密云和阿柔为例,分别设定一个公里尺度(1 km2)的研究区域,采用陆面模式SiB2,综合利用站点观测数据、实地调查数据及卫星遥感数据,对陆面过程进行了模拟,并利用LAS和涡动相关仪(EC)观测的显热通量对模拟结果进行了评估,结果表明:SiB2模式能够对阿柔和密云显热通量的总体情况、日变化情况及季节变化情况进行较好的模拟;利用LAS显热通量进行较大尺度模拟验证,能够在很大程度上避免EC能量不闭合及其观测尺度与模式模拟尺度不匹配在验证中所造成的偏差,验证效果更好.     

基于最优加权组合的甘肃金川矿14行风井变形预测

金川14行风井直接关系到矿山的安全生产。本文建立了3种单一预测模型,并根据最优加权组合原理得到了最优加权组合预测模型。最优加权组合预测模型包含了单一模型的有效信息,提高了变形的预测精度。最优加权组合预测模型的模型精度与权重分配与单一模型的选取有关。作为一种短期预测模型,得出金川14行风井在近两个半年会保持稳态变形,不会出现大的突变。     

金川二矿区14行风井返修支护效果分析

针对金川二矿区14行风井的返修支护方案,本文根据金川矿区高应力破碎岩体的条件,从锚杆、喷射混凝土、钢筋网三方面,分析了该方案中喷锚网支护的作用机理,并通过数值方法分析了该返修支护方案的效果。研究结果表明:14行风井的返修支护措施对竖井围岩移动、变形有一定的限制作用,但效果不是很好;随着开采深度和规模的扩大,井筒围岩还将产生较大的位移,并有可能重新发生破坏。     

新疆北部镁铁-超镁铁质岩的PGE成矿问题

铂族元素(PGE)矿化主要与镁铁-超镁铁杂岩有关,成矿类型主要为岩浆型矿床,这类PGE矿床的形成主要依赖两个条件:一是岩浆中富含PGE;二是具备PGE从岩浆中分离和富集的机制,主要是在岩浆演化过程中硫达到饱和。新疆北部镁铁-超镁铁质杂岩发育,并产有喀拉通克、黄山、黄山东、图拉尔根4个大型铜镍矿床和香山、土墩、葫芦、白石泉等中、小型铜镍矿,以及香山西、尾亚等中型钒钛磁铁矿矿床,但迄今尚未发现成型的PGE矿床。文中通过对PGE矿床的形成机制与镁铁-超镁铁杂岩源区特征研究,探讨了北疆地区PGE矿床的成矿问题。综合分析认为,新疆北部后碰撞镁铁-超镁铁质岩的岩石类型为经过了分离结晶形成的铁质岩石系列,是PGE矿床的有利容矿岩石;矿床的Sr、Nd、Pb、O、Os和S同位素和含矿岩石地球化学特征表明,铜镍硫化物矿床含矿岩浆在岩浆演化和成矿过程中有地壳物质加入并可导致硫化物熔离作用,说明在成矿机制上也存在形成岩浆型PGE矿化的条件。新疆北部PGE矿化微弱的原因可能在于该区广泛发育的亏损型地幔源(具正的εNd值特征),这一亏损型地幔可能部分源于洋壳熔融,与产于后碰撞造山带环境、发育于"洋壳"或"不成熟"陆壳基底之上有关,由此决定了原始岩浆为贫PGE的源区,因此不利于PGE的富集成矿。     

强烈气洗作用导致原油成分变化的定量计算:以库车坳陷天然气藏为例

库车坳陷以产天然气为主,同时产出少量原油和凝析油,油气充注不同步,普遍具有"油早气晚"的特点,晚期大量天然气的侵入,必然对早期聚集的油藏发生改造作用。对气藏中原油成分变化的定量计算和讨论,可为天然气的注入强度定量评价提供直接证据。未遭受气洗的原油,正构烷烃摩尔浓度的对数与相应的碳数呈线性关系,而气洗作用可使轻组分的正构烷烃最先溶解于干气中,并随着天然气继续向前运移,原始油藏中的轻组分正构烷烃大大减少。以此为理论基础,建立了正构烷烃损失的定量计算模型。结果表明克拉2构造原油正构烷烃损失程度最高,平均可达70%左右,大北构造带原油正构烷烃损失程度差异较大,与该地区断块发育有关。气洗作用导致原油正构烷烃减少,而金刚烷、多环芳烃等在天然气中溶解度较低的化合物得以浓缩富集,相对含量大大增加。轻芳烃含量也会随之而增加,原油芳香度增加,石蜡度降低。在模拟实验基础上对气洗程度进行了定量评价,初步估算表明,克拉2构造原油遭受的气洗作用最强,是其他构造带的2～5倍。     

干湿交替条件下包气带土柱中氮素迁移转化规律实验

干湿交替的回灌方法常被用于解决地面回灌补给地下水的堵塞问题。研究干湿交替条件下地面回灌对地下水的影响对于指导再生水回灌地下水具有重要实际意义。通过室内土柱模拟实验,在入渗强度为10.5 mm/h的条件下,日均进水量3 888 mL;用干湿交替的地面回灌模式持续运行136 d,累计灌入氨氮含量为5 mg/L的模拟再生水23 894 L,研究包气带土柱对氨氮的去除效果及氮素在包气带中的迁移转化规律。研究表明,充分利用包气带的好氧、兼氧和厌氧环境,生物脱氮是地下水回灌过程中脱氮的主要途径。包气带对氨氮的去除机理主要为土壤对氨氮的吸附作用和微生物的降解作用。回灌过程中累积在土颗粒表面的氨氮在干期发生硝化作用,干湿交替会加强氮素在包气带的迁移转化,导致干期后的回灌初期大量硝态氮迁移到饱和带地下水中。     

气相色谱-质谱法同时测定河流沉积物中多环芳烃和有机氯农药

建立了用加速溶剂萃取,气相色谱-质谱法同时测定河流沉积物中16种多环芳烃和19种有机氯农药的分析方法,优化了萃取溶剂、萃取温度和时间、凝胶渗透色谱收集时间、固相萃取洗脱溶剂和洗脱体积等条件。16种多环芳烃的方法检出限在0.15~0.59 ng/g,加标回收率为82%~102%,相对标准偏差(RSD,n=5)为1.1%~4.5%。19种有机氯农药的方法检出限在0.14~2.23 ng/g,加标回收率为71%~108%,相对标准偏差(RSD,n=5)为1.0%~4.5%。实际样品的测定结果表明,该方法分离效果较好,能够满足沉积物样品中多环芳烃和有机氯农药的分析要求。     

Investigating the effect of soil models on deformations caused by braced excavations through an inverse-analysis technique

In this study, a series of inverse-analysis numerical experiments was performed to investigate the effect of soil models on the deformations caused by excavation by using the finite element method. The nonlinear optimization technique that was incorporated into the finite element code was used for the inverse-analysis numerical experiments. Three soil models (the hyperbolic model, pseudo-plasticity model, and modified pseudo-plasticity model) were employed in the intended numerical experiments on a well-documented excavation case history. The results indicate that wall deflection due to excavation can be accurately back-figured by each of the three soil models, while the ground surface settlement can be reasonably optimized only by the pseudo-plasticity model and the modified pseudo-plasticity model. Importantly, the modified pseudo-plasticity model can yield more reasonable simulations when the wall deflection and the ground surface settlement are simultaneously back-figured. The results show that selection of an adequate soil model that is capable of adequately describing the stress–strain-strength characteristics of the soils is essentially crucial when predicting the excavation-induced ground response.     

A geochemical survey of trace elements in agricultural and non-agricultural topsoil in Dexing area,China

In China, soil pollution is very serious, which has jeopardized the ecology, food safety, the people's health, and even the sustainable development of agriculture. In order to investigate the soil pollution situation, a total of 874 agricultural and non-agricultural topsoil samples were collected from Dexing area, northeast of Jiangxi Province, China. The total elemental concentrations of 17 elements (As, Hg, Mo, Cd, Cr, Zn, Cu, Mn, Ti, Pb, Fe, Ca, K, Si, Al, Mg, and Na) were determined. The geochemical background and threshold was predicted with the method of the median ± median absolute deviation (MAD). The agricultural soil median concentration of trace elements was similar to that of the non-agricultural soil. In contrast to Jiangxi soil background of trace elements, the geochemical background of the study area was obviously higher. The maps of the pollution indices for As, Cd, Cr, Cu, Hg, Mn, Mo, Pb, Ti and Zn of non-agricultural soil and agricultural soils in the study area, showed that the highest level of pollution is distributed near and along the Lean River, especially in the neighboring and surrounding Dexing and Leping mining area.