Coupled Ce-Nd isotope systematics and rare earth elements differentiation of the moon

¹³⁸Ce/¹⁴²Ce and ¹⁴³Nd/¹⁴⁴Nd isotope ratios of lunar samples are determined to constrain the petrogenetic differentiation and evolution of the moon. High-precision Ce-Nd isotope data, well-defined Rb-Sr isochrons, and rare earth elements (REE) abundances of lunar samples show that unexpectedly low La/Ce ratios of evolved lunar highland samples are preserved from at least 3.9 Ga. Precise analysis of REE abundances indicates that the low La/Ce ratio results from a depletion of La relative to other REE. This depletion can be seen in pristine KREEP basalts and Mg-suite rocks from 3.85 to 4.46 Ga. As REE abundances of all these samples are controlled by the presence of a KREEP component, the depletion was probably inherited from a late crystallization sequence of the lunar magma ocean related to the production of the original KREEP component.     

A study of the groundwater cycle in Sri Lanka using stable isotopes

The characteristics of the groundwater cycle were researched using stable isotope technology in western Sri Lanka where climatic conditions change greatly within a relatively short distance. The effects of local climate, surface water and topography on the groundwater cycle in the study area with similar geological conditions were investigated. Sri Lanka can be divided spatially into a dry zone, an intermediate zone and a wet zone, and also temporally into the rainy season and the dry season. The zonal characteristics of the groundwater cycle were also elucidated using stable isotopic technology. As an input δ diagram of precipitation in the study area, there are obvious seasonal changes in the isotopic composition and a magnitude effect, both in the wet zone and dry zone. In the wet zone, the slope of the regression line between δ D and δ ¹⁸O and deuterium excess is close to 8 and 10, respectively. However, in the dry zone, the slope of the regression line between δ D and δ ¹⁸O and deuterium excess is much less than 8 and 10, respectively. In the wet zone, there is an obvious seasonal change in the isotopic composition of groundwater. The groundwater was recharged by precipitation during the whole year. The isotopically lighter groundwater was found at the valley bottom in the rainy season there. Under the very heavy precipitation conditions, the slope of the regression line between δ D and δ ¹⁸O and deuterium excess for groundwater was close to 8 and 10, respectively. In other cases, the slopes of the regression lines are less than 8. In the dry zone, the groundwater was recharged by precipitation only in the rainy season. The isotopically lighter groundwater was found on the ridge of the valley in the rainy season. The slope of the regression line between δ D and δ ¹⁸O and deuterium excess for groundwater was much less than 8 and 10, respectively. Copyright © 1999 John Wiley & Sons, Ltd.     

Significance of stemflow in groundwater recharge. 2: A cylindrical infiltration model for evaluating the stemflow contribution to groundwater recharge

A primary model for evaluating the effect of stemflow on groundwater recharge has been developed. The model, a cylindrical infiltration model (CI model), is based on the infiltration area of stemflow-induced water instead of canopy projected area for determining the stemflow inputs to the soil surface. The estimated ratio of recharge rate by stemflow to the total recharge rate determined with this model agrees closely with values obtained from the mass balance of chloride in subsurface waters. This primary model is considered to be useful for estimating the effect of stemflow on groundwater recharge.     

Circulation patterns in the lower Arctic Ocean derived from geochemical data

Climatological water-mass structures were identified in the Arctic Ocean using the geochemical dataset in the Hydrochemical Atlas of the Arctic Ocean (HAAC) as well as data on a geochemically conserved parameter, PO₄*, based on phosphate and dissolved oxygen. In the upper ocean above a depth of 500 m, the HAAC was found to reliably depict the boundary between Pacific-Origin Water (P-Water) and Atlantic-Origin Water (A-Water), which is aligned 135°E–45°W near the surface but rotates counterclockwise with depth. Thus, the Arctic and Atlantic oceans exchange high-silicate P-Water and low-silicate A-Water. The PO₄* field in the lower ocean below a depth of 1500 m was analyzed statistically, and the results indicated that the Eurasian Basin receives low-PO₄* Nordic Seas Deep Water, which flows along the bottom from the Greenland Sea. The routes from the upper ocean to the lower ocean were determined. Only the southern portion of the Canada Basin, which receives water from the Chukchi and Beaufort Seas, has high PO₄* levels; the rest of the Amerasian Basin receives low-PO₄* water from the Laptev Sea and/or the Barents Sea. The Eurasian Basin receives moderate levels of PO₄* from the Fram Strait and from the intermediate layer. The intermediate-layer water gradually travels up from the lower ocean and returns to the Atlantic, entraining the subsurface portion. It is likely that high-PO₄* water occasionally flows down from the upper ocean along Greenland, making the Eurasian Basin heterogeneous.     

Estimating the provincial environmental Kuznets curve in China: a geographically weighted regression approach

This study estimates the environmental Kuznets curve (EKC) relationship at the province level in China. We apply empirical methods to test three industrial pollutants—SO₂ emission, wastewater discharge, and solid waste production—in 29 Chinese provinces in 1994–2010. We use the geographically weighted regression (GWR) approach, wherein the model can be fitted at each spatial location in the data, weighting all observations by a function of distance from the regression point. Hence, considering spatial heterogeneity, the EKC relationship can be analyzed region-specifically through this approach, rather than describing the average relationship over the entire area examined. We also investigate the spatial stratified heterogeneity to verify and compare risk factors that affect regional pollution with statistical models. This study finds that the GWR model, aimed at considering spatial heterogeneity, outperforms the OLS model; it is more effective at explaining the relationships between environmental performance and economic growth in China. The results indicate a significant variation in the existence of the EKC relationship. Such spatial patterns suggest province-specific policymaking to achieve balanced growth in those provinces.     

Eccentric installation of splice plates for compressive strength improvement of rectangular hollow section braces

Steel hollow section members are often applied as bracing in steel structures. Field-bolted connections of the slotted-in single splice plate and the gusset plate are popular because of their ease of construction. However, eccentricity between the splice and gusset plate axes reduces the compressive strength of the brace. This study proposes compressive strength improvement of rectangular hollow section braces using eccentrically installed splice plates such that the gusset plate axis coincides with the brace axis. To demonstrate the efficacy of the proposed concept, four compressive loading test results are examined in this study. Test results reveal the influences of splice plate eccentric installation on the brace compressive strength, the out-of-plane displacement, and the strain distribution. The proposed concept is effective for the brace with stiffened splice plates for inducing overall buckling with plastic hinges in the gusset plates. Variation of compressive strength is finally discussed based on the discrepancy between the brace axis and the axis of the plates in which the plastic hinges form at the overall buckling mode ends.     

Japan's earliest ostracods

Mesozoic, Cenozoic and especially Holocene ostracod faunas have been documented from Japan. Not surprisingly, considering the plate tectonic factors at play, very few ostracod faunas are known from its early Paleozoic successions. Our pilot studies have recovered new ostracod assemblages from early Paleozoic terranes of Japan. Acid preparation of carbonates has yielded low diversity, poorly preserved yet significant palaeocopid and podocopid ostracod faunas from Wenlock/Ludlow Series Silurian rocks at Gionyama in the Kurosegawa Terrane, Miyazaki Prefecture, Kyushu, and Hitoegane in the Hida‐Gaien Terrane, Gifu Prefecture, Honshu. The ostracod faunas include new eurychilinoid (Pauproles supparata gen. et sp. nov.), hollinoid (Hollinella orienta sp. nov.) and beyrichioid (Clintiella antifrigga sp. nov.) palaeocopid taxa. Conodonts recovered from the same sample as the ostracods from Gionyama confirm a mid‐Silurian age for the part of the Gionyama Formation in question. The ostracod faunas recovered from Gionyama and Hitoegane are the first confirmed, well‐documented record of the group from the Silurian of Japan and are therefore the earliest known ostracods from that country (a previous record of purported Ordovician ostracods from Japan is incorrect). The ostracod taxa display links with the paleocontinents of particularly Laurentia and Baltica and demonstrate a pan‐tropical signature; it appears that climate control was stronger than geographical control in shaping this pattern of ostracod distribution. The material recovered includes adult dimorphic (assumed sexual) pairs of three palaeocopid species, which represent Japan's oldest (423–433 million years) known ‘couples’.     

Occurrence of juvenile Japanese flounder Paralichthys olivaceus in brackish estuaries

Juvenile Japanese flounder Paralichthys olivaceus usually inhabit high salinity inshore sandy areas. In June–August 1997, 25 individuals of juvenile Japanese flounder (33–75 mm total length) were collected in the Natori and Nanakita River estuaries in Sendai Bay, Japan. This is the first record of this species being collected in brackish estuaries in which salinities fluctuate from 0 to 30 over a spring tidal cycle. Factors of rainfall, river flow, or year class strength of Japanese flounder were unable to explain the unusual occurrence of this species in the estuaries. The collected juvenile Japanese flounder were considered to have migrated into the estuaries around the time of the passage of an unusually early typhoon that affected this area, indicating the possibility that this species utilizes estuaries for refuge from strong disturbance in its usual habitats. The juveniles fed mainly upon mysids both in the estuaries and the sandy beach area, indicating that estuaries can be a substitute nursery habitat for this species.     

Water masses and currents of deep circulation southwest of the Shatsky Rise in the western North Pacific

We conducted full-depth hydrographic observations in the southwestern region of the Northwest Pacific Basin in September 2004 and November 2005. Deep-circulation currents crossed the observation line between the East Mariana Ridge and the Shatsky Rise, carrying Lower Circumpolar Deep Water westward in the lower deep layer (θ<1.2 °C) and Upper Circumpolar Deep Water (UCDW) and North Pacific Deep Water (NPDW) eastward in the upper deep layer (1.3–2.2 °C). In the lower deep layer at depths greater than approximately 3500 m, the eastern branch current of the deep circulation was located south of the Shatsky Rise at 30°24′–30°59′N with volume transport of 3.9 Sv (1 Sv=10⁶ m³ s⁻¹) in 2004 and at 30°06′–31°15′N with 1.6 Sv in 2005. The western branch current of the deep circulation was located north of the Ogasawara Plateau at 26°27′–27°03′N with almost 2.1 Sv in 2004 and at 26°27′–26°45′N with 2.7 Sv in 2005. Integrating past and present results, volume transport southwest of the Shatsky Rise is concluded to be a little less than 4 Sv for the eastern branch current and a little more than 2 Sv for the western branch current. In the upper deep layer at depths of approximately 2000–3500 m, UCDW and NPDW, characterized by high and low dissolved oxygen, respectively, were carried eastward at the observation line by the return flow of the deep circulation composing meridional overturning circulation. UCDW was confined between the East Mariana Ridge and the Ogasawara Plateau (22°03′–25°33′N) in 2004, whereas it extended to 26°45′N north of the Ogasawara Plateau in 2005. NPDW existed over the foot and slope of the Shatsky Rise from 29°48′N in 2004 and 30°06′N in 2005 to at least 32°30′N at the top of the Shatsky Rise. Volume transport of UCDW was estimated to be 4.6 Sv in 2004, whereas that of NPDW was 1.4 Sv in 2004 and 2.6 Sv in 2005, although the values for NPDW may be slightly underestimated, because they do not include the component north of the top of the Shatsky Rise. Volume transport of UCDW and NPDW southwest of the Shatsky Rise is concluded to be approximately 5 and 3 Sv, respectively. The pathways of UCDW and NPDW are new findings and suggest a correction for the past view of the deep circulation in the Pacific Ocean.     

Distinctive stable isotope ratios in important zooplankton species in relation to estuarine salinity gradients: Potential tracer of fish migration

To assess the potential of stable isotope ratios as an indicator of fish migration within estuaries, stable isotope ratios in important zooplankton species were analyzed in relation to estuarine salinity gradients. Gut contents from migratory juveniles of the euryhaline marine fish Lateolabrax japonicus were examined along the Chikugo River estuary of the Ariake Sea, which has the most developed estuarine turbidity maximum (ETM) in Japan. Early juveniles in March and April preyed primarily on two copepod species; Sinocalanus sinensis at lower salinities and Acartia omorii at higher salinities. Late juveniles (standard length > 40 mm) at lower salinities preyed exclusively on the mysid Acanthomysis longirostris until July and complementarily on the decapod Acetes japonicus in August. These prey species were collected along the estuary during the spring–summer seasons of 2003 and 2004, and their carbon and nitrogen stable isotope ratios (δ¹³C and δ¹⁵N) were evaluated. The δ¹³C values of prey species were distinct from each other and were primarily depleted within and in close proximity to the ETM (salinity < 10); S. sinensis (−26.6‰) < Acanthomysis longirostris (−23.3‰) < Acartia omorii (−21.1‰) < Acetes japonicus (−18.5‰). The overall gradient of δ¹³C with salinity occurred for all prey species and showed minor temporal fluctuations, while it was not directly influenced by the δ¹³C values in particulate organic matter along the estuary. In contrast to δ¹³C, the δ¹⁵N values of prey species did not exhibit any clear relationship with salinity. The present study demonstrated that δ¹³C has the potential for application as a tracer of fish migration into lower salinity areas including the ETM.