Analysis of the intensities and profiles of the spectral line Mg xii 8.42 Å in the solar X-ray spectrum

High resolution profiles of the Mg xii 8.42 Å line in the solar X-ray spectrum were recorded from the Intercosmos 7 satellite. The Mg xii line intensity provides a sensitive indicator of the hot plasma content (T ? 3 × 10⁶ K) in coronal condensations and X-ray flare volumes. The ratio of the line intensity to the intensity of the adjacent continuum has been used to compute approximate thermal models of the emitting regions. For all the investigated coronal condensations the temperature distribution of plasma has been found to be a function monotonically decreasing with temperature. But for some X-ray bursts there occurred a distinct excess of the hot plasma of temperature between 6–10 × 10⁶K. FWHM values of the Mg xii line profiles have been used to estimate ion temperature in the emitting regions.     

Coronal changes associated with a disappearing filament

This paper describes Skylab/ATM observations of the events associated with a disappearing filament near the center of the solar disk on January 18, 1974. As the filament disappeared, the nearby coronal plasma was heated to a temperature in excess of 6 × 10⁶K. A change in the pattern of coronal emission occurred during the 11/3 hr period that the soft X-ray flux was increasing. This change seemed to consist of the formation and apparent expansion of a loop-like coronal structure which remained visible until its passage around the west limb several days later. The time history of the X-ray and microwave radio flux displayed the well-known gradual-rise-and-fall (GRF) signature, suggesting that this January 18 event may have properties characteristic of a wide class of X-ray and radio events.In pursuit of this idea, we examined other spatially-resolved Skylab/ATM observations of long-duration X-ray events to see what characteristics they may have in common. Nineteen similar long-lived SOLRAD X-ray events having either the GRF or post-burst radio classification occurred during the nine-month Skylab mission. Sixteen of these occurred during HAO/ATM coronagraph observations, and 7 of these 16 events occurred during observations with both the NRL/ATM slitless spectrograph and the MSFC-A/ATM X-ray telescope. The tabulation of these events suggests that all long-lived SOLRAD X-ray bursts involve transients in the outer corona and that at least two-thirds of the bursts involve either the eruption or major activation of a prominence. Also, these observations indicate that long-lived SOLARD events are characterized by the appearance of new loops of emission in the lower corona during the declining phase of the X-ray emission. However, sometimes these loops disappear after the X-ray event (like the post-flare loops associated with a sporadic coronal condensation), and sometimes the loops remain indefinitely (like the emission from a permanent coronal condensation).Visiting Scientist, Kitt Peak National Observatory, Tucson, Ariz. 85726, U.S.A. operated by the Association of Universities for Research in Astronomy, Inc., under contract with the National Science Foundation.Presently located at NASA/MSFC, Space Sciences Laboratory, Marshall Space Flight Center, Ala. 35812, U. S.A.     

Vapor pressures and evaporation coefficients for melts of ferromagnesian chondrule-like compositions

To determine evaporation coefficients for the major gaseous species that evaporate from silicate melts, the Hertz-Knudsen equation was used to model the compositions of residues of chondrule analogs produced by evaporation in vacuum by Hashimoto [Hashimoto A. (1983) Evaporation metamorphism in the early solar nebula-evaporation experiments on the melt FeO-MgO-SiO₂-CaO-Al₂O₃ and chemical fractionations of primitive materials. Geochem. J. 17, 111-145] and Wang et al. [Wang J., Davis A. M., Clayton R. N., Mayeda T. K., Hashimoto A. (2001) Chemical and isotopic fractionation during the evaporation of the FeO-MgO-SiO₂-CaO-Al₂O₃-TiO₂ rare earth element melt system. Geochim. Cosmochim. Acta 65, 479-494], in vacuum and in H₂ by Yu et al. [Yu Y., Hewins R. H., Alexander C. M. O’D., Wang J. (2003) Experimental study of evaporation and isotopic mass fractionation of potassium in silicate melts. Geochim. Cosmochim. Acta 67, 773-786], and in H₂ by Cohen et al. [Cohen B. A., Hewins R. H., Alexander C. M. O’D. (2004) The formation of chondrules by open-system melting of nebular condensates. Geochim. Cosmochim. Acta 68, 1661-1675]. Vapor pressures were calculated using the thermodynamic model of Ghiorso and Sack [Ghiorso M. S., Sack R. O. (1995) Chemical mass transfer in magmatic processes IV. A revised and internally consistent thermodynamic model for the interpolation and extrapolation of liquid-solid equilibria in magmatic systems at elevated temperatures and pressures. Contrib. Mineral. Petrol. 119, 197-212], except for the late, FeO-free stages of the Wang et al. (2001) and Cohen et al. (2004) experiments, where the CMAS activity model of Berman [Berman R. G. (1983) A thermodynamic model for multicomponent melts, with application to the system CaO-MgO-Al₂O₃-SiO₂. Ph.D. thesis, University of British Columbia] was used. From these vapor pressures, evaporation coefficients (α) were obtained that give the best fits to the time variation of the residue compositions. Evaporation coefficients derived for Fe_(g), Mg_(g), and SiO_(g) from the Hashimoto (1983) experiments are similar to those found by Alexander [Alexander C. M. O’D. (2004) Erratum. Meteoritics Planet. Sci. 39, 163] in his EQR treatment of the same data and also adequately describe the FeO-bearing stages of the Wang et al. (2001) experiments. From the Yu et al. (2003) experiments at 1723 K, α_Na = 0.26 ± 0.05, and α_K = 0.13 ± 0.02 in vacuum, and α_Na = 0.042 ± 0.020, andα_K = 0.017 ± 0.002 in 9 × 10⁻⁵ bar H₂. In the FeO-free stages of the Wang et al. (2001) experiments, α_Mg and α_SiO are significantly different from their respective values in the FeO-bearing portions of the same experiments and from the vacuum values obtained at the same temperature by Richter [Richter F. M., Davis A. M., Ebel D. S., Hashimoto A. (2002) Elemental and isotopic fractionation of Type B calcium-, aluminum-rich inclusions: experiments, theoretical considerations, and constraints on their thermal evolution. Geochim. Cosmochim. Acta 66, 521-540] for CMAS compositions much lower in MgO. When corrected for temperature, the values of α_Mg and α_SiO that best describe the FeO-free stages of the Wang et al. (2001) experiments also adequately describe the FeO-free stage of the Cohen et al. (2004) H₂ experiments, but α_Fe that best describes the FeO-bearing stage of the latter experiment differs significantly from the temperature-corrected value derived from the Hashimoto (1983) vacuum data.     

Layered mantle structure beneath the western Guyana Shield, Venezuela: Evidence from diamonds and xenocrysts in Guaniamo kimberlites

Mantle xenoliths and xenocrysts from Guaniamo, Venezuela kimberlites record equilibration conditions corresponding to a limited range of sampling in the lithosphere (100-150 km). Within this small range, however, compositions vary considerably, but regularly, defining a strongly layered mantle sequence. Major and trace element compositions suggest the following lithologic sequence: highly depleted lherzolite from 100 to 115 km, mixed ultra-depleted harzburgite and lherzolite from 115 to 120 km, relatively fertile lherzolite from 120 to 135 km, and mixed depleted harzburgite and relatively fertile lherzolite from 135 to 150 km. Based on comparison with well-documented mantle peridotites and xenocrysts from elsewhere, we conclude that the Meso-proterozoic Cuchivero Province (host to the Guaniamo kimberlites) is underlain by depleted and ultra-depleted shallow Archean mantle that was underplated, and uplifted, by Proterozoic subduction, perhaps more than once. These Proterozoic subduction events introduced less-depleted oceanic lithosphere beneath the Archean section, which remains there and is the source of the abundant Guaniamo eclogite-suite diamonds that have ocean-floor geochemical signatures. Although diamond-indicative low-Ca Cr-pyrope garnets are abundant, they are derived primarily from the shallow depleted layer within the field of graphite stability, and the rare peridotite-suite diamonds are either metastably preserved at these shallow depths, or were derived from the small amount of depleted lithosphere sampled by these kimberlites that remains within the diamond stability field (the mixture of Archean and Proterozoic mantle in the depth range 135-150 km).     

The impact of vegetation on REE fractionation in stream waters of a small forested catchment (the Strengbach case)

Previous studies on waters of a streamlet in the Vosges Mountains (Eastern France) have shown that strontium and rare earth elements (REE) mainly originate from preferential dissolution of apatite during weathering. However, stream water REE patterns normalized to apatite are still depleted in the light REE (LREE, La-Sm) pointing to the presence of an additional LREE depleting process. Vegetation samples are strongly enriched in LREE compared to stream water and their Sr and Nd isotopic compositions are comparable with those of apatite and stream water. Thus, the preferential LREE uptake by vegetation might lead to an additional LREE depletion of surface runoff in the forested catchment. Mass balance calculations indicate, that the yearly LREE uptake by vegetation is comparable with the LREE export by the streamlet and, therefore, might be an important factor controlling LREE depletion in river water. This is underlined by the observation that rivers from arctic and boreal regions with sparse vegetation appear to be less depleted in LREE than rivers from tropical environments or boreal environments with a dense vegetation cover.     

Study on the kinetics of iron oxide leaching by oxalic acid

The presence of iron oxides in clay or silica raw materials is detrimental to the manufacturing of high quality ceramics. Although iron has been traditionally removed by physical mineral processing, acid washing has been tested as it is more effective, especially for extremely low iron (of less than 0.1% w/w). However, inorganic acids such as sulphuric or hydrochloric acids easily contaminate the clay products with SO₄²⁻ and Cl⁻, and therefore should be avoided as much as possible. On the other hand, if oxalic acid is used, any acid left behind will be destroyed during the firing of the ceramic products. The characteristics of dissolution of iron oxides were therefore investigated in this study.The dissolution of iron oxides in oxalic acid was found to be very slow at temperatures within the range 25–60 °C, but its rate increases rapidly above 90 °C. The dissolution rate also increases with increasing oxalate concentration at the constant pH values set within the optimum range of pH2.5–3.0. At this optimum pH, the dissolution of fine pure hematite (Fe₂O₃) (105–140 μm) follows a diffusion-controlled shrinking core model. The rate expression expressed as 1 − (2 / 3)x − (1 − x)^2 / 3 where x is a fraction of iron dissolution was found to be proportional to [oxalate]^1.5.The addition of magnetite to the leach liquor at 10% w/w hematite was found to enhance the dissolution rate dramatically. Such addition of magnetite allows coarser hematite in the range 0.5–1.4 mm to be leached at a reasonable rate.