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921.
Water quality and presence of pesticides in a tropical coastal wetland in southern Mexico 总被引:6,自引:0,他引:6
Hernández-Romero AH Tovilla-Hernández C Malo EA Bello-Mendoza R 《Marine pollution bulletin》2004,48(11-12):1130-1141
The water quality of the Pozuelos-Murillo lagoon system in southern Mexico was evaluated during three periods between March and October 2002, with particular emphasis on the detection of organochlorine and organophosphorous pesticide residues in water and sediments. Physicochemical and microbiological parameters of water were also measured and integrated in a water quality index (WQI). Multivariate analysis was used to regionalise the lagoon system as a function of the behaviour of all measured parameters. Solid phase micro-extraction followed by gas chromatography (SPME-GC) was used for pesticide analysis. The concentration of phosphorous was found to be higher than that of nitrogenous compounds. This, besides a deficiency in dissolved oxygen and a high organic matter concentration (as COD), reflects eutrophication processes in some areas of the system. Measured levels of faecal coliforms and oils and greases were above the limits established by Mexican law and comparable to the concentrations reported for other highly polluted systems in Mexico. Residues of DDD (2.0 microg L(-1)) in water and DDE (247 ng g(-1)) and endosulfan I (814 ng g(-1)) sediments were detected by SPME-GC. The spatial distribution of these contaminants implies major potential risks because the most polluted sites were found to be those with the highest fishing activity. Although in general the WQI is on acceptable levels (65-80%), some contamination problems are evident. 相似文献
922.
We employ a realistic finite-extent k
-2 stochastic source model with k-dependent rise time, introduced by Bernard et al. (1996) and extended by Gallovi and Brokeová (2004), to synthesize the strong ground motions in near source distances. For a given magnitude, this rupture model involves a number of free parameters (fault dimensions, slip roughness, maximum rise time, slip velocity function). We study their influence on the peak ground acceleration (PGA) maps (parametric study) for an example of the 1999 Athens earthquake of M
w = 5.9. The observed macroseismic intensities serve us as a rough constraint on the simulated PGA's to find a set of suitable k
-2 models. These models agree with empirical source scaling relations. 相似文献
923.
Investigation of natural and anthropogenic hydrocarbon inputs in sediments using geochemical markers. I. Santos, SP--Brazil 总被引:2,自引:0,他引:2
A study on the inputs of organic matter to marine sediments of Santos Bay and Estuary, located in southeastern S?o Paulo State, Brazil, is presented here. The following geochemical markers were identified and quantified: aliphatic hydrocarbons (normal and isoprenoid alkanes), petroleum biomarkers, linear alkylbenzenes (LABs) and polycyclic aromatic hydrocarbons (PAHs). Sediment samples, collected at 15 sites in the bay and surrounding channels, were extracted and analyzed by gas chromatography with flame ionization and mass spectrometer detectors. Total concentrations varied from 0.17 to 107.80 microg g(-1) for aliphatics, from 47.2 to 2560.1 ng g(-1) for petroleum biomarkers, from 16.9 to 430.6 ng g(-1) for LABs and from 79.6 to 15389.1 ng g(-1) for PAHs. Anthropogenic contributions were apparent, indicating the influences of the Cubatao industrial complex, sewage outfalls along the area, the waste deposit of Santos city and storage facilities for petroleum and derivatives, based on the higher concentrations of geochemical markers detected. 相似文献
924.
925.
This study presents a new method for Atterberg limits measurements using dynamic drying. Indeed, for some polluted clays, or clay mixtures, classical methods cannot be used. The principle of liquid and plasticity limits determination by this method is presented. Experimental values for classical clays are close to those obtained with Casagrande's methods, allowing for larger physical mud characterisation. To cite this article: C. Proust et al., C. R. Geoscience 336 (2004). 相似文献
926.
The tilt-angle variation of solar bipolar magnetic regions (BMRs) in space and time is a probable indicator of large-scale properties of magnetic field distribution, the dynamo and other different processes affecting the rising of magnetic flux tubes. We analyze the tilt-angle distribution and evolution of clearly oriented BMRs using sunspot position and area measurements from the Greenwich Photo-Heliographic Results (GPHR) supplemented by high-quality full-disk sunspot drawings made in the Haynald Observatory in Hungary. Our work is made on the basis of the 14th sunspot cycle and we compare our results with present theories of magnetic flux evolution in the convective zone. Our results support the assumption that the scatter of tilt angles of BMRs around Joy`s law is determined by the convective turbulence. Furthermore, we find that regular BMRs grouped by age generally do not show the phenomenon of toroidal relaxation towards the east–west direction. We interpret this by the disconnection of -loops from the bottom of the convection zone. 相似文献
927.
928.
Carvalho S Gaspar MB Moura A Vale C Antunes P Gil O da Fonseca LC Falcão M 《Marine pollution bulletin》2006,52(11):1414-1424
This study reports the longitudinal distribution of sediment properties, including inorganic and organic contaminants, and the structure of the benthic community in Obidos lagoon, a coastal system permanently connected to the sea and with negligible freshwater sources. Sediments from the upper to central lagoon consist of fine particles (91%) and from the lower lagoon of sands (94%). Chemical composition is strongly correlated to the percentage of fine particles. Contamination is relatively low in those sediments suggesting the effect of diffuse sources. The increase in organic matter content from down- to upstream areas was associated with the dominance of opportunistic species, while sensitive and indifferent species to organic enrichment were mainly associated to the clean sandy downstream area. The marine biotic index (AMBI) was suitable for the discrimination of the biological and environmental gradients in the Obidos lagoon and was highly related with the gradient of organic matter content in this system. 相似文献
929.
HAB occurrence is becoming more frequent and problematic in marine recreational waters. However, the exploitation of the coastal area for recreational use is promoting the necessary conditions for the HAB increase. In terms of the harmful effects, we can consider two types of causative organism: the toxic producers and the high-biomass producers. Toxic events can be produced by a very low concentration of the causative organism. This characteristic implies a difficulty for the monitoring programs in relation to human health. It is important to point out in the context of human health and HAB events, that in some coastal regions (e.g. the Mediterranean basin) HABs are an emerging problem. In these regions, the local population and visitors may face a health risk that is difficult to measure. The monitoring of toxic species has mainly been associated -with shellfish farming. However, the risk of intoxication could become even greater in areas not subject to legislation of aquaculture activities. 相似文献
930.
Franco MA Viñas L Soriano JA de Armas D González JJ Beiras R Salas N Bayona JM Albaigés J 《Marine pollution bulletin》2006,53(5-7):260-271
The distribution of aliphatic and aromatic hydrocarbons was determined in surface sediments collected at 36 stations along the Galicia continental shelf (NW Spain), following the Prestige oil spill. Sampling was performed in December 2002, just after the accident, and in February and September 2003. Concentrations of PAHs (summation operator 13 parent components) were in the range of 0.9-422 microg/kgdw, the highest values being close to coastal urban areas (e.g. Pontevedra and A Coru?a), whereas in the stations of the area most heavily impacted by the spill (off Costa da Morte) concentrations were in the range of 14.8-89.6 microg/kgdw, with a certain predominance of alkylated compounds, which may suggest a mixture of petrogenic and pyrolytic sources. The detailed study of petrogenic molecular markers (e.g. steranes and triterpanes) showed the occurrence of an old (weathered) petrogenic chronic pollution in the shelf sediments but not of the Prestige oil, with the possible exception of few stations in the area of Costa da Morte. This was attributed to the heavy nature of the spilled oil that was barely dispersed in the water column and mainly stranded on the coast or sedimented in the form of oil patches. The addition of increasing amounts of fuel oil to a representative sediment sample showed that the molecular indices were indicative of the presence of the Prestige oil when the amount was above 1g/kg of sediment. The toxicity of selected samples (showing the higher PAH concentrations) was tested using the bivalve embryogenesis bioassay. Embryogenesis success reached high values in all cases (80-88%, with 86% in the control), indicating a lack of toxicity in the sediments and supporting the conclusion that the patchiness of the fuel eventually reaching the seafloor reduced its impact on the benthic communities of the Galician shelf. 相似文献