Quartz and polymineral luminescence dating of Japanese loess over the last 0.6 Ma: Comparison with an independent chronology

There are only a few luminescence dating studies of loess sediments in Japan, but interleaved with these deposits are many well-described tephras of known age based on ¹⁴C and fission track analysis; these independent age controls provide an opportunity to test the reliability of loess luminescence ages. This study provides such a comparison at two sites in central Honshu, the largest island in the Japanese archipelago. Samples were collected from sequences of interleaved volcanic tephra and loess deposited on a Middle Pleistocene river terrace in the Niigata Prefecture and on an Early to Middle Pleistocene dissected fluvial surface at in the Tochigi Prefecture, Honshu. Equivalent doses (D_e) were estimated from fine grains (4–11 μm) using both polymineral IR-OSL and (post-IR) blue-OSL, and quartz blue-OSL. The blue-stimulated luminescence signals could be represented by up to three exponentially decaying components; only the most light sensitive of these components was used in the final D_e estimation. Almost all the estimates of D_e from polymineral IR-OSL are smaller than those from polymineral (post-IR) blue-OSL and quartz blue-OSL, whereas the latter two are in good agreement. The blue-light stimulated luminescence ages using the most light sensitive component are shown to be in good agreement with the independent control, up to 500 ka. Although the IR-OSL signals underestimate the known age, a simple laboratory fading test is found empirically to correct for this underestimation. We conclude that the most rapidly blue-stimulated luminescence signals from quartz extracted from our loess samples give reliable ages, and that future loess dating studies should concentrate on these signals.     

Long-term high-frequency measurements of dibromomethane in the atmosphere at algae-rich and algae-poor coastal sites

Dibromomethane (CH₂Br₂), a natural stratospheric ozone depleting substance, is mostly emitted from the ocean, but the relative importance of coastal (or macroalgae) and open ocean emissions is unknown. We made long-term high-frequency measurements of CH₂Br₂ concentrations at two remote coastal sites in Japan, on the subtropical Hateruma Island (poor in macroalgae) and at Cape Ochiishi (rich in macroalgae). CH₂Br₂ concentrations at Hateruma showed prominent seasonal variation, being lower in summer (around 0.94 ppt) than in winter (around 1.23 ppt). In contrast, CH₂Br₂ concentrations at Ochiishi were highly variable, often exceeding 2 ppt in the summer but with minimum baseline concentrations close to those from Hateruma; in the winter the concentrations were almost constant at about 1.3 ppt. Analysis of the data suggested that (1) emissions from macroalgae were not likely to extend offshore, but instead were localized near the shore, (2) strong macroalgal emissions of CH₂Br₂ were almost limited to the summer, but it was not reflected in the seasonality of the baseline concentrations of CH₂Br₂ in the atmosphere, and therefore (3) macroalgal or coastal emissions of CH₂Br₂ in the temperate zone might have a rather limited contribution to the global CH₂Br₂ sources. These findings are especially important for the understanding of the tropospheric and stratospheric bromine budget.