Fluid–rock interaction in the Qitianling granite and associated tin deposits, South China: Evidence from boron and oxygen isotopes

The behavior of boron and its isotopes in fluid-dominant processes and hydrothermal alteration of granites is examined using fresh and altered granite samples from the Qitianling granite and associated hydrothermal tin deposits in South China. Boron concentrations are highest in the fresh granite (37 ppm) and depleted as a result of two stages of fluid mobility and fluid–rock interaction within the granite. Constraints provided both by δ¹¹B and δ¹⁸O data suggest that the first stage was related to exsolution of aqueous fluids from the granite magma at a temperature of > 450 °C. This was followed by further boron depletion in the granite by hydrothermal circulation of meteoric water at lower temperatures (~ 350 °C) and low water/rock ratios. The sensitivity of coupled boron and oxygen isotope systematics to these processes suggests that they can provide valuable constraints on of fluid mobility in granite and associated mineralization.     

Oceanic Rossby waves induced by the meridional shift of the ITCZ in association with ENSO events

This study investigated the eastern Pacific Intertropical Convergence Zone (ITCZ) as an atmospheric forcing to the ocean by using various observed and reanalysis data sets over 29 years. Climatologically, a zonal band of positive wind stress curl (WSC) with a 10° meridional width was exhibited along the ITCZ. A southward shift of the positive WSC band during the El Niño phase induced a negative (positive) WSC anomaly along the northern (southern) portion of the ITCZ, and vice versa during the La Niña phase. This meridional dipole accounted for more than 25 % of interannual variances of the WSC anomalies (WSCAs), based on analysis of the period 1993–2008. The negative (positive) WSCA in the northern portion of the ITCZ during the El Niño (La Niña) phase was collocated with a positive (negative) sea surface height anomaly (SSHA) that propagated westward as a Rossby wave all the way to the western North Pacific. This finding indicates that this off-equatorial Rossby wave is induced by the WSCA around the ITCZ. Our analysis of a 1.5-layer reduced gravity model revealed that the Rossby waves are mostly explained by wind stress forcing, rather than by reflection of an equatorial Kelvin wave on the eastern coastal boundary. The off-equatorial Rossby wave had the same SSHA polarity as the equatorial Kelvin wave, and generation of a phase-preserving Rossby wave without the Kelvin wave reflection was explained by meridional movement of the ITCZ. Thus, the ITCZ acts as an atmospheric bridge that connects the equatorial and off-equatorial oceanic waves.     

High frequency variability of current in the western channel of the Tsushima/Korea Straits

The temporal characteristics and spatial structures of high frequency variability of the current in the western channel of the Tsushima/Korea Straits (TKS) are studied using ADCP data from 10?years along the cruise line of a regular ferry, “Camilla”, between Busan and Hakata. The eddy kinetic energy analysis shows that the high frequency variability has strong seasonal and spatial dependencies. From December to April, the variability is prominent in the entire western channel of the TKS. From July to October, it is enhanced only in the Korean coastal zone. The EOF analysis for the component of the high frequency currents normal to the ferry route illuminates three types of dominant modes, a transport mode and a vortex mode in the western channel during December–April, and a baroclinic coastal-trapped mode in the Korean coastal zone during July–October. The transport mode with a uniform current direction throughout the channel shows good correlation with the high frequency variability of the volume transport through the western channel with dominant time scales of 3.5 and 7?days. The vortex mode with alternating current directions across the channel explains well the variability of the eddy vorticity in the western channel with dominant time scales of 5–8?days. The baroclinic coastal-trapped mode in the Korean coastal zone has characteristics of both baroclinic Kelvin wave and topographic Rossby wave in the vertical current structure with dominant time scales of 14 and 32?days.     

Determination of Lithium Contents in Silicates by Isotope Dilution ICP-MS and its Evaluation by Isotope Dilution Thermal Ionisation Mass Spectrometry

A precise and simple method for the determination of lithium concentrations in small amounts of silicate sample was developed by applying isotope dilution-inductively coupled plasma-mass spectrometry (ID-ICP-MS). Samples plus a Li spike were digested with HF-HClO₄, dried and diluted with HNO₃, and measured by ICP-MS. No matrix effects were observed for ⁷Li/⁶Li in rock solutions with a dilution factor (DF) of 97 at an ICP power of 1.7 kW. By this method, the determination of 0.5 μg g^-1 Li in a silicate sample of 1 mg can be made with a blank correction of < 1%. Lithium contents of ultrabasic to acidic silicate reference materials (JP-1, JB-2, JB-3, JA-1, JA-2, JA-3, JR-1 and JR-2 from the Geological Survey of Japan, and PCC-1 from the US Geological Survey) and chondrites (three different Allende and one Murchison sample) of 8 to 81 mg were determined. The relative standard deviation (RSD) was typically < 1.7%. Lithium contents of these samples were further determined by isotope dilution-thermal ionisation mass spectrometry (ID-TIMS). The relative differences between ID-ICP-MS and ID-TIMS were typically < 2%, indicating the high accuracy of ID-ICP-MS developed in this study.     

Oxygen-isotopic compositions of relict and host grains in chondrules in the Yamato 81020 CO3.0 chondrite

We report the oxygen-isotope compositions of relict and host olivine grains in six high-FeO porphyritic olivine chondrules in one of the most primitive carbonaceous chondrites, CO3.0 Yamato 81020. Because the relict grains predate the host phenocrysts, microscale in situ analyses of O-isotope compositions can help assess the degree of heterogeneity among chondrule precursors and constrain the nebular processes that caused these isotopic differences. In five of six chondrules studied, the Δ¹⁷O (=δ¹⁷O −0.52 · δ¹⁸O) compositions of host phenocrysts are higher than those in low-FeO relict grains; the one exception is for a chondrule with a moderately high-FeO relict. Both the fayalite compositions as well as the O-isotope data support the view that the low-FeO relict grains formed in a previous generation of low-FeO porphyritic chondrules that were subsequently fragmented. It appears that most low-FeO porphyritic chondrules formed earlier than most high-FeO porphyritic chondrules, although there were probably some low-FeO chondrules that formed during the period when most high-FeO chondrules were forming.     

Electrical conductivity measurement of gneiss under mid- to lower crustal P–T conditions

We conducted electrical conductivity measurements perpendicular and parallel to mineral foliation in dry gneiss at up to 1000 K and a constant pressure of 1 GPa. The analyzed gneisses were obtained from the Higo metamorphic belt, Kyushu, Japan. As the metamorphic conditions of these rocks have been well determined by previous studies, we were able to select samples that were representative of the middle to lower crust. Prior to the conductivity measurements, the samples were maintained at the maximum temperature for a long period, until the electrical conductivity had stabilized. Our experiment results reveal linear and reproducible conductivity data between temperatures of 600 and 1000 K. Conductivity measured perpendicular and parallel to foliation differ by an order of magnitude over the same temperature window. A plausible explanation for this discrepancy in conductivity is the contrasting configuration of minerals in the two sample orientations, as observed by backscattered electron image (BEI) and electron probe microanalysis (EPMA). We evaluated the conductivity and computed activation energy for each of the samples and compared the results with those of previous studies; our results are consistent with the conductivity values reported for other types of rocks. We also compared the experiment results with data derived from electromagnetic (EM) soundings. Electrical conductivity measurements undertaken perpendicular to foliation can account for the subsurface conductivity structure beneath central Kyushu, Japan.     

A simple procedure to approximate slip displacement of freestanding rigid body subjected to earthquake motions

A simple calculation procedure for estimating absolute maximum slip displacement of a freestanding rigid body placed on the ground or floor of linear/nonlinear multi‐storey building during an earthquake is developed. The proposed procedure uses the displacement induced by the horizontal sinusoidal acceleration to approximate the absolute maximum slip displacement, i.e. the basic slip displacement. The amplitude of this horizontal sinusoidal acceleration is identical to either the peak horizontal ground acceleration or peak horizontal floor response acceleration. Its period meets the predominant period of the horizontal acceleration employed. The effects of vertical acceleration are considered to reduce the friction force monotonously. The root mean square value of the vertical acceleration at the peak horizontal acceleration is used. A mathematical solution of the basic slip displacement is presented. Employing over one hundred accelerograms, the absolute maximum slip displacements are computed and compared with the corresponding basic slip displacements. Their discrepancies are modelled by the logarithmic normal distribution regardless of the analytical conditions. The modification factor to the basic slip displacement is quantified based on the probability of the non‐exceedence of a certain threshold. Therefore, the product of the modification factor and the basic slip displacement gives the design slip displacement of the body as the maximum expected value. Since the place of the body and linear/nonlinear state of building make the modification factor slightly vary, ensuring it to suit the problem is essential to secure prediction accuracy. Copyright © 2006 John Wiley & Sons, Ltd.     

花岗岩主要造岩矿物间硼同位素分馏的初步研究

本文报道了南岭地区两个花岗岩(大东山和千里山)的全岩以及主要造岩矿物(黑云母、斜长石和石英)的硼含量和硼同位素组成。结果显示,黑云母含有最高的硼含量,斜长石次之,石英中的硼含量则非常低。花岗岩中的硼可能主要以晶格替换方式赋存在黑云母和斜长石中,而石英中的微量硼则来自其包裹的流体包裹体。同时,黑云母具有最低的硼同位素组成,斜长石次之,而石英则具有最高的硼同位素组成。本次研究首次发现花岗岩中的主要造岩矿物间存在着较大的硼同位素分馏:大东山花岗岩中黑云母与斜长石之间存在着-9.3‰的分馏,黑云母与石英之间存在-9.9‰的分馏;千里山花岗岩中黑云母与斜长石之间存在着-6.6‰的分馏,黑云母与石英之间存在着-10.2‰的硼同位素分馏。结合镜下观察和氧同位素研究发现,造成不同矿物间这一大的硼同位素分馏的原因很可能是岩浆后期的热液蚀变作用。综合以往所发表的研究数据,得到含四次配位硼为主的硅酸盐矿物与中酸性热液流体之间的硼同位素分馏方程:1000lnα硅酸盐-流体=-11.19×(103/T[K])+5.09,该分馏是由于硼的四次配位和三次配位之间的转换引起的。     

A substructure shaking table test for reproduction of earthquake responses of high‐rise buildings

When subjected to long‐period ground motions, high‐rise buildings' upper floors undergo large responses. Furniture and nonstructural components are susceptible to significant damage in such events. This paper proposes a full‐scale substructure shaking table test to reproduce large floor responses of high‐rise buildings. The response at the top floor of a virtual 30‐story building model subjected to a synthesized long‐period ground motion is taken as a target wave for reproduction. Since a shaking table has difficulties in directly reproducing such large responses due to various capacity limitations, a rubber‐and‐mass system is proposed to amplify the table motion. To achieve an accurate reproduction of the floor responses, a control algorithm called the open‐loop inverse dynamics compensation via simulation (IDCS) algorithm is used to generate a special input wave for the shaking table. To implement the IDCS algorithm, the model matching method and the H_∞ method are adopted to construct the controller. A numerical example is presented to illustrate the open‐loop IDCS algorithm and compare the performance of different methods of controller design. A series of full‐scale substructure shaking table tests are conducted in E‐Defense to verify the effectiveness of the proposed method and examine the seismic behavior of furniture. The test results demonstrate that the rubber‐and‐mass system is capable of amplifying the table motion by a factor of about 3.5 for the maximum velocity and displacement, and the substructure shaking table test can reproduce the large floor responses for a few minutes. Copyright © 2009 John Wiley & Sons, Ltd.