Development of density measurement for metals at high pressures and high temperatures using X-ray absorption imaging combined with externally heated diamond anvil cell

A technique for density measurement under high pressure and high temperature was developed using the X-ray absorption imaging method combined with an externally heated diamond anvil cell. The densities of solid and liquid In were measured in the pressure and temperature ranges of 3.2–18.6 GPa and 294–719 K. The densities obtained through the X-ray absorption imaging method were in good agreement (less than 2.0% difference) with those obtained through X-ray diffraction. Based on the measured density, the isothermal bulk modulus of solid In is determined as 48.0 ± 1.1?40.9 ± 0.8 GPa at 500 K, assuming K′ = 4 to 6. The compression curve of liquid In approaches that of solid In at higher pressures and does not cross over the solid compression curve in the measurement range. The present technique enables us to determine the densities of both solids and liquids precisely in a wide pressure and temperature range.     

Can global rainfall estimates (satellite and reanalysis) aid landslide hindcasting?

Predicting rainfall-induced landslides hinges on the quality of the rainfall product. Satellite rainfall estimates or rainfall reanalyses aid in studying landslide occurrences especially in ungauged areas, or in the absence of ground-based rainfall radars. Quality of these rainfall estimates is critical; hence, they are commonly crosschecked with their ground-based counterparts. Beyond their temporal precision compared to ground-based observations, we investigate whether these rainfall estimates are adequate for hindcasting landslides, which particularly requires accurate representation of spatial variability of rainfall. We developed a logistic regression model to hindcast rainfall-induced landslides in two sites in Japan. The model contains only a few topographic and geologic predictors to leave room for different rainfall products to improve the model as additional predictors. By changing the input rainfall product, we compared GPM IMERG and ERA5 rainfall estimates with ground radar–based rainfall data. Our findings emphasize that there is a lot of room for improvement of spatiotemporal prediction of landslides, as shown by a strong performance increase of the models with the benchmark radar data attaining 95% diagnostic performance accuracy. Yet, this improvement is not met by global rainfall products which still face challenges in reliably capturing spatiotemporal patterns of precipitation events.

     

Iron-water reaction at high pressure and temperature, and hydrogen transport into the core

We observed a direct reaction of metallic iron with water to form iron hydride and iron oxide, 3Fe + H₂O–>2FeH_x + FeO, at pressures from 6 GPa to 84 GPa and temperatures above 1,000 K in diamond anvil cell (DAC). Iron hydride is dhcpFeH_x or -FeH_x, and iron oxide has the rhombohedral or B1 structure at pressures at least up to 37 GPa. The formation of an assembly composed of dhcpFeH_x and FeO with the B8 structure was observed at 84 GPa. In primordial Earth, water formed by dehydration of the low temperature primitive materials reacts with metallic iron in the high temperature component to form iron hydride FeH_x and iron oxide FeO. The former would be incorporated in the iron forming the core. Thus hydrogen could be an important element of the Earths core. This reaction would be essential for transport of hydrogen into the core in the accretion stage of the Earth.     

Formation of Distinct Granitic Magma Batches by Partial Melting of Hybrid Lower Crust in the Izu Arc Collision Zone, Central Japan

The Miocene Kofu Granitic Complex (KGC) occurs in the Izu CollisionZone where the Izu–Bonin–Mariana (IBM) arc has beencolliding with the Honshu arc since the middle Miocene. TheKGC includes rocks ranging in compositions from biotite-bearinggranite (the Shosenkyo and Mizugaki plutons), and hornblende–biotite-bearinggranodiorite, tonalite, quartz-diorite, and granite (the Shiodaira,Sanpo, Hirose and Sasago plutons), to hornblende-bearing tonaliteand trondhjemite (the Ashigawa–Tonogi pluton), indicatingthat it was constructed from multiple intrusions of magma withdifferent bulk chemistry. The Sr-isotopic compositions correctedto sensitive high-resolution ion microprobe (SHRIMP) zirconages (SrI) suggest that the primary magmas of each pluton wereformed by anatexis of mixed lower crustal sources involvingboth juvenile basalt of the IBM arc and Shimanto sedimentaryrocks of the Honshu arc. After the primary magmas had formed,the individual plutons evolved by crystal fractionation processeswithout significant crustal assimilation or additional mantlecontribution. SHRIMP zircon U–Pb ages in the KGC rangefrom 16·8 to 10·6 Ma and overlap the resumptionof magmatic activity in the IBM and Honshu arcs at c. 17 Maand the onset of IBM arc–Honshu arc collision at c. 15Ma. The age of the granite plutons is closely related to theepisodic activity of arc magmatism and distinct granitic magmabatches could be formed by lower crustal anatexis induced byintrusion of underplated mantle-derived arc magmas. Based onpressures determined with the Al-in-hornblende geobarometer,the KGC magmas intruded into the middle crust. Thus, the KGCcould represent an example of the middle-crust layer indicatedthroughout the IBM arc by 6·0–6·5 km/s seismicvelocities. This granitic middle-crust layer acted buoyantlyduring the IBM arc–Honshu arc collision, leading to accretionof buoyant IBM arc middle crust to the Honshu arc. KEY WORDS: arc–arc collision; crustal anatexis; granite; Izu–Bonin–Mariana (IBM) arc; Izu Collision Zone     

Sequence-stratigraphic signatures of hemipelagic siltstones in deep-water successions: the Lower Pleistocene Kiwada and Otadai Formations, Boso Peninsula, Japan

Sequence-stratigraphic signatures of hemipelagic siltstones were investigated using profiles of the magnetic susceptibility and selected chemical composition of the Early Pleistocene deep-water successions of the Kiwada and Otadai Formations on the Boso Peninsula, Japan. In the context of an independently developed sequence-stratigraphic framework for the submarine-fan deposits of the Otadai Formation, the magnetic susceptibility and chemical composition, such as the concentrations of TiO₂, MgO and Fe₂O₃, show that the lowstand systems tract deposits have higher values of these parameters than the transgressive and highstand systems tract deposits. In contrast, the CaO contents have inverse relationships with the magnetic susceptibility and are higher in the transgressive and highstand systems tract deposits. The positions of sequence boundaries largely coincide with the horizons from which the magnetic susceptibility and the contents of mafic component increase abruptly. The sequence-stratigraphic variations in the magnetic susceptibility and chemical composition of the submarine-fan hemipelagic siltstones are due to increases in the input of fine-grained, terrigenous clastic sediments from midwater flow suspension, in addition to the direct fluvial supply of relatively unmodified terrigenous clastic sediments during relative sea-level lowstands, although grain size of hemipelagic siltstones does not exhibit any distinct variation through depositional sequences. The Kiwada Formation is characterized by siltstone-dominated basin-plain deposits and its sequence-stratigraphic classification has been difficult when using just lithofacies features. Nevertheless, the profiles of the magnetic susceptibility and chemical composition of the basin-plain deposits are similar to those of the submarine-fan deposits with duration largely equivalent to the 41,000-years obliquity cycle of the Early Pleistocene oxygen isotope sea-level index. This finding indicates that the profiles of the magnetic susceptibility and chemical composition of hemipelagic siltstones reflect sequence-stratigraphic variation in the input of fine-grained terrigenous clastic sediments to the deep-water environments and are crucial for the recognition of cryptic sequence boundaries in hemipelagic successions.     

Early Carboniferous HP metamorphism in the Hida Gaien Belt,Japan: Implications for the Palaeozoic tectonic history of proto‐Japan

We report two new eclogite localities (at Kanayamadani and Shinadani) in the high‐P (HP) metamorphic rocks of the Omi area in the western most region of Niigata Prefecture, Japan, which form part of the Hida Gaien Belt, and determine metamorphic conditions and pressure–temperature (P–T) paths. The metamorphic evolution of the eclogites is characterized by a tight hairpin‐shaped P–T path from prograde epidote–blueschist facies to peak eclogite facies and then retrograde blueschist facies. The prograde metamorphic stage is characterized by various amphibole (winchite, barroisite, glaucophane) inclusions in garnet, whereas the peak eclogite facies assemblage is characterized by omphacite, garnet, phengite and rutile. Peak P–T conditions of the eclogites were estimated to be ~600°C and up to 2.0 GPa by conventional cation‐exchange thermobarometry, Ti‐in‐zircon thermometry and quartz inclusion Raman barometry respectively. However, the Raman spectra of carbonaceous material thermometry of metapelites associated with the eclogites gave lower peak temperatures, possibly due to metamorphism at different conditions before being brought together during exhumation. The blueschist facies overprint following the peak of metamorphism is recognized by the abundance of glaucophane in the matrix. Zircon grains in blueschist facies metasedimentary samples from two localities adjacent to the eclogites have distinct oscillatory‐zoned cores and overgrowth rims. Laser ablation inductively coupled plasma mass spectrometry U–Pb ages of the detrital cores yield a wide range between 3,200 and 400 Ma, with a peak at 600–400 Ma. In the early Palaeozoic, proto‐Japan was located along the continental margin of the South China craton, providing the source of the older population of detrital zircon grains (3,200–600 Ma) deposited in the trench‐fill sediments. In addition, subduction‐related magmatism c. 500–400 Ma is recorded in the crust below proto‐Japan, which might have been the source for the younger detrital zircon grains. The peak metamorphic age was constrained by SHRIMP dating of the overgrowth rims, yielding Tournaisian ages of 347 ± 4 Ma, suggesting subduction in the early Carboniferous. Our results provide clear constraints on the initiation of subduction, accretion and the development of an arc‐trench system along the active continental margin of the South China craton and help to unravel the Palaeozoic tectonic history of proto‐Japan.     

Palynological evidence for late Holocene environmental change on the Gimhae fluvial plain,Southern Korean peninsula: Reconstructing the rise and fall of Golden Crown Gaya State

This paper presents the results of detailed studies of palynomorphs recovered from two cores collected near the Yeanri burial mound on the Gimhae fluvial plain. Two local pollen zones were recognized on the basis of variations in the palynofloral assemblage: a lower Pollen Zone I, dominated by a Pinus‐Quercus assemblage, and an upper Pollen Zone II, dominated by a Pinus‐Quercus‐Gramineae assemblage. The palynological and molluscan analyses indicate that the depositional environments changed from a lower intertidal flat of a shallow bay environment to an upper intertidal flat in a shallow bay (before 1280 ± 110 ¹⁴C yr B.P.), and finally to a fluvial plain similar to that of today. This environmental change may have resulted from uplift along the Yangsan Fault. Afterward, the exposed area was modified by human activities, as indicated by a sudden increase in grassland herbaceous pollen grains. The loss of this bay likely had a dramatic effect on the Golden Crown Gaya State (3rd–7th centuries A.D.), which used it as a major port for regional trade, and may explain why it eventually merged with the Shilla State. © 2003 Wiley Periodicals, Inc.