Measuring hydraulic permeability in a streambed using the packer test

Permeability of a streambed is an important factor regulating nutrient and oxygen availability for aquatic biota. In order to investigate the relationship, an accurate permeability should be measured. However, it is difficult to measure permeability in a coarse gravel bed using a conventional permeability test. Moreover, turbulent flow may occur in coarse bed material, and then deviations from Darcy's law do occur. Thus, permeability calculated following Darcy's law may be overestimated under turbulent flow conditions and should be corrected. The packer test can be used in highly permeable gravel beds. We developed a field method applicable to a gravel bed using the packer test and derived an equation adopting a law of turbulent flow to study the problems under any type of flow condition. The accuracy of the equation was examined using a laboratory flume with a gravel bed. The results suggested that permeability calculated from Hvorslev's equation is overestimated for turbulent flow. In contrast, our equation, developed here, could evaluate permeability accurately under any type of flow condition. Copyright © 2005 John Wiley & Sons, Ltd.     

Determination of regional land surface heat fluxes over a heterogeneous landscape of the Jiddah area of Saudi Arabia by using Landsat‐7 ETM data

In this study, a parameterization method based on Landsat‐7 Enhanced Thematic Mapper (ETM) data and field observations is presented and tested for deriving the regional land surface variables, vegetation variables and land surface heat fluxes over a heterogeneous landscape. As a case study, the method and two Landsat‐7 ETM images are applied to the Jiddah area of Saudi Arabia. The regional distribution maps of surface reflectance, normalized difference vegetation index, modified soil adjusted vegetation index (MSAVI), vegetation coverage, leaf area index, surface temperature, net radiation flux, soil heat flux, sensible heat flux and latent heat flux have been determined over the Jiddah area. The derived results have been validated by using the ‘ground truth’. The results show that the more reasonable regional distributions of land surface variables (surface reflectance, surface temperature), vegetation variables (MSAVI and vegetation coverage), net radiation, soil heat flux and sensible heat flux can be obtained by using the method proposed in this study. Further improvement of the method is also discussed. Copyright © 2006 John Wiley & Sons, Ltd.     

Using sulfur isotopes to determine the sources of vermillion in ancient burial mounds in Japan

This study represents an attempt to determine the sources of vermillion found in ancient Japanese burial mounds of the 1st–6th centuries A.D., by comparing their ratios of sulfur isotopes with those of cinnabar ore samples collected in Japan and China. Cinnabar ore samples were taken from three mines in central Japan (Niu in Mie, Yamato in Nara, and Sui in Tokushima prefectures), and from Wanshan in China, where mining activity has been recorded back to the 6th century A.D. and earlier. When the ratios of a ³⁴S and ³²S were compared with the Canyon Diablo meteorite standard, a high δ³⁴S value of +22.6 ± 3.6‰ was found for the Wanshan mine, as opposed to low values ranging from −7.3 ± 1.9 to −2.1 ± 1.6‰ for the Japanese mines. The ratios of sulfur isotopes in vermillion collected from ancient Japanese burial mounds also divided into two groups. High ratios (+11.1 to +22.8‰) were found in 1st‐ and 2nd‐ century burials in the western regions of northern Kyushu and San'in, suggesting that local, powerful chiefs obtained vermillion through relations with China. Lower ratios (−8.4 to −2.0‰) were found in burials of the 2nd through 6th centuries in central Japan, where the ancient Yamato dynasty emerged as the first unified polity around the end of the 2nd century A.D. We, therefore, conclude that the Yamato dynasty exploited local sources of vermillion, rather than depending solely on China. The present study demonstrates the feasibility of determining sources of vermillion using sulfur isotope ratios, and the relevance of such findings for archaeological research. © 2005 Wiley Periodicals, Inc.     

Earthquake sequences on a frictional fault model with non-uniform strengths and relaxation times

Summary. The space and time characteristics of earthquake sequences, including a main shock, aftershocks and the recurrence of major shocks in a long time range, are investigated on a frictional fault model with non-uniform strengths and relaxation times, which is subjected to a time-dependent shear stress. Aftershocks with low stress drop take place successively in spaced regions so as to fill the gaps which have not yet been ruptured since the main shock, while those with high stress drop occur in and around the regions left unruptured during the main faulting. The frequency decay of aftershocks with time follows a hyperbolic law with the rates p consistent with observations. There are good linear relations in logarithmic scales for source area versus frequency and seismic moment versus frequency of the generated aftershocks. The b -value obtained in the present experiments appears slightly larger than that for observations. It was found that more heterogeneous distribution of the fault strength give smaller p and larger b -values. The recurrence of major shocks, particularly of very large shocks with high stress drop, is often preceded by a completely silent period of activity or very low activity with a small number of foreshocks. The major shocks take place successively in adjacent unruptured regions and sometimes show slow-speed migrations. These results provide explanations to various observations of earthquake sequences.     

Accurate Isotopic and Concentration Analyses of Small Amounts of Pb Using Isotope Dilution Coupled with the Double Spike Technique

A new method has been developed for the simultaneous determination of Pb abundance and Pb isotopic composition with high precision and accuracy for small test portion masses by thermal ionisation mass spectrometry. In this method, a ²⁰⁵pb-²⁰⁴pb double spike is added to samples prior to the chemical separation of Pb, and the isotopic composition of the spike-sample mixture is determined rigorously by the double spike technique using a ²⁰⁷Pb-²⁰⁴Pb spike. The isotopic composition and concentration of Pb in the sample are then obtained by utilising the principle of isotope dilution. Using this technique, replicate determinations of Pb from NIST SRM 981 and GSJ JP-1 (peridotite; 0.07 μg g⁻¹ Pb) were performed. The measured concentration and isotopic data were identical, within uncertainty, to published data or to data that were determined independently in this study. The application of this method to U-Pb dating and the determination of the "initial" Pb isotopic composition was also tested. Lead isotopic compositions and the concentrations of Pb, Th and U were determined for a single batch of samples, through the addition of ²⁰⁵pb-²⁰⁴pb, ²³⁰Th and ²³⁵U spikes to samples prior to chemical separation. Also in these experiments, we confirmed that this routine gives accurate data for Pb, Th and U concentrations and Pb isotopic compositions.     

Mechanism and future risk of slope instability induced by extreme rainfall event in Izu Oshima Island,Japan

Natural Hazards - A volcanic slope in Izu Oshima Island in Japan experienced a profound rain-induced disaster in October 2013. Since this slope had been stable for centuries except for minor...     

River Water Pollution in Developed and Developing Countries: Judge and Assessment of Physicochemical Characteristics and Selected Dissolved Metal Concentration

To compare water quality in rivers of developed and developing countries, a study based on physicochemical parameters and dissolved metals levels was conducted. Water samples were collected from selected sites in Dhaka, Bangladesh; Hokkaido and Osaka, Japan; Erdenet, Mongolia and West Java, Indonesia. Analysis of least significant differences revealed that most water quality parameters were within comparable low levels in both developed and developing countries. The dissolved metals concentrations were found to be similar and below those of water standards except for manganese and cadmium at every sampling point, and lead in Erdenet, Mongolia. Some metals showed high enrichment factors in the rivers of Osaka, Japan and Erdenet, Mongolia, indicating accumulation possibility of metals in the river‐bed sediments. High concentrations of dissolved organic carbon, Escherichia coli and dissolved metals suggested greater water pollution in some rivers of developing countries than in the rivers of Japan. Principal component analysis showed strong correlations between “dissolved organic carbon and chemical oxygen demand” and “conductivity and total dissolved solids” at each sampling point, and E. coli, nitrate (NO), nitrite (NO), and pH levels were found to be higher in the rivers of Dhaka and Erdenet. In addition, there were high levels of Al and Zn in West Java, Pb in Erdenet, and Mn, Fe, and Cr in the rivers of Dhaka and Japan. Based on pressures and impacts, it is evident that dissolved metal, organic, and fecal pollution in the rivers of developing countries are in somewhat dreadful condition in comparison with the rivers of developed country.     

Interplate Coupling in the Kanto District, Central Japan, and the Boso Peninsula Silent Earthquake in May 1996

— I studied crustal deformation in the Kanto district, central Japan, based on continuous GPS data. Horizontal as well as vertical displacement rate demonstrate significant interaction between the landward Kanto block and the Philippine Sea plate. Although the subduction effect of the Pacific plate is not apparent, it is reasonable to consider the entire Kanto district is displaced westward due to the interaction with the Pacific plate. The GPS velocity data were inverted to estimate the slip deficit distribution on the Sagami Trough subduction zone. The result delineates a strongly coupled region on the plate interface, part of which corresponds to the 1923 Kanto earthquake. The strongly coupled region is located shallower than 20 km. In addition, the plate interaction is laterally heterogeneous even in the same depth range, implying thermal structure is not the only factor controlling interplate coupling. The GPS data also detected a silent earthquake event on the interface of the Philippine Sea slab east of the Boso Peninsula in the middle of May, 1996. The silent rupture propagated over a 50 km * 50 km wide area during about a week. The maximum slip was approximately 50 mm and the released seismic moment was 4.7*10¹⁸Nm (M _w 6.4). There was a small seismicity triggered by this silent event. The silent slip was located in the peripheral of the strongly coupled area, suggesting that frictional properties and/or stress conditions are inhomogeneous on the plate boundary interface.     

Simultaneous Analysis of Natural Free Estrogens and Their Conjugates in Wastewater by GC‐MS

A solid‐phase extraction (SPE)‐gas chromatography (GC)‐mass spectrometry (MS) analytical method was developed for the simultaneous analysis of natural free estrogens and their conjugates in wastewater samples. Natural free estrogens and their conjugates in wastewater were successfully separated by the oasis hydrophilic‐lipophilic balance solid phase extraction (Oasis HLB SPE) method, and the conjugates were initially enzyme hydrolyzed by β‐glucuronidase or arylsulfatase from Helix pomatia prior to derivatization. N‐methyl‐N‐(tert‐butyldimethylsilyl)trifluoroacetamide (MTBSTFA) plus 1% tert‐butyldimetheylchlorosilane (TBDMCS) was chosen as the derivatization reagent, and the most appropriate conditions of derivatization were determined to be at 95°C for 90 min. The recovery ratios of nine target chemicals were determined by spiking them in 1 L of ultra‐purified water or the influent of a wastewater treatment plant (WWTP). The recovery ratios of six out of nine for the analytes ranged from 73.3–114.9% with relative standard deviations (RSD) from 1.6–19.9%. The established method was successfully applied to environmental wastewater samples which were collected from one municipal wastewater treatment plant (WWTP) in Osaka, Japan, for the determination of natural free estrogens and their conjugates. In the influent sample, E1, E2, E1‐3S, E3‐3S, and E1‐3G were detected at concentrations of 16.6, 9.6, 8.2, 21.9, and 3.2 ng L^–1, respectively. However, only E1 was detected at a high concentration of 44 ng L^–1 in the effluent sample, suggesting that it is the dominant natural free estrogen in the effluent.