Estimates of the turbulent kinetic energy budget in the oceanic convective boundary layer

The terms of the steady-state turbulent kinetic energy (TKE) budget in the oceanic convective boundary layer (CBL) are estimated by use of microstructure data obtained over the continental shelf of the East China Sea. The dissipation term is calculated from the micro-scale vertical shear of horizontal velocity measured directly using a freely-falling microstructure profiler, whereas the buoyancy flux and shear production terms are estimated indirectly by integrating vertically the one-dimensional conservation equation of density and by applying similarity theory, respectively. The transport term, calculated as the residual of the other three terms, vertically redistributes the TKE from the upper half of the CBL to the lower half, consistent with the TKE budgets in the atmospheric CBL and in shear-free and slightly-sheared CBLs simulated by large eddy-simulation models. The relatively large contribution of the transport term to the TKE budget shows that a local equilibrium form of the TKE equation is not appropriate for the TKE budget in the oceanic CBL.     

Equatorial Atlantic variability and its relation to mean state biases in CMIP5

Coupled general circulation model (GCM) simulations participating in the Coupled Model Intercomparison Project Phase 5 (CMIP5) are analyzed with respect to their performance in the equatorial Atlantic. In terms of the mean state, 29 out of 33 models examined continue to suffer from serious biases including an annual mean zonal equatorial SST gradient whose sign is opposite to observations. Westerly surface wind biases in boreal spring play an important role in the reversed SST gradient by deepening the thermocline in the eastern equatorial Atlantic and thus reducing upwelling efficiency and SST cooling in the following months. Both magnitude and seasonal evolution of the biases are very similar to what was found previously for CMIP3 models, indicating that improvements have only been modest. The weaker than observed equatorial easterlies are also simulated by atmospheric GCMs forced with observed SST. They are related to both continental convection and the latitudinal position of the intertropical convergence zone (ITCZ). Particularly the latter has a strong influence on equatorial zonal winds in both the seasonal cycle and interannual variability. The dependence of equatorial easterlies on ITCZ latitude shows a marked asymmetry. From the equator to 15°N, the equatorial easterlies intensify approximately linearly with ITCZ latitude. When the ITCZ is south of the equator, on the other hand, the equatorial easterlies are uniformly weak. Despite serious mean state biases, several models are able to capture some aspects of the equatorial mode of interannual SST variability, including amplitude, pattern, phase locking to boreal summer, and duration of events. The latitudinal position of the boreal spring ITCZ, through its influence on equatorial surface winds, appears to play an important role in initiating warm events.     

Seasonally asymmetric transition of the Asian monsoon in response to ice age boundary conditions

Modulation of a monsoon under glacial forcing is examined using an atmosphere?Cocean coupled general circulation model (AOGCM) following the specifications established by Paleoclimate Modelling Intercomparison Project phase 2 (PMIP2) to understand the air?Csea?Cland interaction under different climate forcing. Several sensitivity experiments are performed in response to individual changes in the continental ice sheet, orbital parameters, and sea surface temperature (SST) in the Last Glacial Maximum (LGM: 21?ka) to evaluate the driving mechanisms for the anomalous seasonal evolution of the monsoon. Comparison of the model results in the LGM with the pre-industrial (PI) simulation shows that the Arabian Sea and Bay of Bengal are characterized by enhancement of pre-monsoon convection despite a drop in the SST encompassing the globe, while the rainfall is considerably suppressed in the subsequent monsoon period. In the LGM winter relative to the PI, anomalies in the meridional temperature gradient (MTG) between the Asian continents minus the tropical oceans become positive and are consistent with the intensified pre-monsoon circulation. The enhanced MTG anomalies can be explained by a decrease in the condensation heating relevant to the suppressed tropical convection as well as positive insolation anomalies in the higher latitude, showing an opposing view to a warmer future climate. It is also evident that a latitudinal gradient in the SST across the equator plays an important role in the enhancement of pre-monsoon rainfall. As for the summer, the sensitivity experiments imply that two ice sheets over the northern hemisphere cools the air temperature over the Asian continent, which is consistent with the reduction of MTG involved in the attenuated monsoon. The surplus pre-monsoon convection causes a decrease in the SST through increased heat loss from the ocean surface; in other words, negative ocean feedback is also responsible for the subsequent weakening of summer convection.     

Seismicity and magma supply rate of the 1998 failed eruption at Iwate volcano,Japan

Iwate volcano, Japan, showed significant volcanic activity including earthquake swarms and volcano inflation from the beginning of 1998. A large earthquake of magnitude 6.1 hit the south-west of the volcano on September 3. Although a 1 km² fumarole field formed, blighting plants on the ridge in the western part of the volcano in the spring of 1999, no magmatic eruptions occurred. We reconcile the spatio-temporal distributions of volcanic pressure sources determined by previously reported studies in which GPS, strain and tilt data from dense geodetic station networks are analyzed (Miura et al. Earth Planet Space 52:1003–1008, 2000; Sato and Hamaguchi J Volcanol Geotherm Res 155:244–262, 2006). We calculate the magma supply rates from their results and compare them with the occurrence rates of volcanic earthquakes. The results show that the magma supply rates are almost constant or even decrease with time while the earthquake occurrence rate increases with time. This contrast in their temporal changes is interpreted to result from stress accumulation in the volcanic edifice caused by constant magma supply without effusion of magma to the surface. We further show that data showing slight acceleration in strain can be best explained by magma ascent at a constant velocity, and that there is no evidence for increased magma buoyancy resulting from gas bubble growth. This consideration supports the interpretation that the magma stayed at 2 km depth and horizontally migrated. These findings relating magma supply rate and seismicity to magma ascent process are clues to understanding why no magmatic eruption occurred at Iwate volcano in 1998.     

Coseismic changes in the chemical composition of volcanic gases from the Owakudani geothermal area on Hakone volcano,Japan

The chemical and isotopic compositions of volcanic gases at a borehole and a natural fumarole in the Owakudani geothermal area, Hakone volcano, Japan, have been repeatedly measured since 2001, when a seismic swarm occurred in the area. The CO₂/H₂O and CO₂/H₂S ratios were high in 2001. It increased in 2006 and again in 2008 when seismic swarms occurred beneath the geothermal area. The observed increases suggest the injection of CO₂- and SO₂-rich magmatic gas into the underlying hydrothermal reservoir, implying that the magmatic gas was episodically supplied to the hydrothermal system in 2006 and 2008. The earthquake swarms probably resulted from the injection of gas through the shallow crust accompanying the break of the sealing zone.     

Geochemical evolution of historical lavas from Askja Volcano, Iceland: Implications for mechanisms and timescales of magmatic differentiation

The mechanisms and the timescales of magmatic evolution were investigated for historical lavas from the Askja central volcano in the Dyngjufjöll volcanic massif, Iceland, using major and trace element and Sr, Nd, and Pb isotopic data, as well as ²³⁸U-²³⁰Th-²²⁶Ra systematics. Lavas from the volcano show marked compositional variation from magnesian basalt through ferrobasalt to rhyolite. In the magnesian basalt-ferrobasalt suite (5-10 wt% MgO), consisting of lavas older than 1875 A.D., ⁸⁷Sr/⁸⁶Sr increases systematically with increasing SiO₂ content; this suite is suggested to have evolved in a magma chamber located at ∼600 MPa through assimilation and fractional crystallization. On the other hand, in the ferrobasalt-rhyolite suite (1-5 wt% MgO), including 1875 A.D. basalt and rhyolite and 20th century lavas, ⁸⁷Sr/⁸⁶Sr tends to decrease slightly with increasing SiO₂ content. It is suggested that a relatively large magma chamber occupied by ferrobasalt magma was present at ∼100 MPa beneath the Öskjuvatn caldera, and that icelandite and rhyolite magmas were produced by extraction of the less and more evolved interstitial melt, respectively, from the mushy boundary layer along the margin of the ferrobasalt magma chamber, followed by accumulation of the melt to form separate magma bodies. Ferrobasalt and icelandite lavas in the ferrobasalt-rhyolite suite have a significant radioactive disequilibrium in terms of (²²⁶Ra/²³⁰Th), and its systematic decrease with magmatic evolution is considered to reflect aging, along with assimilation and fractional crystallization processes. Using a mass-balance model in which simultaneous fractional crystallization, crustal assimilation, and radioactive decay are taken into account, the timescale for the generation of icelandite magma from ferrobasalt was constrained to be <∼3 kyr which is largely dependent on Ra crystal-melt partition coefficients we used.     

Rain-on-Snow events in Japan as projected by a large ensemble of regional climate simulations

Climate Dynamics - Rain-on-Snow (ROS) events can cause severe snowmelt hazards such as river flooding, avalanches, and landslides that have significant impacts on various sectors. The influence of...     

Hydrogen isotopic substitution of solid methylamine through atomic surface reactions at low temperatures: A potential contribution to the D/H ratio of methylamine in molecular clouds

We experimentally studied hydrogen (H)–deuterium (D) substitution reactions of solid methylamine (CH₃NH₂) under astrophysically relevant conditions. We also calculated the potential energy surface for the H–D substitution reactions of methylamine isotopologues using quantum chemical methods. Despite the relatively large energy barrier of more than 18 kJ mol^?1, CH₃NH₂ reacted with D atoms to yield deuterated methylamines at 10 K, suggesting that the H–D substitution reaction proceeds through quantum tunneling. Deuterated methylamines reacted with H atoms as well. On the basis of present results, we propose that methylamine has potential for D enrichment through atomic surface reactions on interstellar grains at very low temperatures in molecular clouds. D enrichment would occur in particular in the methyl group of methylamine.     

Rates of Thermal and Chemical Evolution of Magmas in a Cooling Magma Chamber: a Chronological and Theoretical Study on Basaltic and Andesitic Lavas from Rishiri Volcano, Japan

Rates of magmatic processes in a cooling magma chamber wereinvestigated for alkali basalt and trachytic andesite lavaserupted sequentially from Rishiri Volcano, northern Japan, bydating of these lavas using ²³⁸U–²³⁰Th radioactive disequilibriumand ¹⁴C dating methods, in combination with theoretical analyses.We obtained the eruption age of the basaltic lavas to be 29·3± 0·6 ka by ¹⁴C dating of charcoals. The eruptionage of the andesitic lavas was estimated to be 20·2 ±3·1 ka, utilizing a whole-rock isochron formed by U–Thfractionation as a result of degassing after lava emplacement.Because these two lavas represent a series of magmas producedby assimilation and fractional crystallization in the same magmachamber, the difference of the ages (i.e. 9 kyr) is a timescaleof magmatic evolution. The thermal and chemical evolution ofthe Rishiri magma chamber was modeled using mass and energybalance constraints, as well as quantitative information obtainedfrom petrological and geochemical observations on the lavas.Using the timescale of 9 kyr, the thickness of the magma chamberis estimated to have been about 1·7 km. The model calculationsshow that, in the early stage of the evolution, the magma cooledat a relatively high rate (>0·1°C/year), and thecooling rate decreased with time. Convective heat flux fromthe main magma body exceeded 2 W/m² when the magma was basaltic,and the intensity diminished exponentially with magmatic evolution.Volume flux of crustal materials to the magma chamber and rateof convective melt exchange (compositional convection) betweenthe main magma and mush melt also decreased with time, from 0·1 m/year to 10^–3 m/year, and from 1 m/yearto 10^–2 m/year, respectively, as the magmas evolved frombasaltic to andesitic compositions. Although the mechanism ofthe cooling (i.e. thermal convection and/or compositional convection)of the main magma could not be constrained uniquely by the model,it is suggested that compositional convection was not effectivein cooling the main magma, and the magma chamber is consideredto have been cooled by thermal convection, in addition to heatconduction. KEY WORDS: convection; magma chamber; heat and mass transport; timescale; U-series disequilibria     

The 2010 European Venus Explorer (EVE) mission proposal

The European Venus Explorer (EVE) mission described in this paper was proposed in December 2010 to ESA as an ‘M-class’ mission under the Cosmic Vision programme. It consists of a single balloon platform floating in the middle of the main convective cloud layer of Venus at an altitude of 55?km, where temperatures and pressures are benign (～25°C and ～0.5 bar). The balloon float lifetime would be at least 10 Earth days, long enough to guarantee at least one full circumnavigation of the planet. This offers an ideal platform for the two main science goals of the mission: study of the current climate through detailed characterization of cloud-level atmosphere, and investigation of the formation and evolution of Venus, through careful measurement of noble gas isotopic abundances. These investigations would provide key data for comparative planetology of terrestrial planets in our solar system and beyond.