Impact-induced phyllosilicate formation from olivine and water

Shock-recovery experiments on mixtures of olivine and water with gas (air) were performed in a previous study to demonstrate water-mineral interactions during impact events (Furukawa et al., 2007). The products of these former experiments were investigated in the present study using transmission electron microscopy, scanning electron microscopy, and X-ray powder diffraction with the aim of finding evidence of aqueous alteration. Serpentine formed on the surface of shocked olivine with well-developed mosaicism. The yield of serpentine depended on the water/olivine ratio in the starting material, indicating progressive serpentinization under water-rich conditions. Comminution and mosaicism were developed in shocked olivine grains. The temperature and pressure changes of the samples during the experiments were estimated by constructing Hugoniots for mixtures of olivine and water, combined with the results of an additional fracturing experiment on a shocked container. Pressures and temperatures reached 4.6-7.2 GPa and at least 230-390 °C, respectively, for 0.7 μs during in-shock compression. Post-shock temperatures reached a maximum of ∼1300 °C, when the shock wave reached the gas in the sample cavity. The serpentine formed after the post-shock temperature maximum, most likely when temperatures dropped to between 200 and 400 °C. This is the first experiment to demonstrate the formation of phyllosilicates using heat supplied by an impact. The present results and estimations suggest that phyllosilicates could form as a result of impacts into oceans as well as by impacts on terrestrial and Martian crustal rocks, and on some asteroidal surfaces, where liquid or solid H₂O is available. A significant amount of phyllosilicates would have formed during the late heavy bombardment of meteorites on the Hadean Earth, and such phyllosilicates might have affected the prebiotic carbon cycle.     

Measuring the k–S–p relations on DNAPLs migration

Migration characteristics of dense non-aqueous phase liquids (DNAPLs) in the subsurface can be expressed as a water–DNAPL two-phase system based on mainly the k–S–p relations, which describe the relations among relative permeability (k), degree of water saturation (S), and capillary pressure head (p). The aims of this research are to develop an experimental system with new type of probes, such as the electrical conductivity probe for measuring the degree of water saturation and the hydrophilic and hydrophobic tensiometer for measuring the pore water and DNAPL pressures, and also to estimate the results obtained from the developed experimental system. From these tests, the excellent k–S–p relations were obtained and the efficiency and validity of this developed experimental system have been confirmed in terms of the concept of the scaling coefficient calculated by interfacial tensions.     

Pull-down basin in the central part of Japan due to subduction-induced mantle flow

The driving force for the basin subsiding against isostatic balance in and around Lake Biwa in the Kinki district, Japan is discussed. The lake region is characterized by strong negative Bouguer anomalies, especially by a steep horizontal gradient zone of gravity anomaly running along the western margin of the lake. The large negative anomaly (>50 mgal) cannot be explained by low-density sediments beneath it. A down-warping structure extending to the Moho depth should be taken into account. This conjecture has been strongly supported by a short-period receiver function imaging, which shows a clear offset of about 8 km for the Moho discontinuity under the steep gravity gradient zone.A question arises as to what is the driving force to create such a large down-warping structure. We consider that the subduction of the shallow-dipping slab under the region (Philippine Sea Slab) may cause crustal deformation by dragging the viscous mantle downward. In order to verify this model, we simulated the induced mantle flow due to the subduction of the Philippine Sea Slab and the pressure distribution on the crust–mantle boundary. This numerical experiment showed that the induced flow makes a strong negative pressure zone under the lake region if the slab has a vertical offset along the direction of subduction. This offset of the slab is consistent with plate models deduced from hypocentral distributions and Sp phases of the deep-focus earthquakes.     

Primary melt from Sannome-gata volcano,NE Japan arc: constraints on generation conditions of rear-arc magmas

The conditions under which rear-arc magmas are generated were estimated using primary basalts from the Sannome-gata volcano, located in the rear of the NE Japan arc. Scoriae from the volcano occur with abundant crustal and mantle xenoliths, suggesting that the magma ascended rapidly from the upper mantle. The scoriae show significant variations in their whole-rock compositions (7.9–11.1 wt% MgO). High-MgO scoriae (MgO > ~9.5 wt%) have mostly homogeneous ⁸⁷Sr/⁸⁶Sr ratios (0.70318–0.70320), whereas low-MgO scoriae (MgO < ~9 wt%) have higher ⁸⁷Sr/⁸⁶Sr ratios (>0.70327); ratios tend to increase with decreasing MgO content. The high-MgO scoriae are aphyric, containing ~5 vol% olivine microphenocrysts with Mg# [100 × Mg/(Mg + Fe²⁺)] of up to 90. In contrast, the low-MgO scoriae have crustal xenocrysts of plagioclase, alkali feldspar, and quartz, and the mineralogic modes correlate negatively with whole-rock MgO content. On the basis of these observations, it is inferred that the high-MgO scoriae represent primary or near-primary melts, while the low-MgO scoriae underwent considerable interaction with the crust. Using thermodynamic analysis of the observed petrological features of the high-MgO scoriae, the eruption temperature of the magmas was constrained to 1,160–1,220 °C. Given that the source mantle was depleted MORB-source mantle, the primary magma was plausibly generated by ~7 % melting of a garnet-bearing spinel peridotite; taking this into consideration, and considering the constraints of multi-component thermodynamics, we estimated that the primary Sannome-gata magma was generated in the source mantle with 0.5–0.6 wt% H₂O at 1,220–1,230 °C and at ~1.8 GPa, and that the H₂O content of the primary magma was 6–7 wt%. The rear-arc Sannome-gata magma was generated by a lower degree of melting of the mantle at greater depths and lower temperatures than the frontal-arc magma from the Iwate volcano, which was also estimated to be generated by ~15 % melting of the source mantle with 0.6–0.7 wt% H₂O at ~1,250 °C and at ~1.3 GPa.     

High-Nb hawaiite–mugearite and high-Mg calc-alkaline lavas from northeastern Iran: Oligo-Miocene melts from modified mantle wedge

Tertiary volcanic rocks in northwestern Firoozeh, Iran (the Meshkan triangular structural unit), constitute vast outcrops (up to 250 km²) of high-Mg basaltic andesites to dacites that are associated with high-Nb hawaiites and mugearites. Whole-rock ⁴⁰Ar/³⁹Ar ages show a restricted range of 24.1 ± 0.4–22.9 ± 0.5 Ma for the volcanic rocks. The initial ratios of ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd vary from 0.703800 to 0.704256 and 0.512681 to 0.512877, respectively, in the high-Mg basaltic andesites–dacites. High-Th contents (up to 11 ppm) and Sr/Y values (27–100) and the isotopic composition of the subalkaline high-Mg basaltic andesites–dacites indicate derivation from a mantle modified by slab and sediment partial melts. Evidence such as reverse zoning and resorbed textures and high Ni and Cr contents in the evolved samples indicate that magma mixing with mafic melts and concurrent fractional crystallization lead to the compositional evolution of this series. The high-Nb hawaiites and mugearites, by contrast, have a sodic alkaline affinity and are silica undersaturated; they are also enriched in Nb (up to 47 ppm) and a wide range of incompatible trace elements, including LILE, LREE, and HFSE. Geochemistry and Sr–Nd isotopic compositions of the high-Nb hawaiites and mugearites suggest derivation from a mantle source affected by lower degrees of slab melts. Post-orogenic slab break-off is suggested to have prompted the asthenospheric upwelling that triggered partial melting in mantle metasomatized by slab-derived melts.     

A simple model of drainage flow in a valley

A model of the drainage flow in a valley under calm conditions has been developed on the basis of the conservation laws of mass, momentum, and heat. The inflow of mass and heat from side-slopes is incorporated, and the momentum and sensible heat exchanges between valley drainage flow and valley floor are parameterized.The characteristic velocity of valley drainage flow is expressed in terms of the following parameters: three potential temperature differences representing the temperature field in the valey; topographic parameters of the valley; mean bulk coefficients representing the aerodynamic conditions of the valley floor; and the stability of the ambient atmosphere. The characteristic thickness includes additional parameters of side-slope flow.That the model satisfactorily predicts the characteristic thickness and velocity is shown from comparison with observations from valleys several hundred meters to a few hundred kilometers long.     

Comparative assessment of Japan's long-term carbon budget under different effort-sharing principles

This article assesses Japan's carbon budgets up to 2100 in the global efforts to achieve the 2?°C target under different effort-sharing approaches based on long-term GHG mitigation scenarios published in 13 studies. The article also presents exemplary emission trajectories for Japan to stay within the calculated budget.

The literature data allow for an in-depth analysis of four effort-sharing categories. For a 450?ppm CO₂e stabilization level, the remaining carbon budgets for 2014–2100 were negative for the effort-sharing category that emphasizes historical responsibility and capability. For the other three, including the reference ‘Cost-effectiveness’ category, which showed the highest budget range among all categories, the calculated remaining budgets (20th and 80th percentile ranges) would run out in 21–29 years if the current emission levels were to continue. A 550?ppm CO₂e stabilization level increases the budgets by 6–17 years-equivalent of the current emissions, depending on the effort-sharing category. Exemplary emissions trajectories staying within the calculated budgets were also analysed for ‘Equality’, ‘Staged’ and ‘Cost-effectiveness’ categories. For a 450?ppm CO₂e stabilization level, Japan's GHG emissions would need to phase out sometime between 2045 and 2080, and the emission reductions in 2030 would be at least 16–29% below 1990 levels even for the most lenient ‘Cost-effectiveness’ category, and 29–36% for the ‘Equality’ category. The start year for accelerated emissions reductions and the emissions convergence level in the long term have major impact on the emissions reduction rates that need to be achieved, particularly in the case of smaller budgets.

Policy relevance

In previous climate mitigation target formulation processes for 2020 and 2030 in Japan, neither equity principles nor long-term management of cumulative GHG emissions was at the centre of discussion. This article quantitatively assesses how much more GHGs Japan can emit by 2100 to achieve the 2?°C target in light of different effort-sharing approaches, and how Japan's GHG emissions can be managed up to 2100. The long-term implications of recent energy policy developments following the Fukushima nuclear disaster for the calculated carbon budgets are also discussed.     

Tree-ring reconstructed summer temperature anomalies for temperate East Asia since 800 C.E.

We develop a summer temperature reconstruction for temperate East Asia based on a network of annual tree-ring chronologies covering the period 800–1989 C.E. The East Asia reconstruction is the regional average of 585 individual grid point summer temperature reconstructions produced using an ensemble version of point-by-point regression. Statistical calibration and validation tests indicate that the regional average possesses sufficient overall skill to allow it to be used to study the causes of temperature variability and change over the region. The reconstruction suggests a moderately warm early medieval epoch (ca. 850–1050 C.E.), followed by generally cooler ‘Little Ice Age’ conditions (ca. 1350–1880 C.E.) and 20th century warming up to the present time. Since 1990, average temperature has exceeded past warm epochs of comparable duration, but it is not statistically unprecedented. Superposed epoch analysis reveals a volcanic forcing signal in the East Asia summer temperature reconstruction, resulting in pulses of cooler summer conditions that may persist for several years. Substantial uncertainties remain, however, particularly at lower frequencies, thus requiring caution and scientific prudence in the interpretation of this record.     

A multi-proxy reconstruction of spatial and temporal variations in Asian summer temperatures over the last millennium

To investigate climate variability in Asia during the last millennium, the spatial and temporal evolution of summer (June–July–August; JJA) temperature in eastern and south-central Asia is reconstructed using multi-proxy records and the regularized expectation maximization (RegEM) algorithm with truncated total least squares (TTLS), under a point-by-point regression (PPR) framework. The temperature index reconstructions show that the late 20th century was the warmest period in Asia over the past millennium. The temperature field reconstructions illustrate that temperatures in central, eastern, and southern China during the 11th and 13th centuries, and in western Asia during the 12th century, were significantly higher than those in other regions, and comparable to levels in the 20th century. Except for the most recent warming, all identified warm events showed distinct regional expressions and none were uniform over the entire reconstruction area. The main finding of the study is that spatial temperature patterns have, on centennial time-scales, varied greatly over the last millennium. Moreover, seven climate model simulations, from the Coupled Model Intercomparison Project Phase 5 (CMIP5), over the same region of Asia, are all consistent with the temperature index reconstruction at the 99 % confidence level. Only spatial temperature patterns extracted as the first empirical orthogonal function (EOF) from the GISS-E2-R and MPI-ESM-P model simulations are significant and consistent with the temperature field reconstruction over the past millennium in Asia at the 90 % confidence level. This indicates that both the reconstruction and the simulations depict the temporal climate variability well over the past millennium. However, the spatial simulation or reconstruction capability of climate variability over the past millennium could be still limited. For reconstruction, some grid points do not pass validation tests and reveal the need for more proxies with high temporal resolution, accurate dating, and sensitive temperature signals, especially in central Asia and before AD 1400.