Influence of submarine fumaroles on the distribution of mercury in the sediment of Kagoshima Bay,Japan

To estimate the influence of mercury emitted from submarine fumaroles, the horizontal and vertical distribution of mercury in sediment of Kagoshima Bay was studied. The fumaroles are located in the northern bay head area, and the sediment samples had been taken from 52 points throughout the bay with a gravity core sampler. The core samples obtained were cut at a thickness of 1–2 cm and used for measurements. The total concentration of mercury in surface sediment in the northern and central areas of the bay was 51–679 μg kg^− 1 (average 199 μg kg^− 1, n = 22) and 23–100 μg kg^− 1 (average 55 μg kg^− 1, n = 30), respectively. The highest value was obtained in the vicinity of the fumaroles. The mercury concentration in sediment near the fumaroles varied with depth, which may reflect the variation in fumarolic activity. A successive extraction method was applied to the speciation of mercury in the sediment. The results showed that sediment taken in the vicinity of submarine fumaroles contained a higher percentage of mercury bound with organic matter.     

Improvement in the Fault Boundary Conditions for a Staggered Grid Finite-difference Method

The staggered grid finite-difference method is a powerful tool in seismology and is commonly used to study earthquake source dynamics. In the staggered grid finite-difference method stress and particle velocity components are calculated at different grid points, and a faulting problem is a mixed boundary problem, therefore different implementations of fault boundary conditions have been proposed. Viriuex and Madariaga (1982) chose the shear stress grid as the fault surface, however, this method has several problems: (1) Fault slip leakage outside the fault, and (2) the stress bump beyond the crack tip caused by S waves is not well resolved. Madariaga et al. (1998) solved the latter problem via thick fault implementation, but the former problem remains and causes a new issue; displacement discontinuity across the slip is not well modeled because of the artificial thickness of the fault. In the present study we improve the implementation of the fault boundary conditions in the staggered grid finite-difference method by using a fictitious surface to satisfy the fault boundary conditions. In our implementation, velocity (or displacement) grids are set on the fault plane, stress grids are shifted half grid spacing from the fault and stress on the fictitious surface in the rupture zone is given such that the interpolated stress on the fault is equal to the frictional stress. Within the area which does not rupture, stress on the fictitious surface is given a condition of no discontinuity of the velocity (or displacement). Fault normal displacement (or velocity) is given such that the normal stress on the fault is continuous across the fault. Artificial viscous damping is introduced on the fault to avoid vibration caused by onset of the slip. Our implementation has five advantages over previous versions: (1) No leakage of the slip prior to rupture and (2) a zero thickness fault, (3) stress on the fault is reliably calculated, (4) our implementation is suitable for the study of fault constitutive laws, as slip is defined as the difference between displacement on the plane of z = + 0 and that of z = − 0, and (5) cessation of slip is achieved correctly.     

Holocene estuarine sediments as a source of arsenic in Pleistocene groundwater in suburbs of Hanoi,Vietnam

Groundwater pollution by arsenic is a major health threat in suburban areas of Hanoi, Vietnam. The present study evaluates the effect of the sedimentary environments of the Pleistocene and Holocene deposits, and the recharge systems, on the groundwater arsenic pollution in Hanoi suburbs distant from the Red River. At two study sites (Linh Dam and Tai Mo communes), undisturbed soil cores identified a Pleistocene confined aquifer (PCA) and Holocene unconfined aquifer (HUA) as major aquifers, and Holocene estuarine and deltaic sediments as an aquitard layer between the two aquifers. The Holocene estuarine sediments (approximately 25–40 m depth, 9.6–4.8 cal ka BP) contained notably high concentrations of arsenic and organic matter, both likely to have been accumulated by mangroves during the Holocene sea-level highstand. The pore waters in these particular sediments exhibited elevated levels of arsenic and dissolved organic carbon. Arsenic in groundwater was higher in the PCA (25–94 μg/L) than in the HUA (5.2–42 μg/L), in both the monitoring wells and neighboring household tubewells. Elevated arsenic concentration in the PCA groundwater was likely due to vertical infiltration through the arsenic-rich and organic-matter-rich overlying Holocene estuarine sediments, caused by massive groundwater abstraction from the PCA. Countermeasures to prevent arsenic pollution of the PCA groundwater may include seeking alternative water resources, reducing water consumption, and/or appropriate choice of aquifers for groundwater supply.     

A lower trophic ecosystem model including iron effects in the Okhotsk Sea

We applied a three-dimensional ecosystem-physical coupled model including iron the effect to the Okhotsk Sea. In order to clarify the sources of iron, four dissolved iron compartments, based on the sources of supply, were added to Kawamiya et al.'s [1995, An ecological-physical coupled model applied to Station Papa. Journal of Oceanography, 51, 635-664] model (KKYS) to create our ecosystem model (KKYS-Fe). We hypothesized that four processes supply iron to sea water: atmospheric loadings from Northeastern Asia, input from the Amur River, dissolution from sediments and regeneration by zooplankton and bacteria. We simulated one year, from 1 January 2001 to 31 December 2001, using both KKYS-Fe and KKYS. KKYS could not reproduce the surface nitrate distribution after the spring bloom, whereas KKYS-Fe agreed well with observations in the northwestern Pacific because it includes iron limitation of phytoplankton growth. During the spring bloom, the main source of iron at the sea surface is from the atmosphere. The contribution of riverine iron to the total iron utilized for primary production is small in the Okhotsk Sea. Atmospheric deposition, the iron flux from sediment and regeneration of iron in the water column play important roles in maintaining high primary production in the Okhotsk Sea.     

Late Permian (Lopingian) foraminifers from the Doi Chiang Dao Limestone in the Inthanon Zone of Northern Thailand

Late Permian foraminifers were found from six localities belonging to the Doi Chiang Dao Limestone, which is considered as having a Paleo-Tethyan seamount-capping carbonates origin, distributed in the Inthanon Zone of Northern Thailand. Among them, three age-diagnostic assemblages are recognized. They are represented by the occurrences of Codonofusiella kwangsiana, Palaeofusulina cf. minima, and P. prisca, and are referable to the Wuchiapingian, early Changhsingian, and late Changhsingian, respectively. In particular, the discovery of an assemblage characterized by advanced Palaeofusulina (P. prisca) is significant because it clearly indicates that the deposition of the Doi Chiang Dao Limestone had continued until the very end of the Permian. These three Late Permian assemblages can be compared with those recently reported from the Shifodong Formation of Pa-leo-Tethyan mid-oceanic carbonates in the Changning-Menglian Belt of West Yunnan, Southwest China.