Experimental study on prevention of acid mine drainage by silica coating of pyrite waste rocks with amorphous silica solution

Acid mine drainage (AMD) is a widespread environmental problem associated with working and abandoned mining operations. It results from the microbial oxidation of pyrite in the presence of water and air, affording an acidic solution that contains toxic metal ions. Pyrite microencapsulation, utilizing silica coating, is a novel approach for controlling AMD that has been shown to be very effective in controlling pyrite oxidation. The roles of the solution pH and silica concentration in the formation mechanism for the AMD-preventing coating were investigated. A silica coating can be formed from silica solution at pH 7, at which the amount of Fe eluted from pyrite into the solution is small. No coating was formed at other pH values, and the amounts of eluted Fe were larger than at pH 7, especially at pH 11. The silica coating forms from 2,500 to 5,000 mg/L silica solutions, but not from 0 or 1,000 mg/L silica solutions. The coating formation rate was slower in the 2,500 mg/L silica solution than in the 5,000 mg/L silica solution. The formation of silica coating on pyrite surfaces depends on three main steps: formation of Fe(OH)₃ on the surface of pyrite, reaction between Fe(OH)₃ and silicate in the solution on the pyrite surface, and growth of the silica layer on the first layer of silica. The best pH condition to enable these steps was around 7, and the silica coating formation rate can be controlled by the concentration of silica.     

Growth of ringwoodite reaction rims from MgSiO3 perovskite and periclase at 22.5 GPa and 1,800 °C

The growth rate of ringwoodite reaction rims between MgSiO₃ perovskite and periclase was investigated at 22.5 GPa and 1,800 °C for 1–24 h using the Kawai-type high-pressure apparatus. The reaction was likely to proceed by a diffusion-controlled mechanism in which the dominant diffusion mechanism was grain-boundary diffusion. The reaction constant (the width of the ringwoodite reaction rim squared divided by time) determined from these experiments was between 1.3 × 10^?15 and 5.6 × 10^?15 m²/s. A Pt inert marker experiment indicated that the MgO component migrated faster than the SiO₂ component in ringwoodite. Thus, either Mg or O having the slower diffusion rate controlled the reaction. Because previous diffusion studies have shown that diffusion rates of O are slower than those of Mg, O would be a rate-controlling element for ringwoodite formation from MgSiO₃ perovskite and periclase. The growth rate appeared to be too fast to explain the observed topographic rise (~10 km) inside mantle plumes at the 660-km discontinuity.     

类石材料--灰泥的冻融过程

Serious failure on the slope of rock ground can be caused by a cyclic action of freezing and thawing in the cold regions. The frost susceptibility and the effect of freezing and thawing onthe rock material, however, have not been well investigated. In order to find out the freezing effect on the rock materials, mortar specimens are frozen as a pseudo-rock material under the constant rate of freezing by means of controlling the temperature of both ends of specimen. The freezing process is given one-dimensionally to the cylindrical samples in the laboratory to simulate the in-situ freezing phenomena in the natural ground. Formation of ice lens, frost heave and water intake during freezing process are observed on the mortar specimen under constant freezing rate, which probably causes cracks or large deformation in the real rock ground. The values of the velocity of elastic wave propagation are compared before and after freezing process to estimate the degree of weathering due to freezing and thawing.     

Deep structure of the Nojima Fault, southwest Japan, estimated from borehole observations of fault-zone trapped waves

To estimate the deep structure of the southern part of the Nojima Fault, southwest Japan without the influence of near-surface structures, we analyzed the Love-wave-type fault-zone trapped waves (LTWs) recorded by a borehole seismometer at 1800 m depth. We examined the polarization, dispersion, and dominant frequency of the wavetrain following the direct S-wave in each seismogram to identify the LTW. We selected eight candidates for typical LTWs from 462 records. Because the duration of the LTW increases with hypocentral distance, we infer that the low velocity fault-zone of the Nojima Fault continues towards the seismogenic depth. In addition, since the duration of the LTW increases nonlinearly with hypocentral distance, we infer that the S-wave velocity of the fault-zone increases with depth. The location of events showing the LTW indicates that the fault-zone dips to the southeast at 75° and continues to a depth of approximately 10 km. We assumed a uniform low-velocity waveguide to estimate the average structure of the fault-zone. We estimated the average width, S-wave velocity, and Q_s of the fault-zone by comparing an analytical solution of the LTW with measured data. The average width, S-wave velocity, and Q_s of the fault-zone are 150 to 290 m, 2.5 to 3.2 km/s, and 40 to 90, respectively. Hence the fault-zone structure with a larger width and smaller velocity reduction than the fault-zone model estimated by previous surface observation is more suitable to represent the average fault-zone structure of the Nojima fault. The present study also indicated that the shallow layers and/or a shallow fault-zone structure drastically changes the characteristics of the LTW recorded at the surface, and therefore cause a discrepancy in the fault-zone model between the borehole observation and surface observation.     

Hydraulic properties of and pressure-head dynamics in thick pyroclastic-fall deposits in Atsuma,Northern Japan: implications for the role of water in shallow landslides induced by the 2018 Hokkaido Eastern Iburi Earthquake

Landslides - The 2018 Hokkaido Eastern Iburi Earthquake triggered numerous shallow landslides on slopes covered with thick pyroclastic-fall deposits. The landslides occurred more frequently on...     

Theory for the critical ionization velocity phenomenon

A theoretical consideration is given to the critical ionization velocity. A macroscopic theory is constructed, assuming that (1) the newly born ions have an unstable velocity distribution and (2) the resultant fluctuating electric field heats the electrons. For the critical ionization velocity to operate in the case of $\text{m}{}_{\mathrm{a}}\text{V}{}^2\text{2}\text{> eφ}{}_{\mathrm{<mtext>ion</mtext>}}$, the initial values of high speed ion (or newly ionized ion) density and suprathermal electron energy density should be above a certain threshold. This threshold depends upon the velocity diffusion co-efficient and the collisional loss rate of the newly ionized ion.