Geotechnical properties of submarine sediments in the Seto Inland Sea

Abstract

Sampling of submarine sediments by an improved piston corer and a bucket dredger has been carried out since 1973. The length of the core samples ranged from 0.9 m to 5.4 m. The recovery ratio ranged from 39.1 percent to 98.9 percent. The physical and engineering properties of 16 sediment cores and the physical properties of 125 dredged samples were determined, and variation of these properties was analyzed.

Clayey silts and silty clays cover the floor of relatively wide bays and sea areas. Sands and sandy silts blanket the floor of channels that have swift currents, and are also found in the vicinity of estuaries.

The piston core samples showed considerable sample disturbance, which should be estimated quantitatively in the future.     

Effects of heavy oil in the developing spotted halibut, Verasper variegatus

It is well known that heavy oil (HO) on the sea surface causes serious problems in the aquatic environment. In particular, some species of teleosts which develop on the sea surface are thought to be affected by the HO which flows out from tankers or coastal industry. However, the toxicological effects of HO are not fully understood. We performed exposure experiments using the Pleuronectiformean fish, spotted halibut (Verasper variegatus), which is an important fishery resource in Japan. In course of the development, HO-exposed embryos showed remarkable delay in developmental processes including somite formation. We further observed abnormal development of the head morphology. Notably, treated embryos had relatively small eyes and craniofacial structures. These findings strongly suggest that HO seriously affects the cell proliferation and differentiation of the embryo. In addition, HO-exposed embryos showed abnormal neuronal development. We also performed the exposure in the larval stage. Treatment of post-hatching larvae with HO resulted in significantly greater mortality compared with controls. Through these observations, we finally conclude that HO is strongly toxic to halibut in their early life stages.     

Effects of heavy oil in the developing spotted halibut, Verasper variegatus

It is well known that heavy oil (HO) on the sea surface causes serious problems in the aquatic environment. In particular, some species of teleosts which develop on the sea surface are thought to be affected by the HO which flows out from tankers or coastal industry. However, the toxicological effects of HO are not fully understood. We performed exposure experiments using the Pleuronectiformean fish, spotted halibut (Verasper variegatus), which is an important fishery resource in Japan. In course of the development, HO-exposed embryos showed remarkable delay in developmental processes including somite formation. We further observed abnormal development of the head morphology. Notably, treated embryos had relatively small eyes and craniofacial structures. These findings strongly suggest that HO seriously affects the cell proliferation and differentiation of the embryo. In addition, HO-exposed embryos showed abnormal neuronal development. We also performed the exposure in the larval stage. Treatment of post-hatching larvae with HO resulted in significantly greater mortality compared with controls. Through these observations, we finally conclude that HO is strongly toxic to halibut in their early life stages.     

Determination of Ti, K, Sm and Gd Values in Geological Survey of Japan Reference Materials by Prompt Gamma Neutron Activation Analysis

Prompt gamma neutron activation analysis was applied to the determination of the titanium, potassium, samarium and gadolinium contents of nine Geological Survey of Japan (GSJ) reference materials (JB-1, 1a, 2, 3; JA-1, 2, 3; JR-1, 2). Firstly, the values in JB-1 were determined by the standard addition method: pressed powder disks of JB-1 were used for neutron irradiation and gamma-ray measurements, after known quantities of standard reagents had been added. Secondly, the contents of eight other reference materials were determined by comparison methods using JB-1 as the comparative standard. The precision of analyses were obtained by replicate determinations on these samples. The relative standard deviation was generally less than 5%. For most samples, analysed values agreed well (< 5%) with the recommended values.     

Twin formation in hematite during dehydration of goethite

Twin formation in hematite during dehydration was investigated using X-ray diffraction, electron diffraction, and high-resolution transmission electron microscopy (TEM). When synthetic goethite was heated at different temperatures between 100 and 800 °C, a phase transformation occurred at temperatures above 250 °C. The electron diffraction patterns showed that the single-crystalline goethite with a growth direction of [001]_G was transformed into hematite with a growth direction of [100]_H. Two non-equivalent structures emerged in hematite after dehydration, with twin boundaries at the interface between the two variants. As the temperature was increased, crystal growth occurred. At 800 °C, the majority of the twin boundaries disappeared; however, some hematite particles remained in the twinned variant. The electron diffraction patterns and high-resolution TEM observations indicated that the twin boundaries consisted of crystallographically equivalent prismatic (100) (010), and (1\(\bar{1}\)0) planes. According to the total energy calculations based on spin-polarized density functional theory, the twin boundary of prismatic (100) screw had small interfacial energy (0.24 J/m²). Owing to this low interfacial energy, the prismatic (100) screw interface remained after higher-temperature treatment at 800 °C.     

Subdivision of the Sanbagawa pumpellyite–actinolite facies region in central Shikoku, southwest Japan

Abstract   The mineral assemblages of the pumpellyite–actinolite facies such as pumpellyite + actinolite + epidote + chlorite or actinolite + epidote + hematite + chlorite occur in the Sanbagawa low-grade metamorphic region, central Shikoku, southwest Japan. Chemical compositions of these minerals from the eight newly studied areas were analyzed in order to evaluate the areal extent and thermal structure of the region. In the buffered assemblage of pumpellyite + actinolite + epidote + chlorite, the Fe³⁺/(Fe³⁺ + Al) values of epidote decrease slightly with decreasing Fe²⁺/(Fe²⁺ + Mg) values for chlorite. The changes in these values show a general correlation with temperature. The presence of this relationship implies that the Fe³⁺/(Fe³⁺ + Al) values of epidote can be used to divide the Sanbagawa low-grade metamorphic region into low-, medium- and high-grade subzones. The areal distribution of these subzones indicates that: (i) the temperature seems to decrease in the same sense as envisaged by the zonal mapping of the higher-grade pelitic schists; and (ii) there is no significant gap of metamorphic conditions through the boundary between the two structural units (Besshi and Oboke units). It follows that the Sanbagawa low-grade metamorphic region decreases in temperature going up the structural section, and tectonic discontinuities have not affected the thermal structure.     

Soil column experiments for iodate and iodide using K-edge XANES and HPLC–ICP-MS

Radioactive iodine is one of the most problematic radionuclides because of its long half life and high mobility. Mobility of iodine depends on the chemical form to a great extent. This paper reports the results of soil column experiments we conducted to evaluate the mobilities of IO₃⁻ and I⁻. In order to determine the mechanisms of adsorption of IO₃⁻ and I⁻ on soil, adsorption isotherms were obtained by batch experiments. Both adsorption isotherms of IO₃⁻ and I⁻ are well explained by Langmuir model. The adsorption maximum of IO₃⁻ is about five times larger than that of I⁻. In the column experiments, iodine distributions between soil and pore water in the soil column were determined at various depths. Chemical forms of iodine in soil and pore water were determined by X-ray absorption near-edge structure (XANES), and high performance liquid chromatography connected to inductively coupled plasma mass spectrometry (HPLC–ICP-MS), respectively. Vertical profiles of iodine in pore water were simulated using Visual MODFLOW. Our results showed, upon I⁻ infiltration through the column, that a small amount of I⁻ adsorbed on soil, and its mobility is mainly controlled by advection and dispersion. The profile of iodine concentration in pore water was well simulated by assuming equilibrium-controlled Langmuir type adsorption without considering any chemical transformations. For the IO₃⁻ addition system into the column, however, IO₃⁻ adsorbed to soil to a larger degree, which causes a much larger retardation effect than I⁻. In addition, reduction of IO₃⁻ to I⁻ was also confirmed in both soil and pore water by XANES and HPLC–ICP-MS, respectively. The fraction of I⁻ increased toward the deeper end in both phases because of its lower affinity for soil than IO₃⁻, where the reduced I⁻ was released to the pore water and transported by the water flow. In this study, such reduction effect was clearly demonstrated by the speciation analyses of iodine in both soil and water phases, which confirmed that the mobility of I⁻ is a dominant factor that controls the fate of iodine in the surface environment.     

Fission–track Ages and Magnetic Susceptibility of Cretaceous to Paleogene Volcanic Rocks in Southeastern Sikhote Alin, Far East Russia

Abstract: Seven zircon fission-track ages and 30 magnetic susceptibilities were measured on welded pyroclastic rocks from the Bogopol and Sijanov Groups of the Cretaceous to Paleogene volcanic rocks in the southeastern part of the eastern Sikhote Alin volcano-plutonic belt, Far East Russia. The fission-track ages range from 42. 7 Ma to 64. O Ma which indicate that both the groups are of Early Paleogene time. Two thirds of the samples from the Bogopol Group have high magnetic susceptibility values, more than 3 A- 10^-3 SI unit, which imply that they are of the magnetite–series, whereas the samples from the Sijanov Group show 3 A- 10^-3 to 8 A- 10^-5 SI unit which suggest this group of probably the ilmenite-series.
The Paleogene age and high magnetic susceptibility of the Bogopol Group are quite similar to the Paleogene igneous rocks of the San'in belt, Southwest Japan. This suggests, taking accounts of the opening of the Japan Sea, that the eastern Sikhote Alin volcano-plutonic belt continued to the San'in Belt, and that the Paleogene igneous rocks along the Japan Sea coast of Northeast Japan were situated along the volcanic front of the eastern Sikhote Alin volcano-plutonic belt.     

Effects of Scale and Normal Stress on Shear Behavior of a Soft Fracture Replica

The effects of the fracture scale (size) and normal stress on the shear behavior of a fracture were investigated in direct shear rig using mortar fracture replicas of different sizes (100–200 mm), which were reproduced from a tensile fracture created in granite. Monotonic shear loading was applied at normal stresses of 0.3 and 1 MPa for shear displacements of 2 and 20 mm. The change in surface topography was measured by using a profile measurement system with a laser profilometer to determine the changes in surface damage and the aperture during shear. Additionally, the effect of gouge material on the non-linearity of the closure curve during shear was investigated. The results show that the standard deviation of the initial aperture during shear increases not only with scale but also with the normal stress, since the matedness decreases due to the fact that asperities are more damaged with normal stress, and accordingly, the non-linearity in the closure curve during shear increases with normal stress. The results also show that the non-linearity of the closure curve during shear increases with the presence of gouge material/debris that is produced in the shearing process. This is mainly because gouge is soft and easily deforms under the application of normal stress. Moreover, gouge material is distributed non-uniformly around the contact areas. Thus, the normal stiffness during shear decreases not only with a decrease in the matedness between the surfaces, but also with the presence of gouge material.     

Style of fluid flow and deformation in and around an ancient out-of-sequence thrust: An example from the Nobeoka Tectonic Line in the Shimanto accretionary complex, Southwest Japan

To understand the characteristics of deformation of an out-of-sequence thrust (OST) and the style of fluid flow along it, we investigated the Nobeoka Tectonic Line, which has been interpreted as a deep OST (7–9 km), in the Shimanto accretionary complex, Southwest Japan. The shear zone in the footwall differs significantly in the along-strike direction not only in thickness, which varied from 100 to 300 m, but also in lithology and mineral vein development. These variations might reflect primarily differences in lithology; that is, the sandstone-dominant shear zone with a large amount of mineral veins precipitated in microcracks is relatively thick, whereas the shale-dominant shear zone with a small amount of veins and with textures indicating highly pressurized pore fluid, is thinner. By comparison with characteristics of a shallow OST (3–5 km), we conclude that the shallow OST has experienced repeated brittle failure with rapid slip and focused fluid flow whereas the deep OST has experienced both brittle and ductile deformation, followed by fluid flow of various styles, depending on the lithology.