建立回弹现场测强曲线的位置参数法

工程上迫切需要在现场数据较少的情况下,建立高精度和高可靠度的现场测强曲线(经验公式)。本文利用位置参数法,提出了一种回弹法现场测强曲线(经验公式)。此曲线(经验公式)仍运用原有的幂函数形式并保持回归参数不变,通过增加位置参数反映现场试验的个性信息。此曲线(经验公式)融合了所在地区混凝土强度值、回弹值、碳化深度值之间的共性趋势和现场检测得到的反映现场情况的个性信息,而且解决了地区测强曲线(经验公式)不能完全描述现场的实际情况,而现场检测数据一般不能满足制定现场专用测强曲线(经验公式)要求的问题。在建筑结构无损检测中,利用本文提出的测强曲线(经验公式)可以极大地提高检测精度和检测结果的可靠性,使检测结果更加符合施工现场的实际情况。     

环球海洋大气气溶胶化学研究

1986年11月—1987年5月,在中国第三次南极考察和环球科学考察期间,收集了58个海洋气溶胶样品,采用中子活化法分析了Al,V,Mn,I,Br,Mg,Na,Cl等元素。应用因子分析、回归分析和富集因子分析对气溶胶中元素进行分类、定量评估和来源判别,讨论不同来源元素的特征,计算各主要来源的贡献分量。结果表明,海洋气溶胶中Al的99.99％是来自陆源地壳风化物,Na的99.2％。和Cl的99.99％是来自海水,V的91.4％。来自陆源污染物。因此,Al可作为海洋气溶胶中陆源地壳风化物的示踪元素,Na和Cl可作为海水源示踪元素,非地壳源的V则可选择为陆源污染物的示踪元素。     

An Investigation of Digestion Methods for Trace Elements in Bauxite and Their Determination in Ten Bauxite Reference Materials Using Inductively Coupled Plasma‐Mass Spectrometry

Trace elements from samples of bauxite deposits can provide useful information relevant to the exploration of the ore‐forming process. Sample digestion is a fundamental and critical stage in the process of geochemical analysis, which enables the acquisition of accurate trace element data by ICP‐MS. However, the conventional bomb digestion method with HF/HNO₃ results in a significant loss of rare earth elements (REEs) due to the formation of insoluble AlF₃ precipitates during the digestion of bauxite samples. In this study, the digestion capability of the following methods was investigated: (a) ‘Mg‐addition’ bomb digestion, (b) NH₄HF₂ open vessel digestion and (c) NH₄F open vessel digestion. ‘Mg‐addition’ bomb digestion can effectively suppress the formation of AlF₃ and simultaneously ensure the complete decomposition of resistant minerals in bauxite samples. The addition of MgO to the bauxite samples resulted in (Mg + Ca)/Al ratios ≥ 1. However, adding a large amount of MgO leads to significant blank contamination for some transition elements (V, Cr, Ni and Zn). The NH₄HF₂ or NH₄F open vessel digestion methods can also completely digest resistant minerals in bauxite samples in a short period of time (5 hr). Unlike conventional bomb digestion with HF/HNO₃, the white precipitates and the semi‐transparent gels present in the NH₄HF₂ and NH₄F digestion methods could be efficiently dissolved by evaporation with HClO₄. Based on these three optimised digestion methods, thirty‐seven trace elements including REEs in ten bauxite reference materials (RMs) were determined by ICP‐MS. The data obtained showed excellent inter‐method reproducibility (agreement within 5% for REEs). The relative standard deviation (% RSD) for most elements was < 6%. The concentrations of trace elements in the ten bauxite RMs showed agreement with the limited certified (Li, V, Cr, Cu, Zn, Ga, Sr, Zr and Pb) and information values (Co, Ba, Ce and Hf) available. New trace element data for the ten RMs are provided, some of which for the first time.     

围填海对海洋水动力与生态环境的影响

近10年来,中国海岸带围填海活动呈现出规模大、速度快的发展态势。围填海能带来显著的经济效益,但对海洋环境与生态的负面影响也不可忽视。针对围填海对海洋环境和生态的影响及作用机制,分别从水动力和生态系统两个方面进行了概述。围填海改变了海洋的自然几何属性(原始岸线、地形地貌、海湾面积),引起水动力环境的变化(潮汐系统和海湾水交换能力),进而影响了海湾的环境容量;围填海破坏了生物栖息地、导致生物多样性的丧失,影响到生态系统结构与功能的稳定性;水动力与生物多样性的变化可显著影响到生物地球化学过程,加速富营养化进程,恶化水质,增加生态灾害风险。目前,围填海后的生态修复策略主要有增加生物量、建设自然保护区、退陆还海3种方式;而生态补偿策略则多基于“生态系统服务功能与生境面积的大小为线性关系”,通过对其经济价值的量化后进行生态补偿与实施相关政策。国际上,生态系统服务功能的量化参数逐步纳入实际管理,并在线性关系研究的基础上,逐步纳入一些非线性的理念,使生态补偿机制更为合理化;而我国对于围填海生态效应的定量化研究及科学理论在管理政策中的实际应用仍亟待提高。整体而言,全面、准确地评估围填海对海洋环境与生态的影响离不开自然科学与社会科学的交叉与融合。     

胶州湾北部水层生态动力学模型与模拟 Ⅱ.胶州湾北部水层生态动力学的模拟研究

利用建立起的浅海水层生态动力学箱式模型,模拟了胶州湾北部１９９５年的浮游植物、浮游动物、无机氮、无机磷、溶解氧以及ＤＯＣ和ＰＯＣ年变化特征。结果是合理的。通过模型参数敏感性实验分析,揭示了该模型系统的一些动力学特征     

坛紫菜中藻胆蛋白的性质与化学组成研究

坛紫菜(于1988年采自青岛太平角海区人工养殖筏上)的水溶性色素粗提物经过硫酸铵沉淀和羟基磷灰石(HA)柱层析后,分离出藻蓝蛋白(RPC)、藻红蛋白(RPE)和变藻蓝蛋白(APC)。在中性介质中,其吸收光谱和荧光发射光谱与文献报道基本一致;但在酸性(pH=3)或碱性(pH=12)介质中,吸收光谱较在中性介质中有明显改变,原有的荧光性质也消失。RPC和APC只分离到一种聚集体,但RPE有两种不同的聚集体。用SephadexG—100凝胶过滤方法测量藻胆蛋白的分子量分别为:RPC117000,APC112000,小分子RPE38000,大分子RPE232000。对三种藻胆蛋白的氨基酸分析的结果表明,三种藻胆蛋白中都是酸性氨基酸的含量大于碱性氨基酸的含量。     

Model tests on installation and extraction of suction caissons in dense sand

A series of model tests were performed on steel- and Perspex-made suction caissons in saturated dense marine sand to explore installation and extraction behaviors. The extractions of the caisson were conducted by applying monotonic loading or by pumping water into the caisson. Responses of suction caissons to pullout rates, aspect ratios, and extraction manners were examined. Test results show that a cone-shaped subsidence region occurs around the suction caisson during the suction-assisted installation. The pullout bearing capacity of the suction caisson in sand is dominated by the loading rate and the loading manner. For the suction caisson subjected to monotonic loading, the maximum bearing capacity is reached at the pullout rate of about 20.0?mm/s. The mobilized vertical displacement corresponding to the pullout capacity increases with increasing the pullout rate. The passive suction beneath the suction caisson lid reaches the maximum value when the pullout bearing capacity is mobilized. In addition, during the suction caisson extracted by pumping water into the caisson, the maximum pore water pressure in the caisson is obtained under the displacement of approximately 0.04 times the caisson diameter. The absolute values of the maximum pore water pressures for the suction caissons approximately equal those of the maximum vertical resistances at the monotonic pullout rate of 5 mm/s. When the vertical displacements of the suction caissons with the aspect ratio of 1.0 and 2.0 reach 0.92 and 1.77 times the caisson diameter, respectively, the seepage failure occurs around the caissons. Using a scaling method, the test results can be used to predict the time length required for the prototype suction caisson to be extracted from the seabed.     

Laboratory study on cement admixed marine silt bricks

For the purpose of efficient utilization of sediments dredged from harbor, a new method was proposed in this study. Marine silt bricks were made by mixing sediments with cement and gypsum, placing it in a cubic mold with 240 mm in length, 115 mm in width, and 53 mm in height, and curing for certain days. To investigate the effects of cement and initial water content of soil on the mechanical behavior of marine silt bricks, unconfined compressive and flexural strength tests were carried out. Given the same curing time and cement content, the higher the initial water content, the lower the compressive and flexural strength. After 60 days of curing, the compressive strength of marine silt bricks with cement content = 20% and water content = LL (liquid limit) reached approximately 5 MPa. The flexural strength was relatively low. The flexural strength of marine silt bricks with 20% cement and water content = LL was around 1.5 MPa. The compressive and flexural strength decreased with the increase of water/cement ratio. As for the curing time, longer curing time had a positive impact on the compressive strength. The ratio of flexural to compressive strength varied slightly in the range of 0.4–0.5.     

数值波浪水槽消波器的改进与检验

数值波浪水槽技术是一种新兴的水波动力学数值模拟技术, 它能够实现水波现象的精确模拟。作为数值波浪水槽的一个重要功能, 消波技术被用于消除传入波浪在水槽末端的反射效应, 以防止反射波对有效实验区域的污染, 从而保证特定要求的水波实验的精确性。目前被广泛采用的消波技术可分为阻尼消波区和主动消波器两类。     

Spatial variability in the partial pressures of CO2 in the northern Bering and Chukchi seas

In the summers of 1999 and 2003, the 1st and 2nd Chinese National Arctic Research Expeditions measured the partial pressure of CO₂ in the air and surface waters (pCO₂) of the Bering Sea and the western Arctic Ocean. The lowest pCO₂ values were found in continental shelf waters, increased values over the Bering Sea shelf slope, and the highest values in the waters of the Bering Abyssal Plain (BAP) and the Canadian Basin. These differences arise from a combination of various source waters, biological uptake, and seasonal warming. The Chukchi Sea was found to be a carbon dioxide sink, a result of the increased open water due to rapid sea-ice melting, high primary production over the shelf and in marginal ice zones (MIZ), and transport of low pCO₂ waters from the Bering Sea. As a consequence of differences in inflow water masses, relatively low pCO₂ concentrations occurred in the Anadyr waters that dominate the western Bering Strait, and relatively high values in the waters of the Alaskan Coastal Current (ACC) in the eastern strait. The generally lower pCO₂ values found in mid-August compared to at the end of July in the Bering Strait region (66–69°N) are attributed to the presence of phytoplankton blooms. In August, higher pCO₂ than in July between 68.5 and 69°N along 169°W was associated with higher sea-surface temperatures (SST), possibly as an influence of the ACC. In August in the MIZ, pCO₂ was observed to increase along with the temperature, indicating that SST plays an important role when the pack ice melts and recedes.