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121.
Sajjad Hussain Saima Gul Sabir Khan Habib ur Rehman 《Arabian Journal of Geosciences》2013,6(11):4547-4556
In the present study, the retention capacity of carbonaceous material obtained from the diesel engine exhaust mufflers for Cr(VI) removal has been investigated. The physicochemical properties such as density, pH of aqueous slurry, pH at point of zero charge, ash content, moisture content, volatile matter, surface area, scanning electron microscopy and electron dispersive spectroscopy of the carbonaceous material were determined. The capacity of adsorbent for removal of Cr(VI) from aqueous solution was observed under different experimental condition like contact time, initial concentration of metal ions, pH and temperatures on the adsorption capacity of the adsorbent. Maximum adsorption of Cr(VI) ions was found at low pH. The adsorption process was found to follow second-order kinetics. The rate constant was evaluated at different temperatures along with other thermodynamic parameters like activation energy, Gibbs free energy change, enthalpy change and entropy change. Both Langmuir and Freundlich isotherms were used to describe the adsorption equilibrium of carbonaceous material at different temperatures. Langmuir isotherm shows better fit than Freundlich isotherm at given conditions. The result shows that low-cost carbonaceous material from diesel engine exhaust mufflers can be efficiently used for wastewater treatment containing Cr(VI) ions. 相似文献
122.
Muhammad Irfan Aziz Akbar Mubashir Aziz Ammad Hassan Khan 《Geotechnical and Geological Engineering》2013,31(2):729-738
Rapid urbanization and expansion of metropolitans in the developing world is pressing the need of tall structures with multiple basements. In several such projects, open land is available around excavation site and unsupported deep excavations by maintaining appropriate side slopes offer economical solution. In this research, subsoil stratigraphy of Lahore district was established to be comprising of a top clay stratum 1.5–8 m thick, followed by a sand layer. Considering subsoil data from several geotechnical investigation reports, the effect of four key parameters viz., cohesion of clay layer, friction angle of sand layer, thickness of clay layer at the top and slope inclination of underlying sand layer on safety factor of open excavations was studied. Six hundred twenty-five slope stability analyses were conducted by considering different geometries and soil properties. Based on the results of these analyses, a regression model was suggested to estimate safety factor of open excavations in similar stratigraphy which would be useful in feasibility studies and preliminary design of deep excavations. It was established that the clay layer cohesion was the most dominant contributor to safety factor. 相似文献
123.
Richard A. Beck Douglas W. Burbank William J. Sercombe Asrar M. Khan Robert D. Lawrence 《Geodinamica Acta》2013,26(2-3):114-144
AbstractCollision of the Kohistan island arc with Asia at ~100 Ma resulted in N-S compression within the Neo-Tethys at a spreading center north of the Indo-Pakistani craton. Subsequent India-Asia convergence converted the Neo-Tethyan spreading center into a short-lived subduction zone. The hanging wall of the subduction zone became the Waziristan, Khost and Jalalabad igneous complexes. During the Santonian- Campanian (late Cretaceous), thrusting of the NW IndoPakistani craton beneath Albian oceanic crust and a Cenomanian volcano-sedimentary complex, generated an ophiolite-radiolarite belt. Ophiolite obduction resulted in tectonic loading and flexural subsidence of the NW Indian margin and sub-CCD deposition of shelf-derived olistostromes and turbidites in the foredeep. Campanian-Maastriehtian calci- clastic and siliciclastic sediment gravity flows derived from both margins filled the foredeep as a huge allochthon of Triassic-Jurassic rise and slope strata was thrust ahead of the ophiolites onto the Indo-Pakistani craton. Shallow to intermediate marine strata covered the foredeep during the late Maastrichtian. As ophiolite obduction neared completion during the Maastrichtian, the majority of India-Asia convergence was accommodated along the southern margin of Asia. During the Paleocene, India was thrust beneath a second allochthon that included open marine middle Maastrichtian colored mélange which represents the Asian Makran-Indus-Tsangpo accretionary prism. Latérites that formed on the eroded ophiolites and structurally higher colored mélange during the Paleocene wei’e unconformably overlapped by upper Paleocene and Middle Eocene shallow marine limestone and shale that delineate distinct episodes of Paleocene collisional and Early Eocene post-collisional deformation. 相似文献
124.
Fatigue reliability analysis of deep water rigid marine risers associated with Morison-type wave loading 总被引:1,自引:0,他引:1
Muddassir Nazir Faisal Khan Paul Amyotte 《Stochastic Environmental Research and Risk Assessment (SERRA)》2008,22(3):379-390
This work presents a simple and efficient framework for the fatigue reliability assessment of a vertical top-tensioned rigid
riser. The fatigue damage response is considered as a narrow-band Gaussian stationary random process with a zero mean for
the short-term behavior of a riser. Non-linearity in a response associated with Morison-type wave loading is accounted for
by using a factor, which is the ratio of expected damage according to a non-linear probability distribution to the expected
damage according to a linear method of analysis. Long-term non-stationary response is obtained by summing up a large number
of short-term stationary responses. Uncertainties associated with both the strength and stress parts of the limit state function
are quantified by a lognormal distribution. A closed form reliability analysis is carried out, which is based on the limit
state function formulated in terms of Miner’s cumulative damage rule. The results thus obtained are compared with the well-documented
lognormal format of reliability analysis based on time to fatigue failure. The validity of using the lognormal hazard rate
function in predicting the fatigue life is discussed. A Monte Carlo simulation technique is also used as a reliability assessment
method. A simple algorithm is used to reduce the uncertainty associated with direct sampling at small probability of failure
values and a small number of simulations. Simulation results are compared with closed form solutions. A worked example is
included to show the practical riser design problem based on reliability analysis. 相似文献
125.
Assessment of Trace Metal Contamination of Drinking Water in the Pearl Valley,Azad Jammu and Kashmir
Saboor Javaid Syed Ghulam Sarwar Shah Abdul Jabbar Chaudhary Mohammad Haleem Khan 《洁净——土壤、空气、水》2008,36(2):216-221
The aim of this study was to assess trace metal contamination of drinking water in the Pearl Valley, Azad Jammu and Kashmir (Pakistan). The objectives were to determine physical properties and the dissolved concentration of five trace metals, i. e., lead, copper, nickel, zinc, and manganese, in drinking water samples collected from various sites of municipal water supply, natural water springs and wells in the valley. Concentrations of the metals in the water samples were determined by flame atomic absorption spectrometry. Results showed physical parameters, i. e., appearance, taste and odor within acceptable limits and pH was between 5.5 and 7.0. The observed concentrations of the metals varied between sources of water samples and between sampling sites. Maximum dissolved concentration observed was 4.7 mg/L for Pb and Mn, 4.6 mg/L for Zn, 2.9 mg/L for Ni and 2.8 mg/L for Cu. The observed concentrations of the metals were compared with the World Health Organization's guideline values for drinking water. Overall, the quality of water samples taken from the water springs at Mutyal Mara and Bonjosa was good; however, the water quality was unsuitable for drinking in Kiraki, Kharick, and Pothi Bala localities particularly. Finally, the authors discuss possible causes for increased concentrations of the trace metals in drinking water in the study area. 相似文献
126.
The Andaman–Sumatra margin displays a unique set‐up of extensional subduction–accretion complexes, which are the Java Trench, a tectonic (outer arc) prism, a sliver plate, a forearc, oceanic rises, inner‐arc volcanoes, and an extensional back‐arc with active spreading. Existing knowledge is reviewed in this paper, and some new data on the surface and subsurface signatures for operative geotectonics of this margin is analyzed. Subduction‐related deformation along the trench has been operating either continuously or intermittently since the Cretaceous. The oblique subduction has initiated strike–slip motion in the northern Sumatra–Andaman sector, and has formed a sliver plate between the subduction zone and a complex, right‐lateral fault system. The sliver fault, initiated in the Eocene, extended through the outer‐arc ridge offshore from Sumatra, and continued through the Andaman Sea connecting the Sagaing Fault in the north. Dominance of regional plate dynamics over simple subduction‐related accretionary processes led to the development and evolution of sedimentary basins of widely varied tectonic character along this margin. A number of north–south‐trending dismembered ophiolite slices of Cretaceous age, occurring at different structural levels with Eocene trench‐slope sediments, were uplifted and emplaced by a series of east‐dipping thrusts to shape the outer‐arc prism. North–south and east–west strike–slip faults controlled the subsidence, resulting in the development of a forearc basins and record Oligocene to Miocene–Pliocene sedimentation within mixed siliciclastic–carbonate systems. The opening of the Andaman Sea back‐arc occurred in two phases: an early (~11 Ma) stretching and rifting, followed by spreading since 4–5 Ma. The history of inner‐arc volcanic activity in the Andaman region extends to the early Miocene, and since the Miocene arc volcanism has been associated with an evolution from felsic to basaltic composition. 相似文献
127.
The discovery of hydrocarbons (mainly gas) in commercial quantities from Gondwanan sediments in the Mandapeta field of Krishna-Godavari Basin, India, provided impetus for intensified exploration in Mandapeta and the adjoining Kommugudem, Draksharama and Endamuru fields. Both oil and gas have been found in the reservoirs of Mandapeta (Triassic) and Golapalli (Early Cretaceous) formations. Mature, localised, basal shales (1.0–1.1% Ro) in the Mandapeta formation have sourced the oils from the Mandapeta Sandstone reservoir (Triassic). The oils being produced from Golapalli Sandstone reservoir (Early Cretaceous) are relatively less mature and have been sourced by the underlying shales in the Mandapeta Formation at a maturity level of 0.80–0.85% Ro. The source and maturity data preclude liquid hydrocarbon sourcing from the Kommugudem (Permian) sequence. Permian coals and shales of the Kommugudem Formation are the major source rocks for gaseous hydrocarbons in this area. The hydrocarbon generation started in Early Cretaceous in the Kommugudem Formation, but the intermittent tectonic activity (with associated structural developments) has resulted in reorientation and redistribution of the then existing trap configurations. The present day maturity level of the Permian sediments in the Mandapeta field is 1.2% Ro or greater, capable of generating gas dominantly. The Raghavapuram shale in the Mandapeta area is adequately mature and has good hydrocarbon potential for oil generation. The probability of finding hydrocarbon reserves in the sands of Raghavapuram shales and other suitable traps is high. Modern seismic information together with geologic models can give new exploration leads. 相似文献
128.
Visual interpretation of IRS-L1SS-II (January, 1995) FCC (1:50,000 scale) of spectral bands 2, 3 and 4 was carried out for the identification and mapping of major physiographic units in an arid watershed of Jodhpur district (Rajasthan). Based on image characteristics and field traverses, seven major physiographic units identified are (1) hills (2) pediments, flat to undulating (3) buried pediments, moderately deep to deep, coarse textured (4) buried pediment, shallow to moderately deep and deep, medium to fine textured, saline (5) older alluvial plains, deep and very deep, coarse textured (6) younger alluvial plains, deep to very deep, very coarse textured and (7) dune complexes. Based on physiographicvariatton and soil or site characteristics such as texture, depth, slope, erosion and underneath substrata, 41 soil mapping units were identified and mapped. Final physiography, soil, slope, drainage and landuse maps were prepared on 1:5,000 scale. Taxonomically, the soils of the watershed were classified as Para-Lithic Torriorthents, coarse-loamy, Lithic/Typic Haplocambids, fine-loamy, Lithic/Typic Haplosalids and Typic Torrifluvents and Typic Torripsamments. Land suitability for various mapping units in the watershed have been assessed on the basis of soil physico-chemical characteristics. 相似文献
129.
We have previously shown that lead (lead chloride) and a polychlorinated biphenyl (PCB) mixture (Aroclor 1254) can alter hypothalamic serotonin (5-hydroxytryptamine, 5-HT) content, and pituitary gonadotropin II (GTH II) release in vitro, in the Atlantic croaker (Micropogonias undulatus). In the present study we investigated whether impairment of the hypothalamic 5-HT pathway involves alterations in tryptophan hydroxylase (TPH), the rate-limiting enzyme in 5-HT biosynthesis, or monoamine oxidase (MAO), the catabolic enzyme. Aroclor 1254 (1 mg/kg body wt. for 30 days) significantly inhibited hypothalamic TPH activity without altering MAO activity, and caused a significant decline in 5-HT content. On the other hand, lead exposure (15 mg/kg body wt. for 30 days) only induced a slight decrease in hypothalamic 5-HT content and TPH activity, and a minor increase in MAO activity. However, both Aroclor 1254 and lead significantly inhibited the GTH II response to stimulation by a luteinizing hormone-releasing hormone analog (LHRHa) in vivo and caused reduced gonadal growth. These results demonstrate that impairment of hypothalamic serotonin metabolism by Aroclor 1254 involves inhibition of 5-HT synthesis, whereas lead does not exert a profound influence on 5-HT metabolism. The decline in 5-HT availability due to reduced 5-HT synthesis in the PCB-exposed fish may result in disruption of the stimulatory 5-HT-GnRH pathway controlling GTH II secretion leading to impairment of gonadal growth. 相似文献
130.