Simultaneous Measurement of Hydrogen Peroxide and Fe Species (Fe(II) and Fe<Subscript>(tot)</Subscript>) in Okinawa Island Seawater: Impacts of Red Soil Pollution

The northern part of Okinawa Island suffers from red soil pollution—runoff of red soil into coastal seawater—which damages coastal ecosystems and scenery. To elucidate the impacts of red soil pollution on the oxidizing power of seawater, hydrogen peroxide (HOOH) and iron species including Fe(II) and total iron (Fe_(tot), defined as the sum of Fe(II) and Fe(III)) were measured simultaneously in seawater from Taira Bay (red-soil-polluted sea) and Sesoko Island (unpolluted sea), off the northern part of Okinawa Island, Japan. We performed simultaneous measurements of HOOH and Fe(II) because the reaction between HOOH and Fe(II) forms hydroxyl radical (•OH), the most potent environmental oxidant. Gas-phase HOOH concentrations were also measured to better understand the sources of HOOH in seawater. Both HOOH and Fe(II) in seawater showed a clear diurnal variation, i.e. higher in the daytime and lower at night, while Fe_(tot) concentrations were relatively constant throughout the sampling period. Fe(II) and Fe_(tot) concentrations were approximately 58% and 19% higher in red-soil-polluted seawater than in unpolluted seawater. Gas-phase HOOH and seawater HOOH concentrations were comparable at both sampling sites, ranging from 1.4 to 5.4 ppbv in air and 30 to 160 nM in seawater. Since Fe(II) concentrations were higher in red-soil-polluted seawater while concentrations of HOOH were similar, •OH would form faster in red-soil-polluted seawater than in unpolluted seawater. Since the major scavenger of •OH, Br⁻, is expected to have similar concentrations at both sites, red-soil-polluted seawater is expected to have higher steady-state •OH concentrations.     

Aircraft measurements of oxides of nitrogen along the eastern rim of the Asian continent: Winter observations

Aircraft observations of oxides of nitrogen (NO _y ), measured with a ferrous sulfate converter, over the sea surrounding the Japanese islands (30–43° N, 131–141° E) were carried out in the winter of 1983 and 1984 at altitudes mostly between 3 and 8 km. NO _y defined here is the sum of NO, NO₂, and other unstable oxides of nitrogen that are converted to NO by ferrous sulfate. The main observations were:

1. Over the Pacific Ocean between the latitudes of 30–35° N, the observed NO _y mixing ratio between 3 and 8 km was a fairly constant 200 pptv. The NO mixing ratio increased with altitude from 15 pptv at 3 km to 35 pptv at 7 km.
2. Over the Sea of Japan, tropospheric NO _y mesured between 1 and 6 km started increasing with latitude North of 35° N and reached about 1000 pptv at 40° N.
3. NO _y was measured in an air mass transported from the stratosphere near a tropopause fold region. When the ozone mixing ratio was between 80 and 140 ppbv, the NO _y mixing ratio was about 200 pptv.

     

Inland penetration of the sea breeze over the suburban area of Tokyo

Observational results of the structure of the sea breeze over the urban and suburban areas of Tokyo for four summer days are presented.On two of these days, the inland penetration of the sea breeze front could be clearly traced. In one case, the sea breeze was first observed along the shores of Tokyo Bay around 0900 JST, and propagated in three hours through the Tokyo City area, the width of which is about 20 km. It then advanced inland at a rate of 16 km h^–1. Prior to the arrival of the sea breeze at the suburban site, the mixing height had remained at about 600 m for four hours. With the arrival of the sea breeze front, accompanied by an abrupt change in wind speed and direction, the mixing height increased sharply to 1700 m. It is suggested that this behavior and the structure of the front are intensified due to the urban effect, or the difference in the thermal characteristics between the urban and rural areas.On the days without a sea breeze front, the land breeze system during the early morning was less intense, allowing the sea breeze to develop simultaneously with the inland valley wind and easily form a large-scale local wind system during the morning hours. In both cases, the vertical motion accompanying the local wind system works as a feedback mechanism to control the local winds by modifying the thermal and pressure fields.     

On the formation of a neutron star in a close binary system

The effects on a close binary system of one component becoming a neutron star as a result of a supernova explosion are discussed in this paper. In the case of a Type I supernova, the system can remain bound in many cases of interest. For a Type II supernova, the system will probably be disrupted although in some cases a remnant of the companion to the supernova may remain in a bound orbit.Consequently, neutron stars formed in Type I supernova explosions may exist in close binary systems. Such systems may be strong X-ray emitters due to mass flow as suggested by Shklovsky. Photons with energies in the 1–50 MeV region should also be emitted.     

Localized rheological weakening by grain-size reduction during lithospheric extension

Grain-size reduction may be a possible mechanism for the origin of localized deformation in the ductile regime. I investigated the effects of grain-size reduction due to dynamic recrystallization, cataclasis, and syntectonic metamorphic reaction on the stress envelope in the lithospheric mantle during extension by using a simple one-dimensional model. In this model, the lithosphere extends uniformly with a constant strain rate, and a fall in rock strength appears as a decrease in stress. Because grain-size distribution at the onset of extension is unknown, I regarded the steady state grain-size due to dynamic recrystallization as the initial size. Then, I evaluated the maximum effects of grain-size reduction by dynamic recrystallization during extension, and consequently examined the effects of grain-size reduction by cataclasis and metamorphic reaction under conditions when dynamic recrystallization occurs significantly. I find that it is difficult to bring about localized rheological weakening by grain-size reduction owing to dynamic recrystallization. In contrast, grain-size reduction by cataclasis can cause localized weakening during extension. There is a wide-ranging rate of grain-size reduction by means of cataclasis that causes localized weakening just below the Moho. I specified the reaction from spinel-lherzolite to plagioclase-lherzolite that plays a role in grain-size reduction by syntectonic metamorphism. The reaction occurs at depths less than 35 km, which is independent of the initial thermal state of the lithosphere. Localized rheological weakening can occur if the following conditions are satisfied: (1) grain-size before the reaction is greater than 0.7 mm under dry conditions and greater than 0.5 mm under wet conditions, and it decreases down to those values by the reaction; (2) grain-size decreases down to less than initial grain-size, when the dominant deformation mechanism is GSS creep at the onset of extension. It is also noted that dry conditions are more favourable for localized weakening.     

Geologic evidence for late Quaternary repetitive surface faulting on the Isurugi fault along the northwestern margin of the Tonami Plain,north‐central Japan

Our detailed field investigation, paleoseismic trenching, and airborne light detection and ranging (LiDAR)‐derived topographic data provides the first direct evidence for late Quaternary repetitive surface faulting on the northeast‐striking Isurugi fault along the northwestern margin of the Tonami Plain in the Hokuriku region of north‐central Japan. This fault has been interpreted previously by different researchers as both inactive and active, owing to a lack of geologic evidence and a failure to identify fault‐related geomorphic features. Our mapping of LiDAR topography revealed a series of northeast‐trending warped fluvial terraces, about 1.5 km long and 170 m wide, with an age of ≤ 29 ka. We interpreted these geomorphologic features to represent an active pop‐up structure bounded to the southeast by the northwest‐dipping main thrust of the Isurugi fault and to the northwest by a southeast‐dipping backthrust that splays off the main thrust in the shallow subsurface. Paleoseismic trenching across the northwestern part of an elongate terrace exposed a series of southeast‐dipping backthrusts and associated northwest‐verging monoclines. The deformation and depositional age of the strata provide evidence for repetitive surface rupturing on the backthrusts since the latest Pleistocene; the latest of these events occurred in the Holocene between about 4.0 and 0.9 ka. Despite the poor preservation of the surface expression of the Isurugi fault, repetitive scarp‐forming faulting in the late Quaternary and the proximity of the Oyabe River and its tributaries to the fault trace suggest that there may be an extension of the Isurugi fault to the northeast and southwest beneath the Tonami Plain that makes the fault long enough to generate a large earthquake (Mw ≥ 6.8) accompanied by surface rupture.     

A study of the groundwater cycle in Sri Lanka using stable isotopes

The characteristics of the groundwater cycle were researched using stable isotope technology in western Sri Lanka where climatic conditions change greatly within a relatively short distance. The effects of local climate, surface water and topography on the groundwater cycle in the study area with similar geological conditions were investigated. Sri Lanka can be divided spatially into a dry zone, an intermediate zone and a wet zone, and also temporally into the rainy season and the dry season. The zonal characteristics of the groundwater cycle were also elucidated using stable isotopic technology. As an input δ diagram of precipitation in the study area, there are obvious seasonal changes in the isotopic composition and a magnitude effect, both in the wet zone and dry zone. In the wet zone, the slope of the regression line between δ D and δ ¹⁸O and deuterium excess is close to 8 and 10, respectively. However, in the dry zone, the slope of the regression line between δ D and δ ¹⁸O and deuterium excess is much less than 8 and 10, respectively. In the wet zone, there is an obvious seasonal change in the isotopic composition of groundwater. The groundwater was recharged by precipitation during the whole year. The isotopically lighter groundwater was found at the valley bottom in the rainy season there. Under the very heavy precipitation conditions, the slope of the regression line between δ D and δ ¹⁸O and deuterium excess for groundwater was close to 8 and 10, respectively. In other cases, the slopes of the regression lines are less than 8. In the dry zone, the groundwater was recharged by precipitation only in the rainy season. The isotopically lighter groundwater was found on the ridge of the valley in the rainy season. The slope of the regression line between δ D and δ ¹⁸O and deuterium excess for groundwater was much less than 8 and 10, respectively. Copyright © 1999 John Wiley & Sons, Ltd.     

Effective strength of saturated double porous media with a Drucker–Prager solid phase

This study aims at determining the macroscopic strength of porous materials having a Drucker–Prager solid phase at microscale and two populations of saturated pores with different pressures at both micro and meso scales. To this end, and taking account of the available results by Maghous et al. (2009), we first derive a closed‐form expression of approximate criterion for a dry porous medium whose matrix obeys to a general elliptic criterion. The methodology to formulate this criterion is based on limit analysis of a hollow sphere subjected to a uniform strain rate boundary conditions. The obtained results are then implemented in a two‐step homogenization procedure, which interestingly delivers analytical expression of the macroscopic criterion for dry double porous media whose solid phase at microscale obeys to a Drucker–Prager criterion. After a brief discussion of the results, we propose an extension to double porous saturated media, allowing therefore to quantify the simultaneous effects of the different pore pressures applied on each voids population. The results are discussed in terms of the existence or not of effective stresses. Finally, they are assessed by comparing them to recently available results. Copyright © 2013 John Wiley & Sons, Ltd.     

Numerical modelling study on the flexural uplift of the Transantarctic Mountains

In this study, based on a 2-D thermomechanical finite element model, the uplift of the Transantarctic Mountains (TAM) is discussed in relation to the flexural uplift of a rheologically layered lithosphere, which is described by Vening-Meinesz's cantilever kinematics. The general model behaviour shows that the thickness of the crust and the geothermal gradient in the lithosphere are the principal factors in controlling the effective elastic thickness ( T _e). Although T _e is also significantly dependent on the magnitude of the uplift and the wet or dry rheological condition of rocks, these two factors do not have a dominant influence on the half-wavelength of the TAM. The model with a plausible crustal structure beneath Antarctica shows that the thermal structure beneath East Antarctica is the critical factor, controlling the half-wavelength of the TAM. If there is a significant radiogenic heat source in the Antarctic lithosphere, T _e beneath East Antarctica is estimated to be 50 km, at most, and the lithosphere has no potential to explain an exceptionally large-scale half-wavelength of the TAM. Even for the model without a heat source, if East Antarctica is significantly thermally influenced by West Antarctica, T _e is estimated to be about 60 km, and it is difficult to reproduce the half-wavelength of the TAM. Contrarily, when a radiogenic heat source is absent and the thermal structure beneath East Antarctica is not significantly affected by that beneath West Antarctica, the rheological structure beneath East Antarctica has the potential to reproduce the half-wavelength of the TAM ( T _e∼ 100 km). Thus, the presence of a radiogenic heat source in the crust and mantle and the thermal influence of West Antarctica on East Antarctica are crucial factors in the reproduction of the half-wavelength found in the TAM.     

Color measurements of volcanic ash deposits from three different styles of summit activity at Sakurajima volcano,Japan: Conduit processes recorded in color of volcanic ash

We measured quantitatively colors of volcanic ash deposits erupted from three different styles of summit activity (Strombolian activity, Vulcanian explosions and continuous ash venting activity) at Sakurajima volcano from 1974 to 1985. Colors of Strombolian ash samples have larger yellow components of their visible spectra (b^? values) than those of explosion and continuous venting ash samples. Colors of explosion ash samples show larger variation in both red and yellow components of their visible spectra (a^? and b^? values, respectively), while colors of continuous venting ash samples are in the narrow ranges within colors of explosion ash samples. Colors of components with lower densities than 3.1 g/cm³ (groundmass and phenocrystic plagioclase) obtained by magnetic and heavy liquid separation methods are similar to the unseparated bulk ash samples. This result suggests that the color variations of ash deposits are mainly originated from the particles composed of groundmass. The particles can be classified into three different types of particles with different vesicularity and crystallinity (vesicular particle [VP], dense particle with vesicles [DPV] and dense particle without vesicles [DP]). Analytical results of component proportions, chemical compositions of groundmass glasses, ferrous iron contents and surface ferric materials show that (1) VP has larger yellow components of the visible spectrum (b^? values) and high ferrous iron content, and is less crystallized than the DP and DPV, (2) DP has larger red and yellow components of its visible spectrum (a^? and b^? values, respectively) and involves ferric materials on the surfaces produced by oxidation process, and (3) DPV has smaller red and yellow components of its visible spectrum (a^? and b^? values, respectively) and involves less ferric materials on the ash surfaces. Color differences of ash deposits from three different activity styles can be explained by the different mixing ratios of VP, DPV and DP. During the Strombolian activity, the VP is a main component in the ash, which is formed from relatively less degassed and crystallized magma. In the Vulcanian explosion and continuous ash venting activity, the proportions of DPV and DP in ash are larger than that in the Strombolian activity. The highly crystallized DP may correspond to a vent cap, and DPV to a magma below the cap. The color measurements of ash deposits provide information on the pre-eruptive processes at the shallower levels of a conduit.