Sound velocity and elastic properties of Fe–Ni and Fe–Ni–C liquids at high pressure

The sound velocity (V _P) of liquid Fe–10 wt% Ni and Fe–10 wt% Ni–4 wt% C up to 6.6 GPa was studied using the ultrasonic pulse-echo method combined with synchrotron X-ray techniques. The obtained V _P of liquid Fe–Ni is insensitive to temperature, whereas that of liquid Fe–Ni–C tends to decrease with increasing temperature. The V _P values of both liquid Fe–Ni and Fe–Ni–C increase with pressure. Alloying with 10 wt% of Ni slightly reduces the V _P of liquid Fe, whereas alloying with C is likely to increase the V _P. However, a difference in V _P between liquid Fe–Ni and Fe–Ni–C becomes to be smaller at higher temperature. By fitting the measured V _P data with the Murnaghan equation of state, the adiabatic bulk modulus (K _S0) and its pressure derivative (K _S ^′ ) were obtained to be K _S0 = 103 GPa and K _S ^′  = 5.7 for liquid Fe–Ni and K _S0 = 110 GPa and K _S ^′  = 7.6 for liquid Fe–Ni–C. The calculated density of liquid Fe–Ni–C using the obtained elastic parameters was consistent with the density values measured directly using the X-ray computed tomography technique. In the relation between the density (ρ) and sound velocity (V _P) at 5 GPa (the lunar core condition), it was found that the effect of alloying Fe with Ni was that ρ increased mildly and V _P decreased, whereas the effect of C dissolution was to decrease ρ but increase V _P. In contrast, alloying with S significantly reduces both ρ and V _P. Therefore, the effects of light elements (C and S) and Ni on the ρ and V _P of liquid Fe are quite different under the lunar core conditions, providing a clue to constrain the light element in the lunar core by comparing with lunar seismic data.     

Field experiments on remediation of coastal sediments using granulated coal ash

Field experiments were carried out to evaluate the effect of Granulated Coal Ash (GCA) on remediation of coastal sediments in terms of removing phosphates and hydrogen sulfide. Phosphate concentrations in the sediment were kept below 0.2 mg/l after the application of GCA, whereas those in the control sites increased up to 1.0 mg/l. The concentration of hydrogen sulfide in the sediment was maintained at almost zero in the experimental sites (GCA application sites) for over one year, whereas it ranged 0.1–2.4 mg S L⁻¹ in control sites. Meanwhile, individual number of benthos increased in the experimental sites by several orders of magnitude compared to the control sites. The major process involved in hydrogen sulfide removal by GCA was thought to be the increase in pH, which suppresses hydrogen sulfide formation. From our findings, we concluded that GCA is an effective material for remediating organically enriched coastal sediment.     

Paleoseismic events and the 1596 Keicho-Fushimi large earthquake produced by a slip on the Gosukebashi fault at the eastern Rokko Mountains,Japan

Field surveys and trench excavation investigations revealed that there were at least four large seismic events produced by slips on the Gosukebashi fault in the Holocene in the southeastern Rokko Mountains of Japan. The characteristics of deformed topographies and three-dimensionally excavated exposures show that this fault is a right-lateral strike–slip fault having an average slip rate of 1.0 mm/year, with a reverse displacement component. The principle indicators of past faulting events are: (i) termination of secondary faults; (ii) sedimentary deposits related to faulting; and (iii) injection veins of fault gouge related to seismic faulting in the fractured zone. Radiocarbon dates indicate that the events occurred pre-1660 BC , 1660 BC –220 AD , from ～ 30–220 to 600 AD and 15th century AD . The youngest event is probably associated with the large 1596 AD Keicho-Fushimi earthquake which occurred in the area around Kyoto and Kobe Cities. The second younger event is probably correlated with the 416 AD Yamato earthquake, which is the oldest historic earthquake in Japanese historic records. The results of trench surveys show that the horizontal displacement produced by an individual event is ～ 1.5 m, and the recurrence of seismic event intervals is ～ 1200 years in the Gosukebashi fault.     

Trace element concentrations in silicate spherules from oceanic sediments

The possible existence of meteoritic spherules was investigated among several silicate spherules separated from oceanic sediments and analyzed by means of INAA (instrumental neutron activation analysis).A 0.72 mg glassy spherule was found to have uniform enrichment of 4 ~ 5 for the refractory REE (rare earth elements) and Sc with substantial depletion of Ce relative to chondritic abundances. This implies that this spherule is meteoritic in origin and that the enrichment of refractory elements was established by high temperature heating in a high O/H environment, possibly at the time of entering the Earth's atmosphere.The other three analyzed spherules showed major and trace element abundances that are consistent with an origin in the oceanic environment.     

Equation of state of iron–silicon alloys to megabar pressure

The stability and pressure–volume equation of state of iron–silicon alloys, Fe-8.7 wt% Si and Fe-17.8 wt% Si, have been investigated using diamond-anvil cell techniques up to 196 and 124 GPa, respectively. Angular–dispersive X-ray diffractions of iron–silicon alloys were measured at room temperature using monochromatic synchrotron radiation and an imaging plate (IP). A bcc–Fe-8.7 wt% Si transformed to hcp structure at around 1636 GPa. The high-pressure phase of Fe-8.7 wt% Si with hexagonal close-packed (hcp) structure was found to be stable up to 196 GPa and no phase transition of bcc–Fe-17.8 wt% Si was observed up to 124 GPa. The pressure–volume data were fitted to a third-order Birch–Murnaghan equation of state (BM EOS) with zero–pressure parameters: V₀=22.2(8) ų, K₀=198(9) GPa, and K₀=4.7(3) for hcp–Fe-8.7 wt% Si and V₀=179.41(45) ų, K₀=207(15) GPa and K₀=5.1(6) for Fe-17.8 wt% Si. The density and bulk sound velocity of hcp–Fe-8.7 wt% Si indicate that the inner core could contain 3–5 wt% Si.     

Significance of stemflow in groundwater recharge. 2: A cylindrical infiltration model for evaluating the stemflow contribution to groundwater recharge

A primary model for evaluating the effect of stemflow on groundwater recharge has been developed. The model, a cylindrical infiltration model (CI model), is based on the infiltration area of stemflow-induced water instead of canopy projected area for determining the stemflow inputs to the soil surface. The estimated ratio of recharge rate by stemflow to the total recharge rate determined with this model agrees closely with values obtained from the mass balance of chloride in subsurface waters. This primary model is considered to be useful for estimating the effect of stemflow on groundwater recharge.     

Sensitive high-resolution ion microprobe U-Pb ages of the Latest Oligocene-Early Miocene rift-related Hidaka high-temperature metamorphism in Hokkaido, northern Japan

Abstract   In order to define the timing of granulite facies metamorphism, sensitive high-resolution ion microprobe (SHRIMP) U-Pb analyses were performed on zircons of three pelitic granulites from the lower metamorphic sequence of the Hidaka Metamorphic Belt, southern central Hokkaido, Japan. Both rounded and prismatic zircons were found in the granulite samples. The rounded zircons had thin (10–20 µm) concentric overgrowth rims on detrital cores, while the prismatic zircons did not have detrital cores. Both the overgrowth rims on the rounded zircons and the entire prismatic zircons were formed under granulite facies metamorphism and consistently yield Latest Oligocene–Early Miocene ages (23.7 ± 0.4 Ma to 17.2 ± 0.5 Ma; ²⁰⁶Pb/ ²³⁸U ages ( n  = 31) with low Th/U ratios, mostly <0.1). The internal structure of zircons and their SHRIMP U-Pb ages provide strong evidence in support of the granulite facies event occurring during the Latest Oligocene-Early Miocene. The detrital cores of rounded zircons show a huge variety of ages; Mesoarchean to Paleoproterozoic, Paleozoic to Mesozoic and Paleogene. The interior and marginal portions of the Eurasian continent including cratonic areas are suggested for their source provenances. These wide variations in age suggest that the protolith of the granulites of the lower metamorphic sequence were deposited near the trench of the Eurasian continental margin during Paleogene. The protolith of the lower metamorphic sequence of the Hidaka metamorphic belt was thrust under the upper metamorphic sequence, which had already been metamorphosed in early Paleogene. The Latest Oligocene-Early Miocene Hidaka high-temperature metamorphic event is presumed to have been caused by asthenospheric upwelling during back-arc rifting of the Kuril and Japan basins.     

Tsunami Assessment for Risk Management at Nuclear Power Facilities in Japan

The present study focuses on evaluation of the maximum and minimum water levels caused by tsunamis as risk factors for operation and management at nuclear power facilities along the coastal area of Japan. Tsunamis generated by submarine earthquakes are examined, basing literature reviews and databases of information on historical tsunami events and run-up heights. For simulation of water level along the coast, a numerical calculation system should be designed with computational regions covering a particular site. Also the calculation system should be verified by comparison of historical and calculated tsunami heights. At the beginning of the tsunami assessment, the standard faults, their locations, mechanisms and maximum magnitudes should be carefully estimated by considering historical earthquake-induced tsunamis and seismo-tectonics at each area. Secondly, the range of errors in the model parameters should be considered since earthquakes and tsunamis are natural phenomena that involve natural variability as well as errors in estimating parameters. For these reasons, uncertainty-induced errors should be taken into account in the process of tsunami assessment with parametric study of the tsunami source model. The element tsunamis calculated by the standard fault models with the errors would be given for the design. Then, the design tsunami can be selected among the element tsunamis with the most significant impact, maximum and minimum water levels, on the site, bearing in mind the possible errors in the numerical calculation system. Finally, the design tsunami is verified by comparison with the run-up heights of historical tsunamis, ensuring that the design tsunami is selected as the highest of all historical and possible future tsunamis at the site.     

Dynamical classification of trans-neptunian objects: Probing their origin, evolution, and interrelation

The orbital structure of trans-neptunian objects (TNOs) in the trans-neptunian belt (Edgeworth-Kuiper belt) and scattered disk provides important clues to understand the origin and evolution of the Solar System. To better characterize these populations, we performed computer simulations of currently observed objects using long-arc orbits and several thousands of clones. Our preliminary analysis identified 622 TNOs, and 65 non-resonant objects whose orbits penetrate that of at least one of the giant planets within 1 Myr (the centaurs). In addition, we identified 196 TNOs locked in resonances with Neptune, which, sorted by distance from the Sun, are 1:1 (Neptune trojans), 5:4, 4:3, 11:8, 3:2, 18:11, 5:3, 12:7, 19:11, 7:4, 9:5, 11:6, 2:1, 9:4, 16:7, 7:3, 12:5, 5:2, 8:3, 3:1, 4:1, 11:2, and 27:4. Kozai resonant TNOs are found inside the 3:2, 5:3, 7:4, and 2:1 resonances. We present detailed general features for the resonant populations (i.e., libration amplitude angles, libration centers, Kozai libration amplitudes, etc.). Taking together the simulations of Lykawka and Mukai [Lykawka, P.S., Mukai, T., 2007. Icarus 186, 331-341], an improved classification scheme is presented revealing five main classes: centaurs, resonant, scattered, detached and classical TNOs. Scattered and detached TNOs (non-resonant) have q (perihelion distance) <37 AU and q>40 AU, respectively. TNOs with 37 AU<q<40 AU occupy an intermediate region where both classes coexist. Thus, there are no clear boundaries between the scattered and detached regions. We also securely identified a total of 9 detached TNOs by using 4-5 Gyr orbital integrations. Classical objects are non-resonant TNOs usually divided into cold and hot populations. Their boundaries are as follows: cold classical TNOs (i?5°) are located at 37 AU<a<40 AU (q>37 AU) and 42 AU<a<47.5 AU (q>38 AU), and hot classical TNOs (i>5°) occupy orbits with 37 AU<a<47.5 AU (q>37 AU). However, a more firm classification is found with i>10° for hot classical TNOs. Lastly, we discuss some implications of our classification scheme comparing all TNOs with our model and other past models.