Hydration-dehydration interactions between glycine and anhydrous salts: Implications for a chemical evolution of life

Polymerizations of organic monomers including amino acids, nucleotides and monosaccharides are essential processes for chemical evolution of life. Since these reactions proceed with “dehydration” reactions, they are possibly promoted if combined with thermodynamically favorable “hydration” reactions of minerals and salts. To test the possibility, we conducted heating experiments of the simplest amino acid “glycine (Gly)” mixed with four simple anhydrous salts (MgSO₄, SrCl₂, BaCl₂ and Li₂SO₄) at 140 °C up to 20 days. Gly polymerization was strongly promoted by mixing with the salts in the order of MgSO₄ > SrCl₂ > BaCl₂ > Li₂SO₄. Up to 6-mer of Gly polymers were synthesized in the Gly-MgSO₄ mixture, and a total yield of Gly polymers attained about 7% of the initial amount of Gly by the 20 days heating. The total yield was about 200 times larger than that from the heating of Gly alone. XRD measurements of the Gly-MgSO₄ mixture revealed the generation of MgSO₄ monohydrate during Gly polymerization. These observations indicate that Gly polymerization was promoted by the salt hydrations through the hydration-dehydration interactions. Based on the observations, we tried to find a relationship between thermodynamic characteristics of the interactions and the promotion effects of each salt on Gly polymerization. It was found that the salts having lower hydration Δ_rG⁰ (easier to hydrate) promote Gly polymerization more strongly. The relationship was used to estimate promotion effects of simple oxide minerals on Gly polymerization. The estimations were consistent with previous observations about the effects of these minerals on Gly polymerization. The fact suggests that the hydration-dehydration interactions between amino acids and minerals are an important mechanism for amino acids’ polymerizations on minerals.     

焉耆盆地活动构造的遥感图像特征

焉耆盆地是一个位于天山东南部的山间盆地 ,在遥感图像上 ,可以看到盆地西面的活动构造在地表留下的痕迹 :清楚的线形构造 ,被错开的水系、冲沟等。经分析认为 ,这些活动构造主要由北边的活动褶皱和南边的右行走滑活动断裂组成。野外的实际调查与图像分析的结果十分吻合 ,表明遥感图像在研究活动构造方面是一个十分有力和快速的工具。活动断层的最大水平位移为 2 10m ,最大垂直位移为 2 0m ,主要以走滑作用为主。天山地区活动构造的发育表明印度板块向欧亚板块的碰撞仍在持续     

Spectral analysis of four quiescent prominences observed at the Peruvian eclipse

Two-dimensional distributions of kinetic temperature, density and turbulent velocity are obtained for four quiescent prominences observed at the Peruvian eclipse of 12 November, 1966.

1. The kinetic temperature derived from line widths is around 6000–7000 K in the central part of prominences and rises to 12000K in both edges and possibly in the top of prominences.
2. The turbulent velocity shows a similar tendency, being 7–9 km/sec in the central part and ≈ 20 km/sec in the outer part. The turbulent velocity also increases slowly towards higher heights in the prominence.
3. The electron density derived both from the Stark effect and the intensity ratio of the continuous spectra turns out to be about 10^10.2–10^10.6 cm^?3 in the central portion of two prominences.
4. From the width and the intensity, neutral helium lines are shown to originate in the same region as hydrogen and metallic lines where the kinetic temperature goes down to 6000 K. This indicates that neutral helium is emitted after the ionization due to UV radiation from the corona and the transition region.

     

Seismotectonics and tectonic history of the andaman sea

The Andaman Sea is considered as an actively spreading back-arc basin. Seismicity and newly determined focal-mechanism solutions in the Andaman Sea area support this view. The tectonic history of the region is inferred from magnetic lineations in the northeastern Indian Ocean and the northward motion of Greater India. The mid-oceanic ridge which migrated northward along the east side of the Ninetyeast Ridge collided with the western end of the “old Sunda Trench” in the Middle or Late Miocene (10–20 m.y. B.P.). This ridge—trench collision released much of the compressional stress in the back-arc area and the continued northward movement of India that collided with Eurasia exerted a drag on the back-arc region, causing the opening of the Andaman Sea. In appearance, the subducted ridge jumped to the back-arc area. Thus, the Andaman Sea is not an ordinary subduction-related back-arc basin, but probably a basin formed by oblique extensional rifting associated with both ridge subduction and deformation of the back-arc area caused by a nearby continental collision.     

Late Quaternary activity and dextral strike-slip movement on the Karakax Fault Zone, northwest Tibet

Field observations and interpretations of satellite images reveal that the westernmost segment of the Altyn Tagh Fault (called Karakax Fault Zone) striking WNW located in the northwestern margin of the Tibetan Plateau has distinctive geomorphic and tectonic features indicative of right-lateral strike-slip fault in the Late Quaternary. South-flowing gullies and N–S-trending ridges are systematically deflected and offset by up to ~ 1250 m, and Late Pleistocene–Holocene alluvial fans and small gullies that incise south-sloping fans record dextral offset up to ~ 150 m along the fault zone. Fault scarps developed on alluvial fans vary in height from 1 to 24 m. Riedel composite fabrics of foliated cataclastic rocks including cataclasite and fault gouge developed in the shear zone indicate a principal right-lateral shear sense with a thrust component. Based on offset Late Quaternary alluvial fans, ¹⁴C ages and composite fabrics of cataclastic fault rocks, it is inferred that the average right-lateral strike-slip rate along the Karakax Fault Zone is ~ 9 mm/a in the Late Quaternary, with a vertical component of ~ 2 mm/a, and that a M 7.5 morphogenic earthquake occurred along this fault in 1902. We suggest that right-lateral slip in the Late Quaternary along the WNW-trending Karakax Fault Zone is caused by escape tectonics that accommodate north–south shortening of the western Tibetan Plateau due to ongoing northward penetration of the Indian plate into the Eurasian plate.     

Comparison of extractability of Cd, Cu, Pb and Zn with sequential extraction in contaminated and non-contaminated soils

Various extraction procedures were employed for measuring extractable concentrations of potential toxic elements in soil. The extractability of Cd, Cu, Pb and Zn in four contaminated and four non-contaminated soils of Japan, was compared by single extraction (CaCl₂, DTPA, NH₄Cl, 0.1 M HCl and 1 M HCl ) and sequential extraction procedures [(six operationally defined chemical phases, viz. water soluble (Fl), exchangeable (F2), carbonate (F3), oxide (F4), organic (F5) and residual (F6) fractions)]. Extractability of metals from soils samples varied depending on metals and/or extradants used. Among the extradants, 1 M HCl extracted the largest proportion of Cd (79 to 96% of total), Cu (61 to 83%), Pb (51 to 99%) and Zn (23 to 52%) from soils followed by 0.1 M HCl, NH₄Cl, DTPA and CaCl₂. In all the extradants, the proportion of extractability of metals was higher in the contaminated soils than the non-contaminated soils. Regardless of soils and extradants, relative extractability was higher for Cd as compared to other three metals. The use of 1 M HCl may be recommended for first-level screening of soil contamination with heavy metals. The other four weak extradants are believed to provide a better assessment of bioavailable/mobile metals content in soils than 1 M HCl extradant. However, 0.1 M HCl mobilized all four metals irrespective of soil types, therefore, might be the best choice if only one extradant is to be used. The sequential extraction procedures showed 22 to 64% of total Cd was in the mobile fraction (sum of Fl to F3), while the corresponding values for Cu, Pb and Zn in this fractions were 2 to 23% suggesting higher mobility of Cd than other three metals. The single extraction procedures are simple and easy to perform and obtained results are comparable with sequential extraction procedure.     

Estrogen equivalent concentration of individual isomer-specific 4-nonylphenol in Ariake sea water, Japan

Concentrations of 4-nonylphenol (NP) were determined by isomer-specific quantification of individual NP isomers based on relative response factor (RRF) quantification with GC–MS in combination with steam distillation extraction. Concentrations of NP in the Ariake Sea decreased with distance from the river mouth (St.A; 49 ng NP/l) to offshore areas (St.C; 11 ng NP/l). Even the least concentration in water from St.C in Ariake Sea was sufficient to have adverse effects on barnacles. The isomers, NP1–NP14 were separated by GC–PFC and identified structurally with NMR. The isomers varied in estrogenic activity with NP7 exhibiting the greatest estrogenic activity with a potency that was approximately 1.9 × 10⁻³ that of 17β-estradiol (E2) in recombinant yeast screen system. The coefficient of variation (CV) of NP isomer’s concentrations among three samples at St.A, B and C were 4–75%. This suggests that NP isomers might be independently degraded in aquatic environmental samples. The predicted estrogenic activity of measured concentrations of NP in Ariake Sea was 2.7–3.0-fold greater than the measured estrogen agonist activity.     

Numerical study on the bulk heat transfer coefficient for a variety of vegetation types and densities

The relationship between the geometrical structure of a canopy layer and the bulk transfer coefficient was investigated using a numerical canopy model. The following results were obtained:

1. The bulk transfer coefficients for momentum and heat, C _M and C _H , change with non-dimensional canopy density C _* each has a maximum.
2. The value of C _M is always larger than the value of C _H for a canopy with c _m > c _h , c _m and c _h being the drag coefficient and the heat transfer coefficient of an individual canopy element, respectively.
3. The value of C _* at which C _H has its maximum value is larger than the value of C _* at which C _M has its maximum. Therefore, the reciprocal of the sublayer Stanton number b _h ^?1 ranges between 50 and 65 for C _* around 0.1 while it ranges between 0 and 30 for C _* < 10^?2 and C _* > 2 (when c _m = 0.5).
4. The value of B _H ^?1 in the present study is consistent with most available observations, except for canopies of medium density (when C _* is around 0.1) for which no observational value has been obtained.

     

Infrared properties of haze particles of Venus

The computed variation of the infrared flux and polarization of Venus as a function of phase angle, based upon multiple-scattering calculations for the cloud model of Kawabata et al. (1980) with an internal heat source, precludes the possibility of sulfuric acid as the composition of the haze particles located above the main cloud. Furthermore, our calculations reveal that the hazticle should have a large absorption coefficient at these wavelengths, i.e, $\text{k(}\text{imaginary part of the complex refractive index}\text{) ? 1.3}\text{at a wavelength}\text{λ = 3.4 μ}\text{m}$. The optical thickness of the haze layer must be about 0.15 at λ = 3.4 μm.     

The Influence Of Urban Canopy Configuration On Urban Albedo

We propose a calculation method for shortwave radiation flux and longwave radiation flux within the urban canopy and investigate the influence of urban canopy configuration on net radiation flux. In the assumed urban configuration, buildings of equal size are arranged in a regular lattice within the urban canopy. The net shortwave radiation flux and longwave radiation flux within the urban canopy were calculated by the photon tracking method based on the Monte Carlo method. The albedo value obtained by this method shows close agreement with experimental data, and the average sky view factor shows almost perfect agreement with the theoretical value. Moreover, we calculated the urban albedo for the urban canopy configuration including roads and building height distribution.%Moreover, we calculated net radiation within the urban canopy in %consideration of roads and building height distribution.We found that the sky view factor of the ground surface is high when building coverage is low, building height is low, open space by roads exists, and building height is non-uniform. Moreover, we found that the albedo value is high when building height is small, open space by roads is wide, and building height is uniform. The albedo value was found to vary in a complicated manner with change in building coverage.