Estrogen equivalent concentration of individual isomer-specific 4-nonylphenol in Ariake sea water, Japan

Concentrations of 4-nonylphenol (NP) were determined by isomer-specific quantification of individual NP isomers based on relative response factor (RRF) quantification with GC–MS in combination with steam distillation extraction. Concentrations of NP in the Ariake Sea decreased with distance from the river mouth (St.A; 49 ng NP/l) to offshore areas (St.C; 11 ng NP/l). Even the least concentration in water from St.C in Ariake Sea was sufficient to have adverse effects on barnacles. The isomers, NP1–NP14 were separated by GC–PFC and identified structurally with NMR. The isomers varied in estrogenic activity with NP7 exhibiting the greatest estrogenic activity with a potency that was approximately 1.9 × 10⁻³ that of 17β-estradiol (E2) in recombinant yeast screen system. The coefficient of variation (CV) of NP isomer’s concentrations among three samples at St.A, B and C were 4–75%. This suggests that NP isomers might be independently degraded in aquatic environmental samples. The predicted estrogenic activity of measured concentrations of NP in Ariake Sea was 2.7–3.0-fold greater than the measured estrogen agonist activity.     

Iron-water reaction at high pressure and temperature, and hydrogen transport into the core

We observed a direct reaction of metallic iron with water to form iron hydride and iron oxide, 3Fe + H₂O–>2FeH_x + FeO, at pressures from 6 GPa to 84 GPa and temperatures above 1,000 K in diamond anvil cell (DAC). Iron hydride is dhcpFeH_x or -FeH_x, and iron oxide has the rhombohedral or B1 structure at pressures at least up to 37 GPa. The formation of an assembly composed of dhcpFeH_x and FeO with the B8 structure was observed at 84 GPa. In primordial Earth, water formed by dehydration of the low temperature primitive materials reacts with metallic iron in the high temperature component to form iron hydride FeH_x and iron oxide FeO. The former would be incorporated in the iron forming the core. Thus hydrogen could be an important element of the Earths core. This reaction would be essential for transport of hydrogen into the core in the accretion stage of the Earth.     

Reappearance of ordered motions in strongly nonlinear Hamiltonian systems

A strongly nonlinear Hamiltonian system which occurs in Celestial Mechanics is studied by the method of surface of section. The reappearance of ordered motions is observed and the numerical experiments suggest that this phenomenon could be predicted by the criterion of interaction of resonances.     

Infrared properties of haze particles of Venus

The computed variation of the infrared flux and polarization of Venus as a function of phase angle, based upon multiple-scattering calculations for the cloud model of Kawabata et al. (1980) with an internal heat source, precludes the possibility of sulfuric acid as the composition of the haze particles located above the main cloud. Furthermore, our calculations reveal that the hazticle should have a large absorption coefficient at these wavelengths, i.e, $\text{k(}\text{imaginary part of the complex refractive index}\text{) ? 1.3}\text{at a wavelength}\text{λ = 3.4 μ}\text{m}$. The optical thickness of the haze layer must be about 0.15 at λ = 3.4 μm.     

Propagation of seismic slip from brittle to ductile crust: Evidence from pseudotachylyte of the Woodroffe thrust, central Australia

The Woodroffe thrust, central Australia, is a > 1.5-km-wide mylonitized shear zone marked by large volumes of mm- to cm-scale pseudotachylyte veins. The pseudotachylytes display typical melt-origin features, including rounded and embayed clasts, spherulitic and dentritic microlites, and flow structures within a fine-grained matrix. Three types of pseudotachylyte are identified on the basis of deformation texture, vein morphology, and host-rock lithology: cataclasite-related (C-Pt), mylonite-related (M-Pt), and ultramylonite-related (Um-Pt). The M-Pt and Um-Pt veins intrude into mylonite and ultramylonite and are themselves overprinted by subsequent mylonitization. These pseudotachylytes contain an internal foliation defined by flattened porphyroclasts and layering of the fine-grained vein matrix, and the foliation is generally oriented parallel to foliation in the surrounding mylonite and ultramylonite. These observations constrain the timing and environment of M-Pt and Um-Pt pseudotachylyte formation to a protracted period of deformation and mylonitization within the ductile regime of the crust. The M-Pt and Um-Pt veins, as well as the host mylonite, are overprinted by cataclasis and multiple generations of late-stage C-Pt veins that were generated in the brittle-dominated regime of the upper crust during uplift and exhumation of the shear zone.The coexistence of multiple generations of voluminous C-Pt, M-Pt, and Um-Pt veins indicates that the pseudotachylyte veins represent a large number of large earthquakes and accompanying seismic slip over an extended period of seismicity on the Woodroffe thrust. The timing and distribution of pseudotachylyte indicate that the earthquakes nucleated at the base of the brittle-dominated seismogenic zone and propagated down through the brittle–ductile transition into the ductile-dominated regime of the crust.     

Characterization of a landslide-triggered debris flow at a rainforest-covered mountain region in Brazil

Natural Hazards - Debris flows represent great hazard to humans due to their high destructive power. Understanding their hydrogeomorphic dynamics is fundamental in hazard assessment studies,...     

Impact of climate and land-use changes on hydrological processes and sediment yield—a case study of the Be River catchment,Vietnam

Abstract

The impact of climate and land-use changes on hydrological processes and sediment yield is investigated in the Be River catchment, Vietnam, using the Soil and Water Assessment Tool (SWAT) hydrological model. The sensitivity analysis, model calibration and validation indicated that the SWAT model could reasonably simulate the hydrology and sediment yield in the catchment. From this, the responses of the hydrology and sediment to climate change and land-use changes were considered. The results indicate that deforestation had increased the annual flow (by 1.2%) and sediment load (by 11.3%), and that climate change had also significantly increased the annual streamflow (by 26.3%) and sediment load (by 31.7%). Under the impact of coupled climate and land-use changes, the annual streamflow and sediment load increased by 28.0% and 46.4%, respectively. In general, during the 1978–2000 period, climate change influenced the hydrological processes in the Be River catchment more strongly than the land-use change.

Editor Z.W. Kundzewicz; Associate editor Q. Zhang

Citation Khoi, D.N. and Suetsugi, T., 2014. Impact of climate and land-use changes on hydrological processes and sediment yield—a case study of the Be River catchment, Vietnam. Hydrological Sciences Journal, 59 (5), 1095–1108.