Simulation of nitrate transport and wastewater seepage in groundwater flow system

Groundwater quantity and quality modeling is one approach for optimal use of available water resources in arid and semiarid regions. This study was conducted to simulate flow treatment and nitrate transport on Shahrekord aquifer using three-dimensional solute transport model and geographical information system. Hydraulic conductivity, specific yield and recharge values in flow simulation process and effect molecular diffusion coefficient, longitudinal dispersivity and distribution coefficient in quality model were calibrated. 120 water samples during July 2007 to June 2008 were collected monthly from 10 wells and measurements of nitrate were carried out. The results show that the developed model is successfully used to simulate flow path and nitrate transport in saturated porous media. The highest values of nitrate occur along Bahram–Abad village and the surroundings. The groundwater quality in the area represents a complex system, which is affected by different factors of pollution, such as urban wastewater and leaching of agricultural lands.     

Utilization of Silica Fume to Maximize the Filler and Pozzolanic Effects of Stabilized Soil with Cement

Silica fume is identified as a pozzolan and supplementary cementitious material that can utilize to improve the mechanical properties of stabilized soil with cement. Silica fume wherein mixes with cemented soil in a proper dosage, it is susceptible to induce pozzolanic effect in cemented soil due to its fineness and high content of SiO₂ and Al₂O₃. The pozzolanic effect is vital to ensure ongoing strength of stabilized soil with cement. Up to now, stabilization of clay with cement and silica fume is not completely explored. This paper investigates: (i) the capability of utilizing the silica fume as a supplementary material for cement to maximize the filler and pozzolanic effects of compacted and stabilized soil (ii) the mechanical properties of compacted and stabilized clay with various proportions of cement and silica fume. For this purpose, a total of 120 untreated and stabilized soil admixtures were prepared by replacing ordinary Portland cement with silica fume. The influence of partial replacement of cement with silica fume on the bearing capacity, shear and compressive strength of compacted and stabilized soil was investigated. To achieve such aims, the stabilized soil specimens were examined in laboratory under direct shear, unconfined compression and California bearing ratio tests. Based on the findings of this paper the 28-day UCS of the stabilized soil with 2% partial substitution of cement with silica fume is almost 3.5-fold greater than that of the untreated. It was found that the optimum mix design for the stabilized soil is 6% cement and 2% silica fume. In conclusion, a notable discovery is that the partial substitution of cement with 2% silica fume in the optimum mix design significantly refined the pore spaces as a result of pozzolanic activity and filler effect of silica fume.     

Evaluation of ANFIS and LR models for seismic rockfalls’ susceptibility mapping: a case study of Firooz Abad-Kojour,Iran, Earthquake (2004)

Seismic rockfall is one of the prevalent geohazards that cause huge losses in the earthquake-stricken areas. In the present research, a model is developed to map susceptibility (occurrence probability) of seismic rockfalls in a regional scale using Logistic Regression (LR) and Adaptive Neuro-Fuzzy Inference System (ANFIS) techniques. In this research, Firooz Abad-Kojour earthquake of 2004 was introduced as the benchmark and the model base. The susceptible zones predicted by LR and ANFIS methods were compared with the database (distribution map) of seismic rockfalls, by which the results revealed a good overlapping between the susceptible zones predicted by the ANFIS and the field observation of rockfalls triggered by this earthquake. Besides, for the statistical evaluation of results obtained by LR and ANFIS models, the verification parameters with high accuracy such as density ratio (Dr), quality sum (Qs), and receiver-operating characteristic curve (ROC) were used. By analyzing the susceptibility maps and considering the Qs index obtained by LR (21.04184) and ANFIS (26.75592), it could be found that the Qs of ANFIS is higher than that of LR. Moreover, based on the obtained value of the area under the curve (AUC) from LR (0.972) and ANFIS (0.984) methods, ANFIS provided a higher accuracy in zonation and susceptibility mapping of rockfalls triggered by Firooz Abad-Kojour earthquake of 2004 compared to the LR method.     

In-depth investigation of precipitation-based climate change and cyclic variation in different climatic zones

Climate change and cyclic variation are investigated based on station data of 61 years (1951–2011), representing twelve climatic zones in Iran. Climate change is investigated by applying the non-parametric Mann–Kendall test and the three-dimensional loglinear model to the12-month SPI time series, and by applying the likelihood ratio test to precipitation time series. Cyclic variation is studied by applying the three-dimensional loglinear model to the 12-month SPI time series. Analysis included entire data period, two sub-periods [(1951–1981), (1982–2011)] and three sub-periods [(1951–1971), (1972–1991), (1992–2011)]. The Mann–Kendall test results indicated combinations of different trend behaviors, whereby climate change could not be evaluated. The likelihood ratio test did not confirm climate change (at 95 % confidence level), in most of the studied stations. However, the more in-depth analysis by the three-dimensional loglinear model, i.e., detection of significant differences among drought frequencies, did not confirm climate change (at 95 % confidence level), in any of the studied stations. Cyclic variation was not confirmed by the three-dimensional loglinear model (at 95 % confidence level), in any of the studied stations. The findings of this research illustrate the need for meticulous techniques like the three-dimensional loglinear model, as a necessary tool for climate change and cyclic variation studies.     

Soil organic carbon stock as affected by land use/cover changes in the humid region of northern Iran

This study was conducted to determine the changes in the soil carbon stocks as influenced by land use in a humid zone of Deylaman district(10,876 ha), a mountainous region of northern Iran. For this, land use maps were produced from TM and ETM+ images for 1985, 2000 and 2010 years; and this was supplemented by field measurement of soil carbon in 2010. The results showed that the mean soil organic carbon(SOC) density was 6.7±1.8 kg C m-2, 5.2±3.4 kg C m-2 and 3.2±1.8 kg C m-2 for 0-20 cm soil layer and 4.8±1.9 kg C m-2, 3.1±2 kg C m-2 and 2.7±1.8 kg C m-2 for 20-40 cm soil layer in forest, rangeland and cultivated land, respectively. During the past 25 years, 14.4% of the forest area had been converted to rangeland; and 28.4% of rangelands had been converted to cultivated land. According to the historical land use changes in the study area, the highest loss of SOC stocks resulted from the conversion of the forest to rangeland(0.45×104 Mg C in 0-40 cm depth layer); and the conversion of rangeland to cultivated land(0.37×104 Mg C in 0-40 cm), which typically led to the loss of soil carbon in the area studied. The knowledge on the historical land use changes and its influence on overall SOC stocks could be helpful for making management decision for farmers and policy managers in the future, for enhancing the potential of C sequestration in northern Iran.     

Seismic assessment of concrete gravity dams using capacity estimation and damage indexes

A new concept to determine state of the damage in concrete gravity dams is introduced. The Pine Flat concrete gravity dam has been selected for the purpose of the analysis and its structural capacity, assuming no sliding plane and rigid foundation, has been estimated using the two well‐known methods: nonlinear static pushover (SPO) and incremental dynamic analysis (IDA). With the use of these two methods, performance and various limit states of the dam have been determined, and three damage indexes have been proposed on the basis of the comparison of seismic demands and the dam's capacity. It is concluded that the SPO and IDA can be effectively used to develop indexes for seismic performance evaluation and damage assessment of concrete gravity dams. Copyright © 2012 John Wiley & Sons, Ltd.     

Application of inverse geochemical modelling for predicting surface water chemistry in Ekbatan watershed,Hamedan, western Iran

ABSTRACT

A study of surface water chemistry evolution was conducted by multivariate statistical analysis and inverse geochemical modelling using the PHREEQC computer program. Using hierarchical cluster analysis the 14 sampling sites were classified into three groups (recharge, transition and discharge areas). Water chemistry changed along a flow path so that waters with Ca–HCO₃ and Mg–Cl composition changed to Mg–Cl–HCO₃ waters. The order of abundance of the major cations was Mg > Ca > Na > K. Their average concentrations were 21, 19, 3.6 and 2.5 mg L^-1, respectively. Inverse geochemical modelling along flow paths indicated that the dissolution of sylvite and kaolinite, and precipitation of feldspars and andalusite, happened with Na entering the solution and Ca, Mg and K leaving the solution.

Editor D. Koutsoyiannis; Associate editor not assigned     

Metamorphism and deformation of golpayegan metapelitic rocks, Sanandaj-Sirjan Zone, Iran

The metapelitic schists of the Golpayegan region can be divided into four groups based on their mineral assemblages: (1) garnet-chloritoid schists, (2) garnet schists, (3) garnet-staurolite schists, and (4) staurolite-kyanite schists. Paleozoic pelagic shales experienced progressive metamorphism and polymetamorphism from greenschist to amphibolite facies along the kyanite geotherm. Mylonitic granites are concentrated in the central part of the region more than in other areas, and formed during the dynamic metamorphic phase by activity on the NW-SE striking Varzaneh and Sfajerd faults. The presence of chloritoid in the metapelites demonstrates low-grade metamorphism in the greenschist facies. The textural and chemical zoning of garnets shows three stages of growth and syntectonic formation. With ongoing metamorphism, staurolite appeared, and the rocks reached amphibolite facies, but the degree of metamorphism did not increase past the kyanite zone. Thus, metamorphism of the pelitic sediments occurred at greenschist to lower amphibolite facies. Thermodynamic studies of these rocks indicate that the metapelites in the north Golpayegan region formed at 511?C618°C and 0.24?C4.1 kbar.