Measuring and adjusting the weathering and hydraulic sorting effects for rigorous provenance analysis of sedimentary rocks: a case study from the Jurassic Ashikita Group,south‐west Japan

The present study examines the provenance of the Jurassic Ashikita Group distributed in south‐west Japan, which is composed of the Idenohana, Kyodomari and Sakamoto Formations. Two geochemical diagrams for provenance analysis were utilized, which incorporate full consideration of compositional modifications resulting from weathering (MFW diagram) and hydraulic sorting processes (SiO₂/Al₂O₃–Na₂O/K₂O diagram). The MFW diagram delineates weathering trends of sedimentary rocks and allows estimation of the original source rock composition by tracing the weathering trends backwards to an unweathered domain. Weathering trends of the Idenohana and Kyodomari Formations extend backward to the domain of intermediate and felsic igneous rocks. In contrast, sediments of the Sakamoto Formation do not fit into a linear weathering trend, indicating that the source rock cannot be approximated to igneous rocks. On the SiO₂/Al₂O₃–Na₂O/K₂O diagram, sediments are organized into compositional trends, in which the range reflects compositional variations induced by the hydraulic sorting effect. On this diagram, sediments derived from the igneous and recycled sedimentary provenances can be distinguished by reading the inclination of the trend. By utilizing this principle, source rocks of the Idenohana and Kyodomari Formations are interpreted as igneous rocks and those of the Sakamoto Formation are interpreted as recycled sedimentary rocks. Therefore, these diagrams concurrently estimate the source rock composition through quantifying and adjusting the weathering and sorting effects, and reveal a systematic transition in the provenance of the Ashikita Group. The Idenohana and Kyodomari Formations were supplied chiefly from an igneous provenance, which shifted from intermediate to felsic compositions in stratigraphic order. Whereas, sediments of the Sakamoto Formation were sourced primarily from a recycled sedimentary provenance.     

Additional Rb-Sr and single-grain zircon datings of Caledonian granitoid rocks from Albert I Land, northwest Spitsbergen

Previous K-Ar and Rb-Sr datings of the metamorphic and granitic rocks from the northwestern basement region of Spitsbergen mainly show the cooling time of the rocks, except for a Rb-Sr isochron age of the Hornemantoppen granitoid. New samples were collected during several years of geological mapping in the area and the Rb-Sr whole rock isochron and single-grain zircon evaporation methods were applied to the Hornemantoppen granitoids and the grey granites. A dioritic dyke was also dated by the latter method. The bulk rock chemistry study shows that most of both granitic rocks are of the S-type and probably post orogenic, with distinctive incorporation of crustal materials. The isotopic data also support this interpretation. The results of the Rb-Sr isotope analyses, 412 ± 4.8 Ma and the zircon Pb evaporation age of 424 ± 56 Ma, confirm the previous age of the Hornemantoppen granitoid, 414 ± 10 Ma. An older zircon age of 547 ± 19 Ma is considered to be the minimum age of inherited zircon. Zircons from the grey granites suggest an age of ca. 420 Ma with a large error. Field relations demonstrate that the grey granites are older than the Hornemantoppen granitoids. A minimum inherited zircon age, 952 ± 20 Ma, has been obtained from the grey granites. Three multi-grain Pb ages, 423 ± 22 Ma (2 grains), 461 ± 42 Ma and 561 ± 93 Ma (the last two 3 grains) were considered to be mixed ages. Although no definitive evidence for the presence of Grenvillian granites in this area has been obtained in the present study, preliminary results from the multi-grain zircon evaporation method, carried out in the Russian laboratory at Apatity, infer Paleo- and Mesoproterozoic protoliths for the metamorphic rocks of northwestern Spitsbergen.     

Grenvillian U-Pb zircon ages of quartz porphyry and rhyolite clasts in a metaconglomerate at Vimsodden, southwestern Spitsbergen

Proterozoic metasupracrustal rocks form a NNW-SSE trending basement zone along the western coast of Spitsbergen. The rocks show complex structures as a result of both Caledonian and Tertiary deformation, and most of the subordinate metaigneous rocks are not suitable for isotopic age determination. Some zircon-bearing rocks were found in the southwestern part of Spitsbergen and an attempt of U-Pb dating was performed.
U-Pb dating was carried out on zircon fractions from quartz porphyry and rhyolite clasts in a metaconglomerate unit of the Pyttholmen Formation northwest of Hornsund, southwestern Spitsbergen. The Pyttholmen Formation is considered to be a lateral equivalent of the upper part of the Gulliksenfjellet quartzite and in the same time as the upper part of the Skålfjellet metavolcanites. Therefore, the obtained ages are applicable to the age of the Skålfjellet igneous activities. Some of the dated samples are strongly schistose and their magmatic origin is difficult to confirm; the interpretation of the isotopic results is not well constrained; however, some explanations are possible which refer to the known geological conditions; an igneous age of siliceous volcanic rocks of ca. 1200 Ma, inherited zircon ages of ca. 2500 Ma and a regional metamorphic age of ca. 930 Ma. The last age belongs to the Grenvillian period and is conformable with the Rb/Sr whole rock age obtained from the garnet-biotite schists of the Isbjernhamna Group underlying the Skålfjellet metavolcanites.     

Ordovician conodonts from the Bulltinden Formation, Motalafjella, central-western Spitsbergen

Seven samples from the Limestone and Boulder Conglomerate Members of the Bulltinden Formation have yielded poorly preserved conodonts. On tentative identifications Periodon aculeatus Hadding and Prioniodus cf. P. alobatus Bergstrom at the base of the formation suggest an Ordovician lower Caradoc, or older age. This confirms that the Vcstgotabrcen Formation unconformably beneath underwent high-pressure mctamorphism during the Taconic and/or Finmarkian phases of the Caledonian orogeny. The conodonts show affinity to the North Atlantic Province suggesting a deeper water marine depositional environment. Conodont colour alteration indices of five indicate that the Bulltinden Formation was heated to temperatures in excess of 300°C, probably during the middle-upper Silurian main Caledonian uplift event.     

Additional evidence of pre-Silurian high-pressure metamorphic rocks in Spitsbergen

It has been previously suggested that the high-pressure metamorphic rock complex of Motalafjclla, central-western Spitsbergen, is older than Lower Silurian. An unconformity has been discovered at the base of a limestone which contains fossils similar to those reported as Lower Silurian from the same massif. This proves that the high-pressure metamorphics represent an older rock complex. The unconformity surface is inverted in the area, and large recumbent folds involving the Silurian Bulltinden Formation have been mapped. These folds are considered to be pre-Carboniferous.     

Late Miocene Magmatic-Hydrothermal Systems in the Jozankei-Zenibako District, Southwest Hokkaido, Japan

Abstract: Hydrothermal systems related to magmatic intrusions in the Jozankei-Zenibako district, southwest Hokkaido are examined, based on field observations, K-Ar ages, and alteration mineral assemblages. The study reveals five major magmat–ic–hydrothermal systems of Late Miocene in age, comprising Ogawa (9. 7 Ma), Jozankei (9. 5–9. 0 Ma), Otarunaigawa (8. 7 Ma), Asarigawa (8. 8 and 6. 7 Ma) and Hariusu (6. 7 Ma). The Ogawa system is related to granodiorite, and the Jozankei, Otarunaigawa and Asarigawa systems are related to quartz porphyry.
The Ogawa system includes potassic, sericitic, propylitic and advanced argillic alteration as well as base-metal mineralization, represented by the Toyotomi deposit. The Jozankei and Otarunaigawa systems lack significant potassic alteration, and are accompanied by sericitic and propylitic alteration. The Otarunaigawa system is associated with base-metal mineralization at Toyohiro and Inatoyo. The Asarigawa and Hariusu systems include advanced argillic and argillic alteration, as well as iron sulfide deposits. The presence of potassic alteration only in the Ogawa system is ascribed to deeper emplacement (˜3 km from the surface) of the intrusive magma. These systems formed in terrestrial environments that existed from ca. 11 Ma to 8. 5 Ma and after 7. 5 Ma in the district.
Age–data compilation shows that the major advanced argillic alteration events in southwest Hokkaido, including those in the Jozankei-Zenibako district, formed during the periods from 9. 7–6. 5 Ma and 3. 5–1. 5 Ma. These periods correspond to the timing of normal subduction of the Pacific plate beneath the Northeast Japan arc. Normal, in contrast to oblique, plate subduction is characterized by andesitic, polygenetic volcanism and associated advanced argillic alteration.     

Geochemistry of the late Proterozoic Kapp Hansteen igneous rocks of Nordaustlandet, Svalbard

Proterozoic igneous rocks occur in three areas in Nordaustlandet, Svalbard, and are found in the upper part of the Lower Hecla Hoek succession, the Botniahalvøya Supergroup. The rocks have been called porphyrites in Botniahalvøya, metadiabases in Prins Oscars Land and quartz porphyries in both areas as well as in the Sabinebukta area. All rocks have been metamorphosed under the greenschist facies conditions. The porphyrites are calc-alkaline acid andesites and dacites of medium to high K2O type, possibly showing a transition to tholeiitic series. The quartz porphyries are calc-alkaline rhyolites of high K20 type. The metadiabases are subdivided into two: the basic dykes of low K20 type and relatively high Fe tholeiite series, while the main bodies are acid andesites of medium to high K20 and low Fe tholeiite series. The basic dykes fall in the oceanic rock field of the Tiø2-K20-P20s diagram, and are most likely belonging to the island arc type volcanism. The metadiabases of main bodies and the porphyrites, and possibly the quartz porphyries, are chemically continuous. The medium to high K20 contents, and their Tiø2-K20-P2O5 ratios suggest that these three rock groups are non-oceanic and resemble the rock associations of the areas having thick continental crust. This conclusion agrees with the reported high initial Sr^87/86 ratios and the existence of a distinct unconformity at the base of this volcanogenic succession.     

Granulites and garnet–cordierite gneisses from Dronning Maud Land, Antarctica

Abstract The central sector of Mühlig-Hofmannfjellet (3°E/71°S) in western Dronning Maud Land (East Antarctic shield) is dominated by large intrusive bodies of predominantly orthopyroxene-bearing quartz syenites (charnockites). Metasedimentary rocks are rare; however, two distinct areas with banded gneiss–marble–quartzite sequences of sedimentary origin were found during the Norwegian Antarctic Research Expedition NARE 1989/90. Cordierite-bearing metapelitic gneisses from two different localities contain the characteristic mineral assemblage: cordierite + garnet + biotite + K-feldspar + plagioclase + quartz ± sillimanite ± spinel. Thermobarometry indicates equilibration conditions of about 650°C and 4 kbar. Associated orthopyroxene–garnet granulites, on the other hand, revealed pressures of about 8 kbar and temperatures of 750°C. The earlier granulite facies metamorphism is not well preserved in the cordierite gneisses as a result of excess K-feldspar combined with interaction with an H₂O-rich fluid phase, probably released by the cooling intrusives. These two features allowed the original high-grade K-feldspar + garnet assemblages to recrystallize as cordierite–biotite–sillimanite gneisses, completely re-equilibrating them. Phase relationships indicate that the younger metamorphic event occurred in the presence of a fluid phase that varied in composition between the lithologies.     

Grenvillian single-grain zircon Pb age of a granitic rock from the southern island of Hesteskoholmen, Liefdefjorden, northwestern Spitsbergen, Svalbard

A N-S trending, narrow zone of crystalline basement occurs from Biscayarhalvøya to Holtedahlfonna in northwestern Spitsbergen and is composed of various metasedimentary and igneous rocks, including granites. Previous isotopic age determinations on these rocks are by the K-Ar. Rb-Sr, ⁴⁰Ar/³⁹Ar and conventional zircon U-Pb method and yielded the Caledonian and Grenvillian ages. The single-grain zircon Pb evaporation method has recently been applied to solve complex problems and this is the first report by the method.
A granitic rock, syntectonically intruded into the phyllitic metasediments of the Biscayarhuken formation, which is the uppermost lithotectonic unit in the metamorphic rocks of the zone, was dated on four zircon grains, yielding a narrow age range from 955 ± 4 to 968 ± 9 Ma in average. This age of ca. 960 Ma is considered to be the age of intrusion, based on the occurrence and zircon morphology, which is roughly simultaneous with the formation of the phyllitic cleavages of the surrounding metasediments. The data obtained imply that the Caledonian events did not reset the Pb isotope system of zircon and major metamorphism occurred during the Grenvillian time in the Biscayarhuken formation, accordingly, the protolith age of the metasediments is Mesoproterozoic.