Geochemical and statistical characterization of the phosphate facies of the Farim‐Saliquinhé phosphate mineralization (Guinea‐Bissau)

The Eocene Farim‐Saliquinhé phosphate mineralization (FSPM) is a buried sedimentary deposit located in the northern part of Guinea‐Bissau, discovered and spatially constrained during the 1980s by the French Geological Survey (BRGM). In the present work some of the data collected at that time are reworked in the framework of the development of a 3D geological and geochemical model of this mineralization. We show the usefulness of two classical multivariate statistical methods – principal component analysis (PCA) and cluster analysis (CA) – applied to eight geochemical variables (P₂O₅, SiO₂, Al₂O₃, Fe₂O₃, CaO, MgO, F and CO₂) measured in 247 samples from phosphate facies, for differentiation of samples taken from the different phosphate facies recognized in the FSPM, namely the main ore FPA (30 to 35% high grade phosphate), the calcareous low grade phosphate FPB (10 to 20% P₂O₅) (both Lutetian), and a mineralized Upper Eocene to Lower Oligocene cover (mainly including the FPO level and a silico‐aluminous phosphate bed), overlying the FPA, which can also be considered a third set of phosphate facies associated with the FSPM.     

Topological redundancy and ‘small‐world’ patterns in a food web in a subtropical ecosystem of Brazil

According to graph theory, the frequency distribution of trophic interactions within a food web has deep structural implications, as it can highlight the presence of patterns associated with the web and indicate whether the properties of the web are independent of its size. A hypothesis is that ‘small‐world’ food webs are sensitive to the loss of species with the highest values. Therefore, the present work aimed to evaluate the degree to which a subtropical food web in Southern Brazil displays small‐world patterns and their resistance. As part of the assessment, we evaluated the topological redundancy values of species in the food web and then we simulated the exclusion of these species (such as sharks and sea birds), and also the exclusion of high centrality species (such as squids Loligo sp., portunid swimming crabs and the cutlassfish Trichiurus lepturus). The food web showed a ‘broad‐scale’ distribution of connections by node, and a small‐world pattern. As expected, a simplification of the network was observed after elimination of some species with high centrality. However, the food web was resistant to the loss of species with low topological redundancy, probably because these species occupy a high trophic level and do not participate in lots of routes within the food web. We highlight however, the importance of the application of multiple analyses to evaluate the importance of components in food webs, and fisheries management plans should consider both species of high centrality values and species with low topological redundancy.     

Relationship between geoacoustic properties and chemical content of submarine polymetallic crusts from offshore Brazil

Abstract

Marine mining is the ocean’s new exploration frontier, and polymetallic crusts (PMCs) and ferromanganese nodules are considered a strategic resource for the future. Acoustic geophysical methods are a valuable tool for oceanic research and have been employed for several decades in the exploration of marine resources and environmental evaluations. The main objective of this work was to investigate the correlation between the chemical composition of PMCs from three different areas along the Brazilian continental margin and their physico-acoustic attributes (P-wave velocity, density and acoustic impedance). The results show that the geoacoustic properties of PMCs are correlated to their chemical composition. Measurements showed positive and negative trends between acoustic impedance and studied elements (Fe, Mn, Co, Cu, Zn, W and Ni) according to the direction of measurement, indicting high anisotropy levels. Our study sheds initial light on the correlation between acoustic properties and metal content of PMCs. The study facilitates assessments of the acoustic responses of PMCs allowing more efficient prospection and exploitation compared to ship-board geophysical techniques that are too qualitative to identify PMCs. The results can contribute to determining the best procedures and techniques for more efficient future exploration of this resource.     

Summer circulation patterns related to the upper tropospheric vortices over the Tropical South Atlantic

Summary Daily 200-hPa relative vorticity data have been used to study the dominant patterns related to the cyclonic vortices over the South Atlantic Ocean in the vicinities of northeast Brazil, during the 1980–1989 period. Reference modes were obtained through empirical orthogonal function (EOF) analysis of the 200-hPa filtered vorticity anomalies over northeast Brazil, considering all the southern hemisphere (SH) summers within the study period. The amplitude time series of the first reference mode, separately for each SH summer, was correlated with the corresponding filtered vorticity anomalies in a larger area extending from 20°N to 40°S and between 120°W and 20°W. The correlation patterns feature a wave-like structure along eastern South America, with three main centers: the first one, over the South Atlantic off the northeast Brazil coast, is associated with the cyclonic vortices; the second one, over eastern Brazil, represents the corresponding anomalously amplified ridges; and the third one, over southern Brazil/Uruguay, is related to the equatorward incursions of midlatitude upper level troughs. This wave-like pattern is consistent with the vortex formation mechanism suggested in previous works. Another wave-like pattern southwest-northeast oriented is evident over the tropical southeastern Pacific, for some years. The internannual variability of these patterns is discussed in this paper.With 9 Figures     

Moisture and heat budgets of the south American monsoon system: climatological aspects

The climatology of the moisture and heat budget equation terms for subareas within the South American Monsoon System (SAMS) region is investigated for the 1958–2014 period considering the distinct phases of the Pacific Decadal Oscillation (PDO). These budget equations are applied to the data from the National Centers for Environmental Prediction (NCEP) Reanalysis project. Sources or sinks of moisture and heat are equation residues, referred to as residue and diabatic terms, respectively. Analyses are done for the Central Amazon Basin (CAM) and Western-Central Brazil (WCB) for three distinct periods, 1958–1976, 1977–1995, and 1996–2014, that correspond to the cold, warm, and undefined PDO phases. The differences among the PDO phases for each term are discussed. The CAM region acts dominantly as a moisture sink and heat source in all months during the three phases. On the other hand, in the WCB region, the monsoon characteristics are better defined, with a moisture sink (source) and a heat source (sink) during the wet (dry) season. The main result of the present analysis is the persistence of SAMS intensification signs in both CAM and WCB areas up to the last analyzed period (1996–2014), which is consistent with intense flooding in the Amazon Basin in 2008/2009, 2012, and 2014.     

Assessing the control exerted by soil mineralogy in the fixation of potentially harmful elements in the urban soils of Lisbon,Portugal

The main purposes of this study are the textural, chemical and mineralogical characterization of the urban soils of Lisbon and the identification of probable relations between the several soil properties. The results are used to infer which soil properties control the superficial dispersion of potential harmful elements to human health. Soil sampling was carried out in 51 selected sites all through the city, under the criterion that such sites should be spaces usually frequented by children. The concentrations of 42 elements in the >2 mm soil size fraction were determined at a commercial laboratory in Canada (ActLabs, LTD), by ICP-MS/ICP-OES after an acid digestion with aqua regia. The soil mineralogy was determined by X-ray diffraction in the <2 and <62 μm size fractions. The results indicate that the urban soils have mainly a sandy texture and a main mineralogical assemblage of quartz, K-feldspar, plagioclase and calcite. In terms of clay minerals, smectite, illite and kaolinite are the main clays in the soil. Smectite and illite show a dichotomy in their distribution, with the smectites prevailing in the soils of the volcanic complex of Lisbon, which are classified as being residual, and illite prevailing in the remaining soils, which are considered mainly as man-made soils. Smectite seems to exert an important role in the fixation of Ni and Cr. The results of the geochemical study show that Ni and Cr have concentrations above the soil guideline value established to the UK and pose a probable risk to human health.     

Tide circulation patterns in a coastal lagoon under sea-level rise

This study evaluates the patterns and effects of relative sea-level rise on the tidal circulation of the basin of the Ria Formosa coastal lagoon using a process-based model that is solved on an unstructured mesh. To predict the changes in the lagoon tidal circulation in the year 2100, the model is forced by tides and a static sea level. The bathymetry and the basin geometry are updated in response to sea-level rise for three morphological response scenarios: no bed updating, barrier island rollover, and basin infilling. Model results indicate that sea-level rise (SLR) will change the baseline current velocity patterns inside the lagoon over the ~100-year study period, due to a strong reduction in the area of the intertidal basin. The basin infilling scenario is associated with the most important adjustments of the tidal circulation (i.e., increases in the flood velocities and delays in the ebb tide), together with an increase in the cumulative discharges of the tidal inlets. Under sea-level rise and in the basin infilling scenario, the salt marshes and tidal flats experience increases in the tidal range and current asymmetry. Basin infilling changes the sediment flushing capacity of the lagoon, leading to the attenuation of the flood dominance in the main inlet and the strengthening of the flood dominance in the two secondary inlets. The predictions resulting from these scenarios provide very useful information on the long-term evolution of similar coastal lagoons that experience varying degrees of SLR. This study highlights the need for research focusing on the quantification of the physical and socio-economic impacts of SLR on lagoon systems, thus enabling the development of effective adaptation strategies.