Stratospheric aerosol measurements in the Arctic winter of 1996/1997 with the M‐55 Geophysika high‐altitude research aircraft

In‐situ aerosol measurements were performed in the northern hemispheric stratosphere up to altitudes of 21 km between 13 November 1996 and 14 January 1997, inside and outside of the polar vortex during the Airborne Polar Experiment (APE) field campaign. These are measurements of particle size distributions with a laser optical particle counter of the FSSP‐300 type operated during 9 flights on the Russian M‐55 high‐altitude research aircraft Geophysika. For specific flights, the FSSP‐300 measurements are compared with balloon‐borne data (launched from Kiruna, Sweden). It was found that the stratospheric aerosol content reached levels well below the background concentrations measured by the NASA operated ER‐2 in 1988/89 in the northern hemisphere. During the APE campaign, no PSC particle formation was observed at flight altitudes although the temperatures were below the NAT condensation point during one flight. The measured correlations between ozone and aerosol give an indication of the subsidence inside the 1996/97 polar vortex. Despite the lower aerosol content in the winter 1996/97 compared to the 1989 background, the heterogeneous reactivity of the aerosol (as calculated from the measured data with additional model input) is comparable. This is due to the dependency of the reactive uptake coefficients on the atmospheric water vapor content. Under the described assumptions the reaction rates on the background aerosol are significantly smaller than for competing gas phase chlorine activation, as can be expected for stratospheric background conditions especially inside the polar vortex.     

A mechanism for emplacement and concentration of diatoms in glacigenic deposits

The occurrence of diatoms (both marine and freshwater) in sediments beneath the West Antarctic Ice Sheet (WAIS) is suggestive of past ice-sheet collapse. However, it is not the only model explaining such occurrences. We propose another mechanism for introducing diatoms beneath ice sheets by considering the fate of a diatom placed (by eolian processes) on top of an ice sheet. Mathematical modeling indicates that the route the diatom will take through the ice sheet is dictated by the basal melting rate. If no basal melting takes place, flowlines will crop out at the ice-sheet margin. However, if basal melting is as low as 0.01 m/yr the trajectories of all Howlines except for those nearest the margin will intersect the bed, with those diatoms deposited near the dome reaching the bed about halfway down the Howband. Larger values of basal melting lead to the diatoms reaching the bed even faster and closer to the point of origin. In light of these results, the presence of diatoms in sediments beneath the WAIS does not lead to a unique solution; it is not necessary to invoke past ice-sheet collapse to account for their presence.     

Full-glacial — late-glacial palaeoclimate of the Southern Andes: evidence from pollen,beetle and glacial records

Palaeoecological studies carried out in the Chilean Lake District and Chilotan Archipelago (41°–43°S) record full-glacial and late-glacial pollen assemblages beginning just after 21000 and beetle assemblages after 18000, both sets extending until 10000 ¹⁴C yr BP. Pollen records indicate that Subantarctic Parkland, the vegetation of the early millennia of record, changed after about 14000 yr BP to become open woodland and later North Patagonian Evergreen Forest. Assemblages of plants and beetles, responding more or less in unison to a strong rise in temperature (≥ 6°C), behaved in accord at around 14000 until 13000–12500 yr BP, the beetle fauna displaying a marked increase in obligate forest types. During full-glacial conditions (17400–16100 and 15300 and 14400 yr BP) and in the late-glacial interval (after about 13000 yr BP), however, climate evidently coerced populations dissimilarly, the pollen sequence showing an increase in plant taxa indicative of colder climate, whereas the beetle fauna underwent little or no variation. Contrasting climate modes implied by plants and beetles may be attributed to differential responses to apparent low-order temperature changes (≤ 2–3°C).     

Temperatures of Granulite-facies Metamorphism: Constraints from Experimental Phase Equilibria and Thermobarometry Corrected for Retrograde Exchange

This study assesses temperatures of formation of common granulitesby combining experimental constraints on the P–T stabilityof granulite-facies mineral associations with a garnet–orthopyroxene(Grt–Opx) thermobarometry scheme based on Al-solubilityin Opx, corrected for late Fe–Mg exchange. We appliedthis scheme to 414 granulites of mafic, intermediate and aluminousbulk compositions. Our findings suggest that granulites aremuch hotter than traditionally assumed and that the P–Tconditions of the amphibolite–granulite transition portrayedin current petrology textbooks are significant underestimatesby over 100°C. For aluminous and intermediate granulites,mean corrected temperatures based on our method are 890 ±17 and 841 ± 11°C, respectively (uncertainties reportedas 95% confidence limits on the mean), consistent with minimumtemperatures for orthopyroxene production by fluid-absent partialmelting in these bulk compositions. In contrast, mean temperaturesbased on Grt–Opx Fe–Mg exchange equilibria, usingthe same thermodynamic data, are 732 ± 22 and 723 ±11°C, respectively, well below the minimum temperaturesfor Opx stability. For mafic granulites, the mean correctedtemperature using our method is 816 ± 12°C, similarto the mean temperature of 793 ± 13°C from Fe–Mgexchange. Reasons for the differences between the mafic granulitesand aluminous–intermediate granulites are unclear butmay be due to the lower Al concentrations in Opx in the maficrocks and possible deficiencies in the thermodynamic modellingof these low concentrations. We discuss a number of well-knowngranulite terrains in the context of our findings, includingthe Adirondacks, the Acadian granulites of New England, theincipient charnockites of southern India and Sri Lanka, andthe Kerala Khondalite Belt. Our findings carry implicationsfor thermotectonic models of granulite formation. A computerprogram to perform our thermobarometry calculations, RCLC, isavailable from the Journal of Petrology website at http://www.petrology.oupjournals.orgor from the authors at http://www.geo.ucalgary.ca/~pattison/drm_pattison-rclc.htm. KEY WORDS: granulite-facies metamorphism; thermobarometry; garnet; orthopyroxene     

Vertical profiles of biospheric and fossil fuel-derived CO2 and fossil fuel CO2 : CO ratios from airborne measurements of Δ14C, CO2 and CO above Colorado, USA

Measurements of  Δ¹⁴C  in atmospheric CO₂ are an effective method of separating CO₂ additions from fossil fuel and biospheric sources or sinks of CO₂. We illustrate this technique with vertical profiles of CO₂ and  Δ¹⁴C  analysed in whole air flask samples collected above Colorado, USA in May and July 2004. Comparison of lower tropospheric composition to cleaner air at higher altitudes (>5 km) revealed considerable additions from respiration in the morning in both urban and rural locations. Afternoon concentrations were mainly governed by fossil fuel emissions and boundary layer depth, also showing net biospheric CO₂ uptake in some cases. We estimate local industrial CO₂:CO emission ratios using in situ measurements of CO concentration. Ratios are found to vary by 100% and average 57 mole CO₂:1 mole CO, higher than expected from emissions inventories. Uncertainty in CO₂ from different sources was ±1.1 to ±4.1 ppm for addition or uptake of −4.6 to 55.8 ppm, limited by  Δ¹⁴C  measurement precision and uncertainty in background  Δ¹⁴C  and CO₂ levels.     

RAPID ESTIMATION OF THE NUMBER OF COELUTING COMPONENTS IN LIQUID CHROMATOGRAPHY BY FACTOR ANALYSIS

Evaluation of the results of factor analysis of sets of spectroscopically detected chromatograms is carriedout by examining the shapes of the abstract factors.This is done either by visual inspection or by analysisof the power density spectra produced from them.Owing to constraints imposed by the column functionand the spectroscopic instrument function,the information content of the chromatograms necessarilyoccurs at low spatial frequencies.As a consequence,it appears as relatively broad features in the abstractchromatograms and as a peak in the low-frequency region of the corresponding power density plot.Onthe basis of examination of the power density distribution,a well-defined distinction is made betweenprimary and secondary abstract factors.The major uncertainty encountered in determining the numberof chemical components appears to arise from effects of contaminants in reagents.