Staurolite porphyroblast controls on local bulk compositional and microstructural changes during decompression of a St–Bt–Grt–Crd–And schist (Ancasti metamorphic complex,Sierras Pampeanas,W Argentina)

The staurolite–biotite–garnet–cordierite–andalusite–plagioclase–muscovite–quartz metapelitic mineral assemblage has been frequently interpreted in the literature as a result of superimposition of various metamorphic events, for example, in polymetamorphic sequences. The assemblage was identified in schists from the Ancasti metamorphic complex (Sierras Pampeanas of Argentina) where previous authors have favoured the polymetamorphic genetic interpretation. A pseudosection in the MnNCKFMASH system for the analysed XRF bulk composition predicts the stability of the sub‐assemblage staurolite–biotite–garnet–plagioclase–muscovite–quartz, and the compositional isopleths also agree with measured mineral compositions. Nevertheless, the XRF pseudosection does not predict any field with staurolite, andalusite and cordierite being stable together. As a result of more detailed modelling making use of the effective bulk composition concept, our interpretation is that the staurolite–biotite–garnet–plagioclase–muscovite–quartz sub‐assemblage was present at peak metamorphic conditions, 590 °C and 5.2 kbar, but that andalusite and cordierite grew later along a continuous P–T path. These minerals are not in mutual contact and are observed in separate microstructural domains with different proportions of staurolite. These domains are explained as a result of local reaction equilibrium subsystems developed during decompression and influenced by the previous peak crystal size and local modal distribution of staurolite porphyroblasts that have remained metastable. Thus, andalusite and cordierite grew synchronously, although in separate microdomains, and represent the decompression stage at 565 °C and 3.5 kbar.     

Quantifying Barrovian metamorphism in the Danba Structural Culmination of eastern Tibet

The Danba Structural Culmination is a tectonic window into the late Triassic to early Jurassic Songpan‐Garzê Fold Belt of eastern Tibet, which exposes an oblique section through a complete Barrovian‐type metamorphic sequence. Systematic analysis of a suite of metapelites from this locality has enabled a general study of Barrovian metamorphism, and provided new insights into the early thermotectonic history of the Tibetan plateau. The suite was used to create a detailed petrographic framework, from which four samples ranging from staurolite to sillimanite grade were selected for thermobarometry and geochronology. Pseudosection analysis was applied to calculate P–T path segments and determine peak conditions between staurolite grade at ～5.2 kbar and 580 °C and sillimanite grade at ～6.0 kbar and 670 °C. In situ U–Pb monazite geochronology reveals that staurolite‐grade conditions were reached at 191.5 ± 2.4 Ma, kyanite‐grade conditions were attained at 184.2 ± 1.5 Ma, and sillimanite‐grade conditions continued until 179.4 ± 1.6 Ma. Integration of the results has provided constraints on the evolution of metamorphism in the region, including a partial reconstruction of the regional metamorphic field gradient. Several key features of Barrovian metamorphism are documented, including nested P–T paths and a polychronic field gradient. In addition, several atypical features are noted, such as P–T path segments having similar slopes to the metamorphic field gradient, and T_max and P_max being reached simultaneously in some samples. These features are attributed to the effects of slow tectonic burial, which allows for thermal relaxation during compression. While nested, clockwise P–T–t loops provide a useful framework for Barrovian metamorphism, this study shows that the effects of slow burial can telescope this model in P–T space. Finally, the study demonstrates that eastern Tibet experienced a significant phase of crustal thickening during the Mesozoic, reinforcing the notion that the plateau may have a long history of uplift and growth.     

Zircon U–Pb Dating and Geochemistry of the Linong Granitoid and Its Relationship to Cu Mineralization in the Yangla Copper Deposit,Yunnan, China

The Yangla copper deposit (Cu reserves: 1.2 Mt) in the Jinshajiang–Lancangjiang–Nujiang region in China is spatially associated with the Linong granitoid. Zircon U–Pb dating shows the granitoid formed at 234.1 ± 1.2 to 235.6 ± 1.2 Ma, and the KT2 ore body of the deposit yields a molybdenite Re–Os model age of 230.9 ± 3.2 Ma. The ages of mineralization and crystallization of the granitoid are identical within the measurement uncertainties, suggesting the Yangla deposit is genitically related to the Indosinian Linong granitoid.     

Implications of trace element composition of syntaxial quartz cements for the geochemical conditions during quartz precipitation in sandstones

A petrographic investigation revealed polyphase quartz cementation in the Finefrau Sandstone (Upper Carboniferous, Western Germany) and the Solling Sandstone (Lower Triassic, Central Germany). Three different cements could be distinguished in each sandstone based on their cathodoluminescence and trace element composition. The first quartz generation is suggested to have been formed during eogenesis due to dissolution and replacement of feldspar. The mesogenetic paragenesis comprises two generations of quartz and illite, which are accompanied by albite in the Solling Sandstone. Sharp luminescence zoning in quartz overgrowths points to distinct episodes of cementation in both sandstones. Significant amounts of Al, Li and H and traces of Ge and B have been detected in the quartz overgrowths. The Al‐content of the quartz cements in the Finefrau Sandstones exceeds that in the quartz cements in the Solling Sandstone by a factor of five. It is suggested that this compositional variation reflects the conditions in the pore‐water, such as temperature and pH. The Al‐concentration is generally correlated to the Li‐content with the exception of the latest quartz generation in the Finefrau Sandstones which is also most enriched in trace elements. The ratio of Li/Al varies between 0·11 and 0·25 in the two sandstones. The Li/H‐ratio, which ranges from 0·12 to 0·3, is controlled by the activity ratio of Li and H in the pore fluid. Clay minerals are the most important source for Li and high salinities favour the mobilization of Li during diagenesis. Thus, a relatively low salinity and low pH are responsible for the low Li/H‐ratio in the Finefrau Sandstone, while high salinity and neutral to alkaline pH results in a high Li/H‐ratio for the Solling Sandstone. The Ge‐contents are generally near the average of detrital quartz and indicate that pressure dissolution is a major source for quartz cementation. Different chemical compositions of distinct quartz generations indicate changes in the physico‐chemical conditions and point to mobilization of silica from different sources (for example, pressure solution and clay mineral transformations).     

An empirical model of subcritical bedform migration

The ability to predict bedform migration in rivers is critical for estimating bed material load, yet there is no relation for predicting bedform migration (downstream translation) that covers the full range of conditions under which subcritical bedforms develop. Here, the relation between bedform migration rates and transport stage is explored using a field and several flume data sets. Transport stage is defined as the non‐dimensional Shields stress divided by its value at the threshold for sediment entrainment. Statistically significant positive correlations between both ripple and dune migration rates and transport stage are found. Stratification of the data by the flow depth to grain‐size ratio improved the amount of variability in migration rates that was explained by transport stage to ca 70%. As transport stage increases for a given depth to grain‐size ratio, migration rates increase. For a given transport stage, the migration rate increases as the flow depth to grain‐size ratio gets smaller. In coarser sediment, bedforms move faster than in finer sediment at the same transport stage. Normalization of dune migration rates by the settling velocity of bed sediment partially collapses the data. Given the large amount of variability that arises from combining data sets from different sources, using different equipment, the partial collapse is remarkable and warrants further testing in the laboratory and field.     

The Scandinavian Ice Sheet: from MIS 4 to the end of the Last Glacial Maximum

Lambeck, K., Purcell, A., Zhao, J. & Svensson, N‐O. 2010 (April): The Scandinavian Ice Sheet: from MIS 4 to the end of the Last Glacial Maximum. Boreas, Vol. 39, pp. 410–435. 10.1111/j.1502‐3885.2010.00140.x. ISSN 0300‐9483. Glacial rebound modelling, to establish constraints on past ice sheets from the observational evidence of palaeo‐shoreline elevations, is well established for the post‐ Last Glacial Maximum (post‐LGM) period, for which the observational evidence is relatively abundant and well distributed spatially and in time. This is particularly the case for Scandinavia. For the earlier part of the glacial cycle this evidence becomes increasingly sparse and uncertain such that, with the exception of the Eemian period, there are very few, if any, direct sea‐level indicators that constrain any part of the Scandinavian Ice Sheet evolution before the LGM. Instead, we assume that ice‐sheet basal conditions during Marine Isotope Stage 3 (MIS 3) are the same as those for the LGM, focus on establishing these conditions from the rebound analysis for the LGM and Lateglacial period, and then extrapolate to the earlier period using observationally constrained locations of the ice margins. The glacial rebound modelling and inversion follow previously established formulations, with the exception that the effects of water loading from proglacial lakes that form within the Baltic Basin and elsewhere have been included. The data set for the inversion of the sea‐ and lake‐level data has been extended to include marine‐limit data in order to extend the observational record further back in time. The result is a sequence of time slices for the Scandinavian Ice Sheet from the time of MIS 4 to the Lateglacial that are characterized by frozen basal conditions until late in the LGM interval when rapid thinning occurred in the eastern and southern sectors of the ice sheet. The primary function of these models is as an interpolator between the fragmentary observational constraints and to produce quantitative models for the glaciation history with predictive capabilities, for example regarding the evolution of the Baltic Basin.     

Geoarchaeological investigation of lithic resources in the central Mesa Verde region,Colorado, USA

An important question in Southwestern archaeological research is how social and economic ties between prehistoric groups changed through time. The chemical and mineralogical matching of stone tools and ceramics to source areas is one approach to addressing this question. Here we challenge the assumption that igneous rocks used for manufacturing stone tools and ceramics in the Mesa Verde region of Colorado were originally derived from the Chuska Mountains of New Mexico. Recent geological surveys suggest that small igneous features present in and around Mesa Verde National Park and Ute Mountain Ute Tribal Park contain similar lithologies and may represent a local source. We systematically visited seven of these igneous exposures and nine downstream gravel deposits, looking for geological sources and quarry sites matching the lithology of analyzed debitage from this region. Our results suggest that the ancestral Puebloans could have procured such igneous rocks as aphanitic minette and trachybasalt pottery temper from local areas. Because the trachybasalt is usually thought to have been imported from the Chuska Mountains, this discovery may require a revision of interpreted trade networks based on pottery temper and lithic raw material distinctions. © 2009 Wiley Periodicals, Inc.     

Archean to Recent aeolian sand systems and their sedimentary record: Current understanding and future prospects

The sedimentary record of aeolian sand systems extends from the Archean to the Quaternary, yet current understanding of aeolian sedimentary processes and product remains limited. Most preserved aeolian successions represent inland sand‐sea or dunefield (erg) deposits, whereas coastal systems are primarily known from the Cenozoic. The complexity of aeolian sedimentary processes and facies variability are under‐represented and excessively simplified in current facies models, which are not sufficiently refined to reliably account for the complexity inherent in bedform morphology and migratory behaviour, and therefore cannot be used to consistently account for and predict the nature of the preserved sedimentary record in terms of formative processes. Archean and Neoproterozoic aeolian successions remain poorly constrained. Palaeozoic ergs developed and accumulated in relation to the palaeogeographical location of land masses and desert belts. During the Triassic, widespread desert conditions prevailed across much of Europe. During the Jurassic, extensive ergs developed in North America and gave rise to anomalously thick aeolian successions. Cretaceous aeolian successions are widespread in South America, Africa, Asia, and locally in Europe (Spain) and the USA. Several Eocene to Pliocene successions represent the direct precursors to the present‐day systems. Quaternary systems include major sand seas (ergs) in low‐lattitude and mid‐latitude arid regions, Pleistocene carbonate and Holocene–Modern siliciclastic coastal systems. The sedimentary record of most modern aeolian systems remains largely unknown. The majority of palaeoenvironmental reconstructions of aeolian systems envisage transverse dunes, whereas successions representing linear and star dunes remain under‐recognized. Research questions that remain to be answered include: (i) what factors control the preservation potential of different types of aeolian bedforms and what are the characteristics of the deposits of different bedform types that can be used for effective reconstruction of original bedform morphology; (ii) what specific set of controlling conditions allow for sustained bedform climb versus episodic sequence accumulation and preservation; (iii) can sophisticated four‐dimensional models be developed for complex patterns of spatial and temporal transition between different mechanisms of accumulation and preservation; and (iv) is it reasonable to assume that the deposits of preserved aeolian successions necessarily represent an unbiased record of the conditions that prevailed during episodes of Earth history when large‐scale aeolian systems were active, or has the evidence to support the existence of other major desert basins been lost for many periods throughout Earth history?     

Does continental crust transform during eclogite facies metamorphism?

Eclogites within exhumed continental collision zones indicate regional burial to depths of at least 60 km, and often more than 100 km in the coesite‐stable, ultra‐high pressure (UHP) eclogite facies. Garnet, omphacitic pyroxene, high‐Si mica, kyanite ± coesite should grow at the expense of low‐P minerals in most felsic compositions, if equilibrium obtained at these conditions. The quartzofeldspathic rocks that comprise the bulk of eclogite facies terranes, however, contain mainly amphibolite facies, plagioclase‐bearing assemblages. To what extent these lower‐P minerals persisted metastably during (U)HP metamorphism, or whether they grew afterwards, reflects closely upon crustal parameters such as density, strength and seismic character. The Nordfjord area in western Norway offers a detailed view into a large crustal section that was subducted into the eclogite facies. The degree of transformation in typical pelite, paragneiss, granitic and granodioritic gneiss was assessed by modelling the equilibrium assemblage, comparing it with existing parageneses in these rocks and using U/Th–Pb zircon geochronology from laser ablation ICPMS to establish the history of mineral growth. U–Pb dates define a period of zircon recrystallization and new growth accompanying burial and metamorphism lasting from 430 to 400 Ma. Eclogite facies mafic rock (~2 vol.% of crust) is the most transformed composition and records the ambient peak conditions. Rare garnet‐bearing pelitic rocks (<10 vol.% of crust) preserve a mostly prograde mineral evolution to near‐peak conditions; REE concentrations in zircon indicate that garnet was present after 425 Ma and feldspar broke down after 410 Ma. Felsic gneiss – by far the most abundant rock type – is dominated by quartz + biotite + feldspar, but minor zoisite/epidote, phengitic white mica, garnet and rutile point to a prograde HP overprint. Relict textures indicate that much of the microstructural framework of plagioclase, K‐feldspar, and perhaps biotite, persisted through at least 25 Ma of burial, and ultimately UHP metamorphism. The signature reaction of the eclogite facies in felsic rocks – jadeite/omphacite growth from plagioclase – cannot be deduced from the presence of pyroxene or its breakdown products. We conclude that prograde dehydration in orthogneiss leads to fluid absent conditions, impeding equilibration beyond ~high‐P amphibolite facies.     

Pressure and temperature conditions for crystallization of metamorphic allanite and monazite in metapelites: a case study from the Miyar Valley (high Himalayan Crystalline of Zanskar,NW India)

The textural and chemical evolution of allanite and monazite along a well‐constrained prograde metamorphic suite in the High Himalayan Crystalline of Zanskar was investigated to determine the P–T conditions for the crystallization of these two REE accessory phases. The results of this study reveals that: (i) allanite is the stable REE accessory phase in the biotite and garnet zone and (ii) allanite disappears at the staurolite‐in isograd, simultaneously with the occurrence of the first metamorphic monazite. Both monazite and allanite occur as inclusions in staurolite, indicating that the breakdown of allanite and the formation of monazite proceeded during staurolite crystallization. Staurolite growth modelling indicates that staurolite crystallized between 580 and 610 °C, thus setting the lower temperature limit for the monazite‐forming reaction at ~600 °C. Preservation of allanite and monazite inclusions in garnet (core and rim) constrains the garnet molar composition when the first monazite was overgrown and subsequently encompassed by the garnet crystallization front. Garnet growth modelling and the intersection of isopleths reveal that the monazite closest to the garnet core was overgrown by the garnet advancing crystallization front at 590 °C, which establishes an upper temperature limit for monazite crystallization. Significantly, the substitution of allanite by monazite occurs in close spatial proximity, i.e. at similar P–T conditions, in all rock types investigated, from Al‐rich metapelites to more psammitic metasedimentary rocks. This indicates that major silicate phases, such as staurolite and garnet, do not play a significant role in the monazite‐forming reaction. Our data show that the occurrence of the first metamorphic monazite in these rocks was mainly determined by the P–T conditions, not by bulk chemical composition. In Barrovian terranes, dating prograde monazite in metapelites thus means constraining the time when these rocks reached the 600 °C isotherm.