An analytical solution for describing the transient temperature distribution in an aquifer thermal energy storage system

A mathematical model is developed for predicting the temperature distribution in an aquifer thermal energy storage (ATES) system, which consists of a confined aquifer bounded from above and below by the rocks of different geological properties. The main transfer processes of heat include the conduction and advection in the aquifer and the conduction in the rocks. The semi‐analytical solution in dimensionless form for the model is developed by Laplace transforms and its corresponding time‐domain solution is evaluated by the modified Crump method. Field geothermal property data are used to simulate the temperature distribution in an ATES system. The results show that the heat transfer in the aquifer is fast and has a vast effect on the vicinity of the wellbore. However, the aquifer temperature decreases with increasing radial and vertical distances. The temperature in the aquifer may be overestimated when ignoring the effect of thermal conductivity. The temperature distribution in an ATES system depends on the vertical thermal conduction in the rocks and the horizontal advection and thermal conduction in the aquifer. The present solution is useful in designing and simulating the heat injection facility in the ATES systems. Copyright © 2010 John Wiley & Sons, Ltd.     

Effect of the Dry Ashing Method on Cadmium Isotope Measurements in Soil and Plant Samples

A dry ashing method is commonly used to remove organic material from samples prior to geochemical analysis. In the course of this study, the Cd isotope ratios of a series of soil and plant reference materials and samples were studied to evaluate the effect of the dry ashing method on measurement results of Cd isotope ratios. The samples were pre‐treated using the dry ashing method and high‐pressure bomb for comparison. The results show that the digestion using high‐pressure bombs did not lead to Cd loss, but using the dry ashing method would cause different proportions of Cd loss. The whole range of Cd isotope difference between two methods was from ?0.07‰ to 3.01‰. There was also an obvious difference in measured Cd isotope ratios from the same leaf sample pre‐treated independently by the dry ashing method, indicating that the amount of Cd loss and the effect on Cd isotope measurement during dry ashing is related to the properties of the samples. Therefore, dry ashing may not be appropriate for the removal of organic material in Cd isotope ratio measurement, especially for samples with high organic contents. The δ^114/110Cd values of reference materials NIST SRM 1573a and GSD‐30 are reported for the first time in this study.     

Parallelization of the distinct lattice spring model

The distinct lattice spring model (DLSM) is a newly developed numerical tool for modeling rock dynamics problems, i.e. dynamic failure and wave propagation. In this paper, parallelization of DLSM is presented. With the development of parallel computing technologies in both hardware and software, parallelization of a code is becoming easier than before. There are many available choices now. In this paper, Open Multi‐Processing (OpenMP) with multicore personal computer (PC) and message passing interface (MPI) with cluster are selected as the environments to parallelize DLSM. Performances of these parallel DLSM codes are tested on different computers. It is found that the parallel DLSM code with OpenMP can reach a maximum speed‐up of 4.68× on a quad‐core PC. The parallel DLSM code with MPI can achieve a speed‐up of 40.886× when 256 CPUs are used on a cluster. At the end of this paper, a high‐resolution model with four million particles, which is too big to handle by the serial code, is simulated by using the parallel DLSM code on a cluster. It is concluded that the parallelization of DLSM is successful. Copyright © 2011 John Wiley & Sons, Ltd.     

Evidence of ameliorated Middle Weichselian climate and sub‐arctic environment in the western Baltic region: coring lake sediments at Klintholm,Møn,Denmark

Coring through glaciotectonically stacked Quaternary sediments situated below sea level on the island of Møn, Denmark, recovered a succession of interstadial sediments of Middle Weichselian age. Plant and animal remains including insects found in laminated sand and mud indicate deposition in a lake surrounded by dwarf shrubs, herbs, mosses and rare trees. The insect fauna indicates a mean July temperature of 8–12 °C, suggesting an arctic to sub‐arctic environment, while winter temperatures around ?8 to ?22 °C suggest periglacial conditions with permafrost. Luminescence dating of sediment samples gave ages from 48–29 ka, and radiocarbon dating indicates deposition of plant fragments between 45 and 36 ka BP. The fossil assemblage from Møn shows close resemblance to those from other sites with similar ages found in the vicinity of the western Baltic Basin.     

Process length variation in cysts of the dinoflagellate Protoceratium reticulatum,from surface sediments of the Baltic–Kattegat–Skagerrak estuarine system: a regional salinity proxy

Mertens, K. N., Dale, B., Ellegaard, M., Jansson, I.‐M., Godhe, A., Kremp, A. & Louwye, S. 2010: Process length variation in cysts of the dinoflagellate Protoceratium reticulatum, from surface sediments of the Baltic–Kattegat–Skagerrak estuarine system: a regional salinity proxy. Boreas, 10.1111/j.1502‐3885.2010.00193.x. ISSN 0300‐9483. Results are presented from a regional comparison of average process length variation in cysts of Protoceratium reticulatum and Lingulodinium polyedrum, extracted from surface sediments in the Skagerrak–Kattegat–Baltic estuarine system, with the environmental variables of seawater temperature and salinity. Although too few cysts of Lingulodinium polyedrum were recovered from the sediments to make reliable correlations, cysts of Protoceratium reticulatum were well represented, and average process length was correlated significantly with both salinity and temperature. Owing to dominant summer surface production, and regional covariation between salinity and density, we propose the use of the significant correlation with summer sea surface salinity (SSS_summer) by the equation SSS_summer=3.16 × average process length ?0.84 (R²=0.8). Application of this equation down‐core in Limfjord (northern Denmark) shows its usefulness as a regional palaeosalinity proxy.     

Intergranular coesite and coesite inclusions in dolomite from the Dabie Shan: Constraints on the preservation of coesite in UHP rocks

Intergranular coesite is extremely rare in, and bears crucial information on the formation and preservation of, ultrahigh‐pressure (UHP) rocks. Here, we report the first occurrence of intergranular coesite in a metasedimentary rock, which occurs in the Ganjialing area in the Dabie Shan, east‐central China, and contains abundant coesite inclusions in both garnet and dolomite. We investigated the content of structural water in these minerals with Fourier transform infrared spectroscopy. Our new results undermine the ubiquity of the “pressure‐vessel” model and highlight the role of reaction kinetics in preserving coesite due to the availability of water in UHP rocks.     

The last deglaciation in the Picos de Europa National Park (Cantabrian Mountains,northern Spain)

A sedimentological and geochemical study of the Lago Enol sequence (Cantabrian Mountains, northern Spain), together with detailed geomorphological mapping, provides a first record of glacier evolution and climate change over the last 40 ka in the Picos de Europa National Park. The Enol glacier retreated from its maximum extent prior to 40 ka BP as demonstrated by the onset of proglacial lacustrine sedimentation in two glaciated depressions: the Comella hollow to the north (before 40 ka BP) and the Lago Enol (before 38 ka BP). These results support previous evidence that the maximum extent of southern European glaciers occurred earlier than in northern Europe. Alternation of homogeneous and laminated proglacial sediments during the glacier retreat illustrate a dynamic glacial evolution during the Marine Isotope Stage (MIS) 3 (40–26 ka BP). A slight warming is detected at 26 ka ago with the change from proglacial sediments (in a lake located in contact to the glacier) to glaciolacustrine sedimentation (in a non‐contact or distal lake). Finally, the onset of organic‐rich sediments took place at 18 ka ago. This last transition occurred in two phases, similarly to the North Atlantic Last Termination, suggesting a link between North Atlantic Deep Water formation oscillations and palaeohydrological variability in the Cantabrian Mountains. Copyright © 2009 John Wiley & Sons, Ltd.     

One‐dimensional consolidation with a threshold gradient: a Stefan problem with rate‐dependent latent heat

During the process of one‐dimensional consolidation with a threshold gradient, the seepage front moves downward gradually, and the problem is indicated as a Stefan problem. The novel feature in this Stefan problem is a latent heat that varies inversely with the rate of the moving boundary. An exact solution for the external load that increases in proportion to the square root of time is constructed using the similarity transformation technique. Computational examples concerning the effect of different parameters on the motion of the seepage front are presented. The exact solution provides a worthwhile benchmark for verifying the accuracy of numerical and approximate methods. Copyright © 2013 John Wiley & Sons, Ltd.     

Zircon U–Pb ages and Hf isotope compositions of migmatites from the North Qinling terrane and their geological implications

Migmatites are predominant in the North Qinling (NQ) orogen, but their formation ages are poorly constrained. This paper presents a combined study of cathodoluminescence imaging, U–Pb age, trace element and Hf isotopes of zircon in migmatites from the NQ unit. In the migmatites, most zircon grains occur as new, homogeneous crystals, while some are present as overgrowth rims around inherited cores. Morphological and trace element features suggest that the zircon crystals are metamorphic and formed during partial melting. The inherited cores have oscillatory zoning and yield U–Pb ages of c. 900 Ma, representing their protolith ages. The early Neoproterozoic protoliths probably formed in an active continental margin, being a response to the assembly of the supercontinent Rodinia. The migmatite zircon yields Hf model ages of 1911 ± 20 to 990 ± 22 Ma, indicating that the protoliths were derived from reworking of Palaeoproterozoic to Neoproterozoic crustal materials. The anatexis zircon yields formation ages ranging from 455 ± 5 to 420 ± 4 Ma, with a peak at c. 435 Ma. Combined with previous results, we suggest that the migmatization of the NQ terrane occurred at c. 455–400 Ma. The migmatization was c. 50 Ma later than the c. 490 Ma ultra‐high‐P (UHP) metamorphism, indicating that they occurred in two independent tectonic events. By contrast, the migmatization was coeval with the granulite facies metamorphism and the granitic magmatism in the NQ unit, which collectively argue for their formation due to the northward subduction of the Shangdan Ocean. UHP rocks were distributed mainly along the northern margin and occasionally in the inner part of the NQ unit, indicating that they were exhumed along the northern edge and detached from the basement by the subsequent migmatization process.     

Geoarchaeological Investigations in Mesoamerica Move into the 21st Century: A Review

Over the past thirty years, geoarchaeology has moved from the fringe to mainstream status within Mesoamerican archaeological investigations. This review focuses on works published since the year 2000. Five themes are identified as central to recent studies: (1) the correlation of environmental change and cultural history; (2) anthropogenic environmental impacts; (3) ancient land cover, land use, and diet; (4) archaeological prospection; and (5) provenance studies. These themes are often interwoven in the application of complex systems approaches that allow scientists to more accurately model the intricacies of ancient human–environment interactions.